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    Aniline derivative and process for producing the same
    6.
    发明公开
    Aniline derivative and process for producing the same 有权
    Verfahren zur Herstellung von perfluoralkylierten Anilinderivaten

    公开(公告)号：EP1006102A2

    公开(公告)日：2000-06-07

    申请号：EP99123023.6

    申请日：1999-11-19

    申请人： NIHON NOHYAKU CO., LTD.

    发明人： Onishi, Masanobu ,  Yoshiura, Akihiko ,  Kohno, Eiji ,  Tsubata, Kenji

    IPC分类号： C07C209/68 ,  C07C211/52 ,  C07C213/08 ,  C07C215/76 ,  C07C217/84 ,  C07C233/15 ,  C07C271/14 ,  C07C323/36 ,  C07C323/41 ,  C07D209/08

    CPC分类号： C07C323/41 ,  C07C209/68 ,  C07C211/52 ,  C07C213/08 ,  C07C215/76 ,  C07C217/84 ,  C07C233/15 ,  C07C271/14 ,  C07C323/36 ,  C07D209/08

    摘要： The present invention provides an aniline derivative represented by the formula (I)
    wherein R 1 and R 2 are each H, (C 1-12 )alkyl, (C 3-8 )cycloalkyl, hydroxy(C 1-12 )alkyl, hydroxycarbonyl (C 1-12 )alkyl, (C 1-6 )alkoxycarbonyl(C 1-6 )alkyl, -COR 8 , wherein R 8 is H, halo(C 1-12 )alkyl, (C 3-8 )cycloalkyl or (substituted) phenyl, COOR 9 , wherein R 9 is a halo(C 1-6 )alkyl group, (substituted) phenyl or (substituted) benzyl; R 3 , R 4 , R 5 , R 6 and R 7 are each H, halogen, OH, nitro, halo(C 1-12 )alkylthio, (substituted) amino(C 1-2 )alkyl, (substituted) phenyl, (substituted) benzyl, amino, -N(R 10 )R 11 wherein R 10 and R 11 are each H, alkyl, cycloalkyl, (substituted) phenyl, (substituted) benzyl, -COR 8 or COOR 9 , or (C 2-27 )perfluoroalkyl, etc., and a process for producing the aniline derivative. According to the process of the present invention, perfluoroalkylaniline derivatives can be obtained by using various anilines as the substrate with a high position selectivity and high yield.

    摘要翻译： 本发明提供由式（I）表示的苯胺衍生物，其中R 1和R 2各自为H，（C 1-12）烷基，（C 3-8）环烷基，羟基（C 1-12） ）烷基，羟基羰基（C 1-12）烷基，（C 1-6）烷氧基羰基（C 1-6）烷基，-COR 8，其中R 8为H，卤代（C 1-12）烷基， ）环烷基或（取代的）苯基，COOR 9，其中R 9是卤代（C 1-6）烷基，（取代的）苯基或（取代的）苄基; R 3，R 4，R 5，R 6和R 7各自为H，卤素，OH，硝基，卤代（C 1-12）烷硫基，（取代的）氨基（C 1-2 ）取代的苯基，（取代的）苄基，氨基，-N（R 10）R 11其中R 10和R 11各自为H，烷基，环烷基，（取代的）苯基， （取代的）苄基，-COR 8或COOR 9，或（C2-27）全氟烷基等，以及苯胺衍生物的制备方法。 根据本发明的方法，可以通过以高位置选择性和高产率使用各种苯胺作为基材来获得全氟烷基苯胺衍生物。

    Fluorine-containing aniline compounds
    7.
    发明公开
    Fluorine-containing aniline compounds 有权
    氟里昂安林 - 维比登根

    公开(公告)号：EP0936212A1

    公开(公告)日：1999-08-18

    申请号：EP99102538.8

    申请日：1999-02-10

    申请人： NIHON NOHYAKU CO., LTD.

    发明人： Tohnishi, Masanori ,  Kohno, Eiji ,  Nakao, Hayami ,  Seo, Akira

    IPC分类号： C07C211/52

    CPC分类号： C07C211/52

    摘要： The present invention provides a novel fluorine-containing aniline compound represented by the general formula (I):
    (wherein R 1 is a halogen atom, a C 1 -C 6 alkyl group, a C 1 -C 6 alkoxy group or a trifluoromethyl group, and each of R 2 , R 3 and R 4 is H or a C 2 -C 6 perfluoroalkyl group, provided that at least one of R 2 , R 3 and R 4 is not H; that R 3 is neither a pentafluoroethyl group nor a n-heptafluoropropyl group, when R 1 is F and each of R 2 and R 4 is H; and that R 3 is not a pentafluoroethyl group, when R 1 is a methyl group and each of R 2 and R 4 is H), which is useful as an intermediate of a medicine, agrochemical, chemical product, etc.

    摘要翻译： 本发明提供由通式（I）表示的新型含氟苯胺化合物：其中R 1为卤素原子，C1-C6烷基，C1-C6烷氧基或三氟甲基 基团，R 2，R 3和R 4各自为H或C 2 -C 6全氟烷基，条件是R 2，R 3和R 4中的至少一个为 不是H; R 3既不是五氟乙基也不是正七氟丙基，当R 1为F且R 2和R 4各自为H时，R 3不为 五氟乙基，当R 1为甲基且R 2和R 4各自为H时），其可用作药物，农业化学品，化学产品等的中间体。