摘要:
The present invention provides novel polyacylurethane, and a process for producing the same. More specifically, the present invention provides polyacylurethane having a molecular weight of 500 to 50,000, wherein a main chain of said polyacylurethane is substantially composed of a repeating unit of the formula:
wherein R₁ represents an alkylene group or an alkenylene group having a molecular weight of 28 to 30,000, which may contain an alicyclic group, an aromatic group and/or an oxygen atom; and R₂ represents an alkylene group, an arylene group or an alkenylene group having 1 to 8 carbon atoms.
摘要翻译:本发明提供新颖的聚酰氨基甲酸酯及其制备方法。 更具体地说,本发明提供分子量为500〜50,000的聚酰氨基甲酸酯,其中所述多酰基氨基甲酸酯的主链基本上由下式的重复单元组成:其中R 1表示亚烷基或亚烯基, 分子量为28〜30,000,可以含有脂环族基团,芳香族基团和/或氧原子; R 2表示亚烷基,亚芳基或碳原子数1〜8的亚烯基。
摘要:
A method for handling and stabilizing a (2-alkyl)acryloyl isocyanate represented by formula (1) is disclosed, which comprises the steps of: reacting an azomethine compound represented by formula (2) with the (2-alkyl)acryloyl isocyanate to obtain a reaction product and dissolving the reaction product into a solvent to regenerate the (2-alkyl)acryloyl isocyanate;
wherein R¹ represents a hydrogen atom or a lower alkyl group,
wherein R² represents an alkyl group, a cycloalkyl group, an aralkyl group, an alkenyl group, or an alkynyl group, and R³ and R⁴ each represents a hydrogen atom or a group which does not cause tautomerism with C=N in the formula, provided that at least one of R³ and R⁴ is not a hydrogen atom, and further a method for producing a (2-alkyl)acryloyl isocyanate is disclosed, which comprises the step of: preparing a heterocyclic compound represented by formula (3) and dissolving the heterocyclic compound into a solvent;
wherein R¹ represents a hydrogen atom or a lower alkyl group,
wherein R⁵ represents a hydrogen atom or a lower alkyl group, R⁶ represents an alkyl group, a cycloalkyl group, an aralkyl group, an alkenyl group, or an alkynyl group, and R⁷ and R⁸ each represents a hydrogen atom or a group in which a carbon atom located in the α-position to carbon atoms constituting a heterocyclic ring does not have a hydrogen atom, provided that at least one of R⁷ and R⁸ is not a hydrogen atom.
摘要:
Quaternary ammonium salts of a non-nucleophilic anion having a heterocycle including the quarternary nitrogen atom are useful as a cation polymerization initiator having a heat latency. A variety of resinous compositions containing this initiator is also disclosed.
摘要:
The present invention provides a process for producing a variety of unsaturated carbamic acid derivatives from corresponding unsaturated carbamates by substitution reaction. The present invention provides a process for producing unsaturated carbamic acid derivatives, comprising reacting an unsaturated carbamate represented by
wherein R represents a hydrogen atom or an alkyl group having 1 to 8 carbon atoms, R¹ represents a residue of an alcohol from which an OH group is removed, with an alcohol, a primary or secondary amine or an oxime at a temperature of 80 to 150 °C to substitute the -OR¹ group in the formula (A).