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公开(公告)号：EP0747123A2
公开(公告)日：1996-12-11
申请号：EP96304095.1
申请日：1996-06-05
IPC分类号： B01J23/22
CPC分类号： C01G31/02 , B01J23/22 , B01J23/8472 , B01J37/0018 , B01J37/033 , C01P2002/02 , C01P2002/20 , C01P2002/72 , C01P2002/78 , C01P2006/82
摘要： A solid acid-base catalyst contains vanadium pentoxide hydrate, preferably of the formula
V 2 O 5 ·nH 2 O
in which n has a value from 0.1 to 3, as confirmed by its X-ray diffraction spectrum shown in Fig. 1. This solid acid-base catalyst displays catalytic activity under mild conditions, and can be applied to the synthesis of olefins and ethers by alcohol dehydration, the synthesis of aldehydes and ketones by alcohol dehydrogenation, the hydration and isomerization of olefins, and alkylation, es terification, amidation, acetalization, amination, hydrogen shift, aldol condensation and polymerization.摘要翻译： 固体酸碱催化剂含有五氧化二钒水合物，优选式V2O5·nH2O，其中n为0.1〜3，如图1所示的X射线衍射光谱所证实。 该固体酸碱催化剂在温和条件下显示催化活性，可用于醇脱水合成烯烃和醚，通过醇脱氢合成醛和酮，烯烃的水合和异构化以及烷基化， 胺化，酰胺化，缩醛化，胺化，氢位移，醛醇缩合和聚合。
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2.发明公开Catalyst for production of substituted benzaldehyde, method for production of the catalyst, and method for production of substituted benzaldehyde 失效催化剂用于制备取代的苯甲醛，过程的催化剂和方法为取代的苯甲醛的制备的制备。
公开(公告)号：EP0459729A1
公开(公告)日：1991-12-04
申请号：EP91304756.9
申请日：1991-05-24
IPC分类号： B01J27/198 , B01J27/199 , B01J23/28 , B01J23/22 , B01J23/84 , C07C45/36
CPC分类号： B01J23/002 , B01J23/28 , B01J27/199 , B01J2523/00 , C07C45/36 , B01J2523/23 , B01J2523/305 , B01J2523/34 , B01J2523/55 , B01J2523/64 , B01J2523/68 , B01J2523/13 , B01J2523/14 , B01J2523/18 , B01J2523/53 , B01J2523/15 , B01J2523/17 , B01J2523/25 , B01J2523/51 , B01J2523/44
摘要： A catalyst for the production of a substituted benzaldehyde by catalytic vapor-phase oxidation of a substituted toluene, which catalyst has as a catalytically active substance being composed of an oxide represented by the general formula III: V a Mo b X c Y d O e wherein V, Mo, and O are respectively for vanadium, molybdenum, and oxygen, X is at least one element selected from the group consisting of sodium, potassium, rubidium, caesium, and thallium, Y is at least one element selected from the group consisting of niobium, tantalum, phosphorus, antimony, bismuth, tellurium, tin, lead, boron, copper, and silver, and a, b, c, d, and e indicate the atomic ratios of relevant elements such that where a + b = 1, then b = 0.05 to 0.4, c = 0.1 to 1, d = 0 to 1, and e = the value determined by the state of oxidation of other elements.
摘要翻译：
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3.发明授权
公开(公告)号：EP0963788B1
公开(公告)日：2004-10-13
申请号：EP99303859.5
申请日：1999-05-18
IPC分类号： B01J23/34 , C07C5/48 , C07C11/02 , B01J27/053
CPC分类号： C07C45/35 , B01J23/002 , B01J23/34 , B01J2523/00 , C07C5/48 , C07C45/33 , C07C45/34 , C07C51/252 , C07C2523/34 , Y02P20/52 , C07C11/02 , C07C47/22 , C07C57/04 , B01J2523/53 , B01J2523/72 , B01J2523/842 , B01J2523/51 , B01J2523/67 , B01J2523/56 , B01J2523/69 , B01J2523/17 , B01J2523/3712 , B01J2523/305 , B01J2523/12 , B01J2523/22 , B01J2523/62 , B01J2523/74 , B01J2523/55 , B01J2523/68 , B01J2523/13 , B01J2523/41 , B01J2523/54 , B01J2523/845
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4.发明公开Lower alkane oxidative dehydrogenation catalysts containing i) Cr or Mo, ii) W and iii) Sb and process for producing olefins 有权催化剂，其包含i）的Cr或Mo，ⅱ）W和ⅲ）的Sb为低级烷烃和方法以生产烯烃的氧化脱氢
公开(公告)号：EP0958860A3
公开(公告)日：2000-04-26
申请号：EP99303866.0
申请日：1999-05-18
CPC分类号： B01J23/8885 , B01J23/30 , B01J23/888 , C07C5/48 , C07C2523/12 , C07C2523/18 , C07C2523/30 , C07C2523/31 , C07C11/02
摘要： A catalyst of formula (1):A α Sb β W γ D δ O x wherein A is molybdenum or chromium; D is at least one of V, Nb, Ta, Fe, Co, Ni, Cu, Ag, Zn, B, Tl, Sn, Pb, Te, Li, Na, K, Rb, Cs, Mg, Ca, Sr, Ba, La, Ce and Sm; α = 1, β = 0.5-10, γ = 0.1-10 and δ = 0-3; and x is a numerical value determined by the oxidation states of the elements other than oxygen.
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5.发明公开Lower alkane oxidative dehydrogenation catalysts containing i) Cr or Mo, ii) W and iii) Sb and process for producing olefins 有权催化剂，其包含i）的Cr或Mo，ⅱ）W和ⅲ）的Sb为低级烷烃和方法以生产烯烃的氧化脱氢
公开(公告)号：EP0958860A2
公开(公告)日：1999-11-24
申请号：EP99303866.0
申请日：1999-05-18
CPC分类号： B01J23/8885 , B01J23/30 , B01J23/888 , C07C5/48 , C07C2523/12 , C07C2523/18 , C07C2523/30 , C07C2523/31 , C07C11/02
摘要： A catalyst of formula (1):
A α Sb β W γ D δ O x (1)
wherein A is molybdenum or chromium; D is at least one of V, Nb, Ta, Fe, Co, Ni, Cu, Ag, Zn, B, Tl, Sn, Pb, Te, Li, Na, K, Rb, Cs, Mg, Ca, Sr, Ba, La, Ce and Sm; α = 1, β = 0.5-10, γ = 0.1-10 and δ = 0-3; and x is a numerical value determined by the oxidation states of the elements other than oxygen.摘要翻译： 式的催化剂（1）：一种阿尔法锑的β伽马宽深增量牛其中，A为钼或铬; D为Ⅴ的至少一个，铌，钽，铁，钴，镍，铜，银，锌，硼，铊，锡，铅，碲，锂，钠，钾，铷，铯，镁，钙，锶， 的Ba，La，Ce和钐; 阿尔法= 1，β= 0.5-10，γ= 0.1-10和delta = 0-3; 和x是由除了氧以外的元素的氧化态确定的开采的数值。
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公开(公告)号：EP0450561B1
公开(公告)日：1996-08-28
申请号：EP91105173.8
申请日：1991-04-02
IPC分类号： H01L39/24
CPC分类号： H01L39/2464 , Y10S505/725 , Y10S505/782
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7.发明授权Lower alkane oxidative dehydrogenation catalysts containing i) Cr or Mo, ii) W and iii) Sb and process for producing olefins 有权催化剂，其包含i）的Cr或Mo，ⅱ）W和ⅲ）的Sb为低级烷烃和方法以生产烯烃的氧化脱氢
公开(公告)号：EP0958860B1
公开(公告)日：2005-03-02
申请号：EP99303866.0
申请日：1999-05-18
CPC分类号： B01J23/8885 , B01J23/30 , B01J23/888 , C07C5/48 , C07C2523/12 , C07C2523/18 , C07C2523/30 , C07C2523/31 , C07C11/02
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8.发明公开
公开(公告)号：EP0963788A2
公开(公告)日：1999-12-15
申请号：EP99303859.5
申请日：1999-05-18
CPC分类号： C07C45/35 , B01J23/002 , B01J23/34 , B01J2523/00 , C07C5/48 , C07C45/33 , C07C45/34 , C07C51/252 , C07C2523/34 , Y02P20/52 , C07C11/02 , C07C47/22 , C07C57/04 , B01J2523/53 , B01J2523/72 , B01J2523/842 , B01J2523/51 , B01J2523/67 , B01J2523/56 , B01J2523/69 , B01J2523/17 , B01J2523/3712 , B01J2523/305 , B01J2523/12 , B01J2523/22 , B01J2523/62 , B01J2523/74 , B01J2523/55 , B01J2523/68 , B01J2523/13 , B01J2523/41 , B01J2523/54 , B01J2523/845
摘要： A catalyst of formula (1):
Mn α E 1 β E 2 γ O x (1)
wherein E 1 is at least one element selected from P, As, Sb, B, S, Se, Te, F, Cl, Br, I, Nb, Ta, W, Re and Cu; E 2 is at least one element selected from Cr, Fe, Co, Ni, Ag, Au, Zn, Tl, Sn, Pb, Bi, Li, Na, K, Rb, Cs, Mg, Ca, Sr, Ba, Y, La, Ce, Nd and Sm; α = 1, β = 0.01-10, γ = 0-5, and x is a numerical value determined by the oxidation states of the elements other than oxygen.-
公开(公告)号：EP0747123A3
公开(公告)日：1997-04-02
申请号：EP96304095.1
申请日：1996-06-05
IPC分类号： B01J23/22
CPC分类号： C01G31/02 , B01J23/22 , B01J23/8472 , B01J37/0018 , B01J37/033 , C01P2002/02 , C01P2002/20 , C01P2002/72 , C01P2002/78 , C01P2006/82
摘要： A solid acid-base catalyst contains vanadium pentoxide hydrate, preferably of the formula
V 2 O 5 ·nH 2 O
in which n has a value from 0.1 to 3, as confirmed by its X-ray diffraction spectrum shown in Fig. 1. This solid acid-base catalyst displays catalytic activity under mild conditions, and can be applied to the synthesis of olefins and ethers by alcohol dehydration, the synthesis of aldehydes and ketones by alcohol dehydrogenation, the hydration and isomerization of olefins, and alkylation, es terification, amidation, acetalization, amination, hydrogen shift, aldol condensation and polymerization.-
公开(公告)号：EP0450561A3
公开(公告)日：1992-01-29
申请号：EP91105173.8
申请日：1991-04-02
IPC分类号： H01L39/24
CPC分类号： H01L39/2464 , Y10S505/725 , Y10S505/782
摘要： The present invention provides a process for producing a superconducting material capable of elevating the Tc of oxide superconductors, in paticular Bi-based superconductors. The feature of the present invention resides in a process for producing an oxide superconductor, in which a intermediate product or a product showing superconducting property is treated with a solution containing a compound having a reducing or oxdising function. As the compound having a reducing function, compounds having two or more enolic hydroxy groups, cycloaliphatic polyhydric alcohol compounds or inorganic type reducing compounds are preferred. As the compound having oxidizing function, there can be mentioned, for example, carbonyl compounds, ozone, hydrogen peroxide, organic peroxide, dimethylsulfoxide and permanganate.
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