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    PROCESS FOR SEPARATING LIQUID MIXTURES
    9.
    发明公开
    PROCESS FOR SEPARATING LIQUID MIXTURES 有权
    VERFAHREN ZUR TRENNUNGFLÜSSIGERMISCHUNGEN

    公开(公告)号：EP2331241A1

    公开(公告)日：2011-06-15

    申请号：EP09808441.1

    申请日：2009-08-19

    申请人： Nederlandse Organisatie voor Toegepast -Natuurwetenschappelijk Onderzoek TNO

    发明人： MEULEMAN, Erik Everhardus Bernardus ,  GEERDINK, Peter ,  GOETHEER, Earl Lawrence Vincent ,  SANCHEZ FERNANDEZ, Eva

    IPC分类号： B01D61/36 ,  B01D63/08 ,  B01D63/02

    CPC分类号： B01D61/362 ,  B01D61/364 ,  B01D63/02 ,  B01D63/082 ,  B01D2313/146 ,  B01D2313/22 ,  C02F1/447 ,  C02F1/448

    摘要： The invention is directed to a process for separating liquid mixtures and an apparatus for separating liquid mixtures by pervaporation. The process of the invention comprises: - passing a stream of the liquid mixture over a permeable non-porous selective membrane, said membrane being selective for at least one of said first and second compounds, whereby at least part of the stream passes through said membrane leaving the other side of said membrane as a vapor, with the remainder forming a retentate stream, and - condensing said vapor on a condenser surface having a lower temperature than the vaporizing stream to give a distillate stream, said condenser surface forming a non-permeable heat conducting separation wall between said distillate stream and a cooling stream which cooling stream is a) said feed stream or b) said retentate stream, so that heat can be transferred between the vapor and the cooling stream, wherein the distance between said membrane and said condenser surface is smaller than 10 mm, and wherein the vapor pressure of said distillate stream is lower than the vapor pressure of the compounds in the vaporizing stream for which the permeable non-porous selective membrane is selective, resulting in sufficient driving force for the separation to occur.

    摘要翻译： 本发明涉及分离液体混合物的方法和用于通过渗透蒸发分离液体混合物的装置。 本发明的方法包括：将液体混合物流通过可渗透的无孔选择性膜，所述膜对于所述第一和第二化合物中的至少一种是选择性的，由此至少部分物流通过所述膜 将所述膜的另一侧作为蒸气离开，其余部分形成滞留物流，并且将所述蒸气冷凝在具有比蒸发流低的温度的冷凝器表面上以产生馏出物流，所述冷凝器表面形成不可渗透的 所述馏出物流和冷却流之间的导热分隔壁是冷却流，a）所述进料流或b）所述渗余物流，使得热量可以在蒸气和冷却流之间传递，其中所述膜和所述 冷凝器表面小于10mm，并且其中所述馏出物流的蒸气压低于蒸汽中化合物的蒸气压 渗透性无孔选择性膜是选择性的，从而产生用于分离发生的足够的驱动力。

    PROCESS FOR THE RECOVERY OF ACIDS
    10.
    发明公开
    PROCESS FOR THE RECOVERY OF ACIDS 审中-公开
    一种获得ACID

    公开(公告)号：EP1825027A2

    公开(公告)日：2007-08-29

    申请号：EP05810796.2

    申请日：2005-11-18

    申请人： Nederlandse Organisatie voor Toegepast-Natuurwetenschappelijk Onderzoek TNO

    发明人： VAN ERKEL, Joost ,  GOETHEER, Earl Lawrence Vincent

    IPC分类号： C25B3/12 ,  C07C51/41

    CPC分类号： B01D11/0492

    摘要： The invention is directed to a process for recovering acids from mixtures containing them, in particular organic acids and amino acids, such as acids produced by fermentation in a fermentation broth. The process of the invention comprises contacting a loaded extractant with a solution containing hydroxide ions in the presence of at least one cathode and at least one anode, wherein said hydroxide ions are produced by using said cathode, whereby said acid is converted to its anionic form, by which it can be removed from said extractant and can migrate in the direction of the anode.