摘要:
There is provided is a hydroxyalkyl alkyl cellulose exhibiting good flowability and high compressibility. More specifically, provided are a hydroxyalkyl alkyl cellulose having a volume-based average particle diameter, determined by dry laser diffractometry, of 50 to 100 µm, and having, on a basis of a dynamic image analysis to divide all particles into fine particles, spherical particles and fibrous particles, a volume fraction of the fibrous particles consisting of long and short fibrous particles relative to all of the particles of 45 to 70%, and a volume fraction of the fine particles relative to all of the particles of less than 2.0%; a solid preparation including the hydroxyalkyl alkyl cellulose; and others.
摘要:
A novel partial ester of cellulose with a nitrogenous carboxylic acid, the ester being useful as an antibacterial agent, a flame retardant, etc.; and a simple process for producing the partial ester. Fibers made of the partial ester have washing-resistant antibacterial properties and flame retardancy. The process comprises contacting a nitrogenous carboxylic acid ester with cellulose and heating the mixture.
摘要:
A method is described for the chemical modification of pre-shaped hydrogels in non-aqueous medium. The conditions permit the reaction of highly expanded, porous hydrogel particles, such as spherical beads, using pseudo homogeneous reaction conditions in the absence of water. The method involves a three step procedure in which the porous gels are solvent exchanged into a water-free solvent (step 1) with minimal change in gel dimension and porosity; followed by reaction under non-aqueous condition (step 2); and followed by solvent exchange into water (step 3). Many different types of reactions requiring non-aqueous conditions may be carried out using these conditions. The method has particularly been demonstrated for crosslinking fluorinating beads, and for esterifying beads in a reaction involving multifunctional free carboxylic acids in the presence of dicyclohexylcarbodiimide (DCC).
摘要:
Die Erfindung betrifft ein Verfahren zur schonenden Veresterung einer empfindlichen Carbonsäure, insbesondere einer geeignet geschützten Aminosäure mit einer Alkoholkomponente, wobei man erfindungsgemäß in Gegenwart von 2,4,6-Mesitylen-1-sulfonyl-3-nitro-1,2,4-triazolid (MSNT) und einer schwachen Base in einem aprotischen und nicth-basischen Lösungsmittel verestert.
摘要:
Die Erfindung betrifft ein Verfahren zur schonenden Veresterung einer empfindlichen Carbonsäure, insbesondere einer geeignet geschützten Aminosäure mit einer Alkoholkomponente, wobei man erfindungsgemäß in Gegenwart von 2,4,6-Mesitylen-1-sulfonyl-3-nitro-1,2,4-triazolid (MSNT) und einer schwachen Base in einem aprotischen und nicth-basischen Lösungsmittel verestert.
摘要:
There is provided a cellulose derivative that has a high amount of a chelate adsorption group introduced, has high hydrophilicity, and is capable of efficiently recovering boron. The cellulose derivative of the present disclosure has a repeating unit represented by the following formula (I-1). In the following formula (I-1), Ra is the same as or different from each other, and is a hydroxyl group or a group represented by the following formula (a). In the following formula (a), R1 represents a hydrogen atom or a methyl group. R2 represents a hydrogen atom or a hydrocarbon group optionally having a hydroxyl group. R3 represents a hydrogen atom or a hydrocarbon group. Note that at least one of all Ra contained in the cellulose derivative is the group represented by the following formula (a).
摘要:
The invention relates to a method of treating chemical pulp fibers by a polymerizing hydroxy acid, the fibers thus obtained and the products refined from them. In the method, the hydroxy acid reacts with the reactive groups of the fibers in the presence of a catalyst, forming ester bonds. The following units of the same hydroxy acid are oligomerized and/or polymerized to these grafted acid residues. The fibers thus treated and the products refined thereof endure better processing stages that include drawing and stretching than untreated fibers.
摘要:
Provided are low-substituted hydroxypropyl cellulose (L-HPC) having a hydroxypropoxy content of from 5 to 16% by weight, and having, on a basis of a dynamic image analysis to divide all particles into fine, spherical, and fibrous particles consisting of long and short fibrous particles, a volume fraction of the long fibrous particles of from 15 to 50% and a volume fraction of the short fibrous particles of from 23 to 60%; and a solid preparation containing the L-HPC. Also provided is a method for producing the L-HPC including the steps: bringing sheet-like or chip-like pulp having a length-weighted average fiber length of from 2.40 to 3.50 mm into contact with an alkali metal hydroxide solution, reacting the resulting alkali cellulose with propylene oxide, and dispersing the resulting reaction product in water containing an acid to partially dissolve it therein, followed by neutralization with an acid to precipitate crude L-HPC.