摘要:
A polymer compound derivative, obtained by modifying part of the hydroxy or amino groups of a polymer compound having the hydroxy or amino groups with molecules of a compound represented by the followinggeneral formula (I) :A-X-Si (Y) n R 3-n (I), whereArepresents a reactive group which reacts with a hydroxy or amino group, X represents an alkylene group which has 1 to 18 carbon atoms and which may have a branch, or an arylene group which may have a substituent, Y represents a reactive group which reacts with a silanol group to form a siloxane bond, R represents an alkyl group which has 1 to 18 carbon atoms and which may have a branch, or an aryl group which may have a substituent, and n represents an integer of 1 to 3.
摘要翻译:通过将具有羟基或氨基的高分子化合物的羟基或氨基的一部分与下列通式(I)表示的化合物的分子一起改性得到的高分子化合物衍生物:AX-Si(Y)n R 3-n (I),其中表示与羟基或氨基反应的反应性基团,X表示具有1至18个碳原子并且可以具有支链的亚烷基或可以具有取代基的亚芳基,Y表示反应性 与硅烷醇基反应以形成硅氧烷键的基团,R表示具有1至18个碳原子并且可以具有支链的烷基或可以具有取代基的芳基,n表示1〜 3。
摘要:
A separatory agent for optical isomers which contains a polysaccharide derivative as an active ingredient, wherein the polysaccharide derivative serving as an active ingredient is one formed by replacing at least part of the hydrogen atoms of the hydroxy groups and amino groups of a polysaccharide with at least one member selected between a benzoyl group having a specific alkyl group and a carbamoyl group in which one hydrogen atom has been replaced with an aromatic group having a specific alkyl group. It is a novel separatory agent for optical isomers which has the high ability to asymmetrically identify the target compound to be analyzed and isolated.
摘要:
A process for producing a high-purity polysaccharide containing hydrophobic groups which comprises: a first-stage reaction in which a C12-50 hydroxylic hydrocarbon or a sterol is reacted with a diisocyanate compound represented by the formula OCN-R -NCO (wherein R is a C1-50 hydrocarbon group) to produce a hydrophobic compound the molecule of which has an isocyanate group and a residue of one molecule of the reacted hydrocarbon or sterol; a second-stage reaction in which the hydrophobic isocyanate compound obtained in the first-stage reaction is reacted with a polysaccharide to produce a polysaccharide having, as hydrophobic groups, either C12-50 hydrocarbon groups or steryl groups; and purifying the product of the second-stage reaction with a ketone solvent.
摘要:
The invention relates to poly(α-1,4-D-glucan)s with a degree of polymerisation of at least approx. 40, preferably at least approx. 50 and most preferably at least approx. 60. Plasticised poly(α-1,4-D-glucan)s with the aforementioned degrees of polymerisation or thermoplastic polymer mixtures containing plasticised thermoplastic poly(α-1,4-D-glucan)s, are especially suitable as a support matrix for active substances used in agriculture, pharmaceutical active substances and/or cosmetic active substances.
摘要:
Methods for producing glycan nitrones comprising reacting glycans with a mono-N-substituted hydroxylamine at pH 6 or greater to form glycan nitrones. Methods for producing glycan derivatives comprising reacting glycan nitrones produced by reacting glycans with a mono-N-substituted hydroxylamine at pH 6 or greater with a reducing agent to form hydroxylamine glycan derivatives and uses of the glycan nitrones and hydroxylamine glycan derivatives produced by the methods.
摘要:
New polysaccharide derivatives useful for the separation of optical isomers, prepared by substituting at least one atomic group of formula (1), (2) or (3) for part or the whole of hydrogen atoms of the hydroxyl or amino groups of the polysaccharide. In the formulae R is a group having 1 to 30 carbon atoms and at least one center of asymmetry.
摘要:
The invention relates to special amyloses for the production of biodegradable, clear, transparent and flexible plastics, especially foils and films, which: (a) swell but do not dissolve in cold water, (b) produce uniform fluid quasi-solutions without gel formation on heating to above 80°C with agitation, where this state is maintained on cooling to a temperature of 50°C without gel formation and deterioration for at least five minutes and the solution, in a concentration of 5 to 25% can be extruded on a flat substrate with a slot width of 100 to 700 νm.
摘要:
The invention provides modified starches having unique gelling properties which are prepared by chemically reacting an amylose containing starch base with an etherification or esterification reagent which will introduce a long linear hydrocarbon chain substituent therein. The aqueous gels formed by the starches are thermally and pH-reversible and the thermally-reversible gels are hot gels. The invention further provides an improved process for preparing starch halfacid esters in water by reacting starch under alkaline conditions with a hydrophobic-substituted cyclic dicarboxylic acid anhydride in the presence of a phase transfer agent.