摘要:
Disclosed is a filler for optical isomer separation which: allows a polymer compound derivative to be immobilized on the surface of a carrier at a high ratio; and is excellent in optical separation ability. The filler is characterized in that the filler is obtained by modifying part of hydroxy or amino groups of a polymer compound having the hydroxy or amino groups with molecules of a compound represented by the following general formula (I) : A-X-Si (Y) n R 3-n , and is carried by a carrier through chemical bonding.
摘要:
A polymer compound derivative, obtained by modifying part of the hydroxy or amino groups of a polymer compound having the hydroxy or amino groups with molecules of a compound represented by the followinggeneral formula (I) :A-X-Si (Y) n R 3-n (I), whereArepresents a reactive group which reacts with a hydroxy or amino group, X represents an alkylene group which has 1 to 18 carbon atoms and which may have a branch, or an arylene group which may have a substituent, Y represents a reactive group which reacts with a silanol group to form a siloxane bond, R represents an alkyl group which has 1 to 18 carbon atoms and which may have a branch, or an aryl group which may have a substituent, and n represents an integer of 1 to 3.
摘要翻译:通过将具有羟基或氨基的高分子化合物的羟基或氨基的一部分与下列通式(I)表示的化合物的分子一起改性得到的高分子化合物衍生物:AX-Si(Y)n R 3-n (I),其中表示与羟基或氨基反应的反应性基团,X表示具有1至18个碳原子并且可以具有支链的亚烷基或可以具有取代基的亚芳基,Y表示反应性 与硅烷醇基反应以形成硅氧烷键的基团,R表示具有1至18个碳原子并且可以具有支链的烷基或可以具有取代基的芳基,n表示1〜 3。
摘要:
The present invention provides: a polysaccharide derivative containing a structure wherein hydrogen atoms in a hydroxyl group or amino group at the 2-position and the 3-position of a structure unit of polysaccharide are substituted with different substituents respectively represented by a specific general formula; and, a separating agent for optical isomers, which contains such a polysaccharide derivative. The present invention can provide a novel polysaccharide derivative which has excellent optical isomer separating ability, and is thus suitable for a separating agent for optical isomers, and can provide a separating agent for optical isomers which comprises the polysaccharide derivative.
摘要:
Provided is a complex obtained by reacting a polymer compound derivative obtained by modifying part of hydroxy groups or amino groups of a polymer compound having the hydroxy groups or amino groups with a compound represented by the following general formula (I) with one or more kinds of compounds represented by the following general formulae (II) to (V): (I) A-X-Si(Y) n R 3-n (where A, X, Y, R, and n are as defined in claim 1); (II) M(OR 1 ) n R 2 4-n ; (III) Al(OR 1 ) p R 2 3-p ; (IV) Mg(OR 1 ) q R 2 2-q (where M, R 1 , R 2 , n, p, and q are as defined in claim 1); and (V) (where R 3 , R 4 , R 5 , and R 6 are as defined in claim 1).
摘要翻译:提供了将通过将具有羟基或氨基的高分子化合物的羟基或氨基的一部分得到的高分子化合物衍生物与下述通式(I)表示的化合物与一种或多种 由以下通式(II)至(V)表示的化合物:(I)AX-Si(Y)n R 3-n(其中A,X,Y,R和n如权利要求1所定义); (II)M(OR 1)n R 2 4-n; (III)Al(OR 1)p R 2 3-p; (IV)Mg(OR 1)q R 2 2-q(其中M,R 1,R 2,n,p和q如权利要求1中所定义); 和(V)(其中R 3,R 4,R 5和R 6如权利要求1中所定义)。
摘要:
To provide a β-pinene polymer excellent in heat resistance while having thermoplasticity, and further also having excellent strength, without impairing the inherent characteristics of small specific gravity and excellent transparency. A desired β-pinene polymer having a weight average molecular weight of 90,000 to 1,000,000 and a glass transition temperature of 80°C or more was obtained by polymerizing β-pinene in the presence of a bifunctional vinyl compound.