专利检索 ap:("Nagoya Industrial Science Research Institute" OR "Kanto Kagaku Kabushiki Kaisha") AND inv:"SANDVAL, Christian A. c/o Shanghai Institute of Org. Chemistry" 第 1 页

1.

发明授权
RUTHENIUM COMPLEX AND PROCESS FOR PRODUCING TERT-ALKYL ALCOHOL THEREWITH 有权
标题翻译：钌及其制造方法TERT烷基醇及其应用

公开(公告)号：EP1813621B1

公开(公告)日：2011-06-08

申请号：EP05795713.6

申请日：2005-10-24

申请人： Nagoya Industrial Science Research Institute , Kanto Kagaku Kabushiki Kaisha

发明人： OHKUMA, Takeshi Verudomiru-Soen 2-401 , SANDVAL, Christian A. c/o Shanghai Institute of Org. Chemistry , NOYORI, Ryoji

IPC分类号： C07F9/50 , C07B53/00 , C07C29/145 , C07C31/125 , C07C33/20 , C07C33/30 , C07C35/08 , C07C67/29 , C07C69/24 , C07D213/73 , C07D307/44 , C07D333/16 , C07B61/00 , C07F15/00

CPC分类号： C07D213/73 , C07B53/00 , C07C29/145 , C07C67/31 , C07F15/0053 , C07C31/125 , C07C69/675 , C07C69/732

摘要： Pinacolone being a tert-alkyl ketone is hydrogenated by pressurized hydrogen in the presence of ruthenium complex (S)-1 and a base, thereby obtaining corresponding (S)-3,3-dimethyl-2-butanol with 100% yield, 97%ee.