摘要:
The invention relates to gas separation, in particular to separation of C02 from C02-rich liquids, particularly from C02 absorption liquids used in the removal of C02 from off-gases or product flows, such as natural gas or synthesis gas. According to the invention, C02 is separated from a C02-rich liquid by a method comprising a step wherein, under elevated pressure, said liquid is contacted with a membrane based on polyacetylene substituted with trimethylsilyl groups such that the pressure across the membrane is at least 1 bar and that at least a part of the C02 is transported from the liquid through the membrane.
摘要:
The invention relates to a method for the absorption of acid gases, such as CO2 and H2S, from gas mixtures. According to the invention, acid gases are absorbed from a gas mixture by contacting this gas mixture with a liquid in which is dissolved so high a concentration of an amino acid or a salt thereof that a precipitate is formed. The contact takes place in a column of the packing-free type or a column suitable for processing slurries.
摘要:
The invention relates to an apparatus for performing membrane gas/liquid absorption at elevated pressure, comprising a pressure vessel in which a membrane unit is provided for separate feed-through of the gas phase and the liquid phase, in such a way that exchange of components to be absorbed can take place between the gas phase and the liquid phase, the flow direction of the gas phase through the absorber being essentially perpendicular to the flow direction of the liquid phase through the absorber. The invention further relates to a method for performing gas/liquid membrane absorption employing this absorber, in particular for the absorption of CO2, H2S, mercury (vapour) and/or water (vapour) from a gas phase at elevated pressure. The invention finally relates to a method for refining natural gas using the absorber and method according to the invention.
摘要:
The invention relates to a method for removing gaseous oxidisable constituents from a gas phase, wherein the oxidisable constituents are absorbed in a liquid phase which contains an oxidising agent for the gaseous oxidisable constituents, the gas phase and the liquid phase being fed on either side along a membrane which is permeable to the constituents to be absorbed. The invention also relates to a method for performing membrane gas absorption, wherein the gas phase contains at least one gaseous oxidisable constituent, the liquid phase contains at least one oxidising agent, such that at least one of the oxidisable gaseous constituents is absorbed into the liquid phase, an oxidation/reduction reaction between the gaseous constituents and the oxidising agent taking place in at least one step. The invention is preferably employed in the removal of ethene during the storage of fruit, the removal of mercury (vapour) from natural gas and the removal of H2S, at concentrations of 0.001-10 mg/m3. The membranes are preferably in the form of hollow fibres.
摘要:
The invention relates to gas separation, in particular to separation of C02 from C02-rich liquids, particularly from C02 absorption liquids used in the removal of C02 from off-gases or product flows, such as natural gas or synthesis gas. According to the invention, C02 is separated from a C02-rich liquid by a method comprising a step wherein, under elevated pressure, said liquid is contacted with a membrane based on polyacetylene substituted with trimethylsilyl groups such that the pressure across the membrane is at least 1 bar and that at least a part of the C02 is transported from the liquid through the membrane.
摘要:
The invention relates to an apparatus for performing membrane gas/liquid absorption at elevated pressure, comprising a pressure vessel in which a membrane unit is provided for separate feed-through of the gas phase and the liquid phase, in such a way that exchange of components to be absorbed can take place between the gas phase and the liquid phase, the flow direction of the gas phase through the absorber being essentially perpendicular to the flow direction of the liquid phase through the absorber. The invention further relates to a method for performing gas/liquid membrane absorption employing this absorber, in particular for the absorption of CO2, H2S, mercury (vapour) and/or water (vapour) from a gas phase at elevated pressure. The invention finally relates to a method for refining natural gas using the absorber and method according to the invention.
摘要:
The invention relates to a method for the absorption of acid gases, such as CO2 and H2S, from gas mixtures. According to the invention, acid gases are absorbed from a gas mixture by contacting this gas mixture with a liquid in which is dissolved so high a concentration of an amino acid or a salt thereof that a precipitate is formed. The contact takes place in a column of the packing-free type or a column suitable for processing slurries.
摘要:
The invention relates to a method for removing gaseous oxidisable constituents from a gas phase, wherein the oxidisable constituents are absorbed in a liquid phase which contains an oxidising agent for the gaseous oxidisable constituents, the gas phase and the liquid phase being fed on either side along a membrane which is permeable to the constituents to be absorbed. The invention also relates to a method for performing membrane gas absorption, wherein the gas phase contains at least one gaseous oxidisable constituent, the liquid phase contains at least one oxidising agent, such that at least one of the oxidisable gaseous constituents is absorbed into the liquid phase, an oxidation/reduction reaction between the gaseous constituents and the oxidising agent taking place in at least one step. The invention is preferably employed in the removal of ethene during the storage of fruit, the removal of mercury (vapour) from natural gas and the removal of H2S, at concentrations of 0.001-10 mg/m . The membranes are preferably in the form of hollow fibres.
摘要:
The invention relates to a method for the absorption of one or more gaseous components from a gas phase, in that the gas phase with the component(s) to be absorbed present therein is brought into contact with a liquid phase, wherein the gas phase and the liquid phase are separated by a hydrophobic membrane of a material other than polytetrafluoroethene, wherein the liquid phase comprises water and a water-miscible and/or water-soluble absorbent, and wherein the liquid phase does not give rise to any leakage from the membrane or is effective in preventing or counteracting leakage from the membrane. According to a first preferred aspect, the liquid phase comprises water and a water-miscible and/or water-soluble organic absorbent, wherein the surface tension at 20 °C has been brought to at least 60 x 10-3 N/m by adding a water-soluble salt. According to a second preferred aspect, the liquid phase comprises an aqueous solution of a water-soluble amino acid or a salt thereof, such as taurine and derivatives. According to a third preferred aspect, the liquid phase comprises an aqueous solution of a water-soluble phosphate salt. The membranes are preferably in the form of hollow fibres of, for example, polypropene or polyethene. The method is suitable in particular for the absorption of carbon dioxide.