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1.发明公开
公开(公告)号：EP1557436A1
公开(公告)日：2005-07-27
申请号：EP03758797.9
申请日：2003-10-23
申请人： NOF CORPORATION
IPC分类号： C08F255/00 , C08F8/46
CPC分类号： C08F255/00 , C08F255/02 , C08L51/06 , C08L2666/02 , C09J151/06
摘要： A graft copolymer having a structure in which a vinyl copolymer segment formed from a vinyl monomer having an acid is suspended in a molecular chain of a polyolefin resin segment via a β-substituted propylene group is obtained, by reaction of polyolefin resin having β-substituted propenyl group as a pendant and a vinyl monomer having an acid, and further a graft copolymer composition containing the same and a molded product thereof are obtained.
The obtained graft copolymer, the composition containing the same and the molded product thereof are excellent in adhesive property to a polar material and scratch resistance.摘要翻译： 具有其中从具有在酸的乙烯基单体形成的乙烯基共聚物链段通过一个测试悬浮在聚烯烃树脂段的分子链的结构的接枝共聚物 - 取代的丙烯基团获得，由具有β-聚烯烃树脂的反应取代 丙烯基作为侧和具有对酸的乙烯基单体，和进一步的接枝共聚物组合物含有相同和成型品物获得。 将所得到的接枝共聚物，含其的组合物和成型品物具有优良的粘合性的极性材料和抗划伤性。
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公开(公告)号：EP2184325B1
公开(公告)日：2013-10-09
申请号：EP08828876.6
申请日：2008-08-26
申请人： NOF Corporation
发明人： TAKAMURA, Masumi , MIMA, Kazuaki
IPC分类号： C08L101/00 , C08J3/20 , C08J5/00 , C08K9/04
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公开(公告)号：EP2123686B1
公开(公告)日：2013-02-20
申请号：EP07738174.7
申请日：2007-03-09
申请人： NOF CORPORATION
发明人： HAYASHI, Masaki , TAKAMURA, Masumi
IPC分类号： C08F291/00 , C08F2/44 , C08F257/02 , C08F265/04 , C08F2/22
CPC分类号： C08F291/00 , C08F2/44 , C08F257/02 , C08F265/04 , C08F271/00 , C08F271/02 , C08F283/00 , C08L51/003 , C09D151/003 , C08L2666/02
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4.发明授权
公开(公告)号：EP1557436B1
公开(公告)日：2008-07-16
申请号：EP03758797.9
申请日：2003-10-23
申请人： NOF CORPORATION
IPC分类号： C08F255/00 , C08F8/46
CPC分类号： C08F255/00 , C08F255/02 , C08L51/06 , C08L2666/02 , C09J151/06
摘要： A graft copolymer having a structure in which a vinyl copolymer segment formed from a vinyl monomer having an acid is suspended in a molecular chain of a polyolefin resin segment via a beta -substituted propylene group is obtained, by reaction of polyolefin resin having beta -substituted propenyl group as a pendant and a vinyl monomer having an acid, and further a graft copolymer composition containing the same and a molded product thereof are obtained. The obtained graft copolymer, the composition containing the same and the molded product thereof are excellent in adhesive property to a polar material and scratch resistance.
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公开(公告)号：EP2184325A1
公开(公告)日：2010-05-12
申请号：EP08828876.6
申请日：2008-08-26
申请人： NOF Corporation
发明人： TAKAMURA, Masumi , MIMA, Kazuaki
IPC分类号： C08L101/00 , C08J3/20 , C08J5/00 , C08K9/04
摘要： Disclosed is a thermoplastic resin composition containing a graft material and an organic peroxide group dispersion medium in which the graft material is dispersed. The graft material is obtained by melt-mixing a metal oxide fine particle having an organic peroxide group on the surface and a thermoplastic resin, and has a structure in which the thermoplastic resin is grafted to the metal oxide fine particle. The organic peroxide group on the surface of the metal oxide fine particle is preferably a peroxymonocarbonate group. The organic peroxide group on the surface of the metal oxide fine particle is preferably obtained by reacting a hydroxy group of a silicon oxide fine particle with an amino-modified silane coupling agent, thereby introducing an amino group to the surface of the silicon oxide fine particle, and then reacting the amino group with a compound having an ethylenically unsaturated group and an organic peroxide group.
摘要翻译： 本发明公开了含有接枝材料和分散有接枝材料的有机过氧化物基分散介质的热塑性树脂组合物。 接枝材料通过将表面具有有机过氧化物基的金属氧化物微粒与热塑性树脂熔融混合而得到，具有热塑性树脂接枝于金属氧化物微粒的结构。 金属氧化物微粒表面上的有机过氧化物基团优选为过氧单碳酸酯基团。 金属氧化物微粒表面上的有机过氧化物基团优选通过使氧化硅微粒的羟基与氨基改性硅烷偶联剂反应，从而在氧化硅微粒表面引入氨基 然后使氨基与具有烯键式不饱和基团和有机过氧化物基团的化合物反应。
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6.发明公开METHOD FOR PRODUCTION OF CORE-SHELL MICROPARTICLE, AND METHOD FOR PRODUCTION OF MONODISPERSE CROSSLINKED MICROPARTICLE HAVING ALKOXYAMINE GROUP FOR USE AS INTERMEDIATE FOR THE PRODUCTION OF THE CORE-SHELL MICROPARTICLE 有权VERFAHREN ZUR HERSTELLUNG VON MONODISPERSEM KERN-SCHALE-MIKROTEILCHEN。
公开(公告)号：EP2123686A1
公开(公告)日：2009-11-25
申请号：EP07738174.7
申请日：2007-03-09
申请人： NOF CORPORATION
发明人： HAYASHI, Masaki , TAKAMURA, Masumi
IPC分类号： C08F291/00 , C08F2/44
CPC分类号： C08F291/00 , C08F2/44 , C08F257/02 , C08F265/04 , C08F271/00 , C08F271/02 , C08F283/00 , C08L51/003 , C09D151/003 , C08L2666/02
摘要： Disclosed is a core-shell microparticle (10) which is produced by heating a mixture of a crosslinked microparticle (11) having an alkoxyamine group (12) and a monomer to 100 to 180°C to cause graft polymerization. The crosslinked microparticle (11) is produced by allowing a seed particle to absorb a monomer mixture comprising 15 to 99% by mass of a crosslinkable monomer and 1 to 85% by weight of a monomer having an alkoxyamine group, and then adding a polymerization initiator to the resulting product to cause the polymerization of the monomer mixture.
摘要翻译： 公开了通过将具有烷氧基胺基（12）的交联微粒（11）和单体的混合物加热至100〜180℃而制造的核 - 壳微粒（10），进行接枝聚合。 交联微粒（11）通过使种子颗粒吸收含有交联性单体15〜99质量％的单体混合物和1〜85重量％的具有烷氧基胺基的单体，然后添加聚合引发剂 向所得产物引起单体混合物的聚合。
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7.发明授权
公开(公告)号：EP1564248B1
公开(公告)日：2007-08-15
申请号：EP02781786.5
申请日：2002-11-15
申请人： NOF CORPORATION
CPC分类号： C08L23/10 , C08F255/00 , C08F255/02 , C08K5/06 , C08K5/20 , C08L23/02 , C08L23/06 , C08L23/08 , C08L23/0815 , C08L23/0869 , C08L23/16 , C08L51/06 , C08L71/02 , C08L2205/03 , C08L2205/035 , C08L51/00 , C08L2666/24 , C08L2666/02 , C08L2666/04 , C08L2666/06
摘要： A graft copolymer composition which gives a molding retaining a satisfactory appearance over long and from which a molding less apt to be worn, marred, or bent can be easily molded. The graft copolymer composition comprises a graft copolymer of a multiphase structure as the main component and a lubricant comprising a fatty acid amide or alkylene oxide derivative. The graft copolymer comprises olefin polymer segments (a) and vinyl polymer segments (b), wherein particles of the segments of one polymer are dispersed in the segments of the other polymer. The particles have a diameter of 0.001 to 10 µm. The vinyl polymer segments (b) are formed from a polar vinyl monomer.
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8.发明公开GRAFT COPOLYMER COMPOSITION, THERMOPLASTIC RESIN COMPOSITION CONTAINING THE SAME, AND MOLDED OBJECT 有权PFROPFCOPOLYMERZUSAMMENSETZUNG，DIESE ENTHALTENDE THERMOPLASTISCHE HARZZUSAMMENSETZUNG UNDFORMKöRPER
公开(公告)号：EP1564248A1
公开(公告)日：2005-08-17
申请号：EP02781786.5
申请日：2002-11-15
申请人： NOF CORPORATION
CPC分类号： C08L23/10 , C08F255/00 , C08F255/02 , C08K5/06 , C08K5/20 , C08L23/02 , C08L23/06 , C08L23/08 , C08L23/0815 , C08L23/0869 , C08L23/16 , C08L51/06 , C08L71/02 , C08L2205/03 , C08L2205/035 , C08L51/00 , C08L2666/24 , C08L2666/02 , C08L2666/04 , C08L2666/06
摘要： A graft copolymer composition capable of producing a molded product retaining a satisfactory appearance over a long period of time and having abrasion resistance, scratching resistance and bending resistance. The graft copolymer composition contains a graft copolymer as the main component and a lubricant including a fatty acid amide or an alkylene oxide derivative. The graft copolymer includes an olefin polymer segment (a) and a vinyl polymer segment (b). Particles of one segment are dispersed in the other one segment. The diameter of the particles is 0.001 to 10 µm. The vinyl polymer segment (b) is formed from a polar vinyl monomer.
摘要翻译： 一种接枝共聚物组合物，其能够长时间地制备保持良好外观的成型体，并且具有耐磨性，耐擦伤性和耐弯曲性。 接枝共聚物组合物含有作为主要成分的接枝共聚物和包含脂肪酸酰胺或烯化氧衍生物的润滑剂。 接枝共聚物包括烯烃聚合物链段（a）和乙烯基聚合物链段（b）。 一段的颗粒分散在另一段中。 颗粒的直径为0.001至10微米。 乙烯基聚合物链段（b）由极性乙烯基单体形成。
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