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公开(公告)号：EP3081674A1
公开(公告)日：2016-10-19
申请号：EP14869821.0
申请日：2014-12-11
摘要： An electroplating apparatus (1) applies an electroplated coating to a female thread (20b) formed on a pipe end portion (20a) of a steel pipe (20). The electroplating apparatus (1) includes an inner seal member (2), a capsule (3), a discharge outlet (3c), an opening (3b), a cylindrical insoluble anode (4), a plating solution supply tube (5a), and a plurality of nozzles (5b). The inner seal member (2) divides the interior of the steel pipe (20) at a location longitudinally inward of a region on which the female thread is formed (20b). The capsule (3) is attached to the pipe end portion (20a). The discharge outlet (3c) is designed to discharge a plating solution inside the capsule (3) therefrom. The opening (3b) facilitates discharge of the plating solution inside the capsule (3). The anode (4) is disposed in the inside of the pipe end portion (20a). The supply tube (5a) projects from a leading end of the anode (4). The nozzles (5b) eject a plating solution between the outer peripheral surface of the anode (4) and the inner peripheral surface of the pipe end portion (20a). The anode (4) has a configuration that does not allow ingress of the plating solution thereto.
摘要翻译： 电镀设备（1）对形成在钢管（20）的管端部（20a）上的内螺纹（20b）施加电镀涂层。 电镀设备（1）包括内密封件（2），胶囊（3），排出口（3c），开口（3b），圆柱形不溶性阳极（4），电镀液供应管（5a） ，和多个喷嘴（5b）。 内密封构件（2）在形成有内螺纹的区域（20b）的纵向内侧的位置处将钢管（20）的内部分割。 胶囊（3）安装在管端部（20a）上。 排出口（3c）被设计成从其中排出胶囊（3）内的电镀液。 开口（3b）有助于电镀液在胶囊（3）内的排出。 阳极（4）设置在管端部（20a）的内部。 供应管（5a）从阳极（4）的前端伸出。 喷嘴（5b）在阳极（4）的外周面与管端部（20a）的内周面之间排出电镀液。 阳极（4）具有不允许电镀液进入其的构造。
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公开(公告)号：EP2868777B1
公开(公告)日：2016-10-05
申请号：EP13812612.3
申请日：2013-06-24
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3.发明公开PLATING SOLUTION FOR SCREWED PIPE JOINT AND PROCESS FOR PRODUCING SCREWED PIPE JOINT 审中-公开巴勒斯坦人民共和国劳德代尔堡
公开(公告)号：EP3144416A1
公开(公告)日：2017-03-22
申请号：EP15793121.3
申请日：2015-05-15
发明人： KIMOTO, Masanari , ISHII, Kazuya , GOTO, Kunio , YAMAMOTO, Tatsuya , OSHIMA, Masahiro , NAKAO, Seiichiro , YAMAGUCHI, Daisuke
摘要： Provided is a plating solution for a threaded connection for pipe or tube used for forming a plating film excellent in galling resistance, crevice corrosion resistance, and exposure corrosion resistance. The plating solution for a threaded connection for pipe or tube of the present embodiment contains no cyanide, but contains: a water-soluble copper salt; a water-soluble tin salt; a water-soluble bismuth salt; a free acid; and a thiourea-based compound of 10 g/L or less (excluding 0) that is represented by Chemical Formula (1):
X 1 X 2 N-C(=S)-NX 3 X 4 (1),
where each of X 1 , X 2 , X 3 , and X 4 is any one of hydrogen, an alkyl group, an allyl group, a tolyl group, or a group represented by Chemical Formula (2), but excluding that X 1 , X 2 , X 3 , and X 4 are all hydrogen:
-CH 2 -CH 2 -S-CH 2 -CH 2 -X 5 (2),
where X 5 is OH or NH 2 .摘要翻译： 本发明提供一种用于形成耐刮擦性，耐缝隙腐蚀性和耐暴露耐腐蚀性优异的电镀膜的管或管用螺纹连接用电镀液。 本实施方式的管道用螺纹连接用电镀液不含有氰化物，但含有水溶性铜盐， 水溶性锡盐; 水溶性铋盐; 游离酸 和化学式（1）表示的10g / L以下（不含0）的硫脲类化合物：ƒ€ƒ€ƒ€ƒ€ƒ€ƒX1 X 2 NC（= S ）-NX 3 X 4€ƒ€ƒ€ƒ€ƒ（1），其中X 1，X 2，X 3和X 4各自为氢，烷基，烯丙基， 甲苯基或化学式（2）表示的基团，但不包括X 1，X 2，X 3和X 4均为氢：ƒ€ƒ€ƒ€ƒ€ƒ€ƒ- CH 2 -CH 2 -S-CH 2 -CH 2 -X 5€ƒ€ƒ€ƒ€ƒ（2），其中X 5是OH或NH 2。
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4.发明公开PLATING SOLUTION FOR PIPE THREADED COUPLING AND MANUFACTURING METHOD FOR PIPE THREADED COUPLING 有权电镀工艺管道用于生产管螺纹连接螺纹连接和方法
公开(公告)号：EP3144415A1
公开(公告)日：2017-03-22
申请号：EP15792205.5
申请日：2015-05-15
发明人： KIMOTO, Masanari , ISHII, Kazuya , GOTO, Kunio , YAMAMOTO, Tatsuya , OSHIMA, Masahiro , NAKAO, Seiichiro , YAMAGUCHI, Daisuke
摘要： Provided is a plating solution for a threaded connection used for forming a plating film excellent in galling resistance, crevice corrosion resistance, and exposure corrosion resistance. The plating solution for a threaded connection of the present embodiment contains no cyanide, but contains copper pyrophosphate, tin pyrophosphate, zinc pyrophosphate, pyrophosphate as a metal complexing agent, and a sulfur-containing compound of 40 g/L or less (excluding 0). The sulfur-containing compound includes: a mercapto compound and a sulfide compound defined by Chemical Formula (1); a dimer formed through a disulfide bond of the mercapto compounds; and one or more types of salts thereof:
RS-(CHX 1 ) m -(CHX 2 ) n -CHX 3 X 4 (1),
where each of m and n is an integer of 1 or 0; each of X 1 , X 2 , X 3 and X 4 is any one of hydrogen, OH, NH 2 , SO 3 H, and CO 2 H, but excluding that X 1 , X 2 , X 3 , and X 4 are all hydrogen; and R is any one of hydrogen, a methyl group, and an ethyl group.摘要翻译： 提供了一种用于用于形成电镀膜，具有优异的耐磨损性，耐裂隙腐蚀性，和暴露耐腐蚀性的螺纹连接的镀覆溶液。 对于本实施例的螺纹连接的电镀液不包含氰化，但包含焦磷酸铜，焦磷酸锡，焦磷酸锌，焦磷酸盐作为金属络合剂，和40克/升或更少（不包括0）含硫化合物 ， 含硫化合物包括：巯基化合物和由化学式（1）定义的硫醚化合物; 通过巯基化合物的二硫键形成的二聚体; 和一种或多种类型的盐或其：€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒRS-（CHX 1）M - （CX 2）n的CHX 3 X 4€ƒ€ƒ€ƒ€ƒ €ƒ（1），其中每个m和n是1或0的整数; 每个X 1，X 2，X 3和X 4为氢的任一项，OH，NH 2，SO 3 H，和CO 2 H，但不包括没有X 1，X 2，X 3和X 4都是 氢; 且R为氢时的任何一种，甲基，和乙基。
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5.发明授权CURVED METALLIC MATERIAL AND PROCESS FOR PRODUCING SAME 有权GEKRÜMMTESMETALLISCHES MATERIAL UND VERFAHREN ZU SEINER HERSTELLUNG
公开(公告)号：EP2390018B1
公开(公告)日：2016-11-16
申请号：EP10733490.6
申请日：2010-01-20
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公开(公告)号：EP3425089A1
公开(公告)日：2019-01-09
申请号：EP17760129.1
申请日：2017-03-02
摘要： An electroplating apparatus is provided that minimizes unplated regions when an alloy plating layer is provided on the surface of a thread on a steel pipe. An electroplating apparatus (10) includes an electrode (1), sealing members (2, 3), and a plating-solution supply unit (4). The electrode (1) faces the thread (Tm). The sealing member (2) is positioned within the steel pipe (P1). The sealing member (3) is attached to the end portion of the steel pipe (P1) and, together with the sealing member (2), forms a receiving space (8). The plating-solution supply unit (4) includes a plurality of nozzles (42). The nozzles (42) are positioned within the receiving space (8) and adjacent one end of the thread (Tm) and arranged around the pipe axis of the steel pipe (P1). The plating-solution supply unit (4) injects a plating solution between the thread (Tm) and electrode (1) through the nozzles (42). The direction in which plating solution is injected from the nozzles (42) is inclined at an angle larger than 20 degrees and smaller than 90 degrees toward the thread (Tm) relative to a plane perpendicular to the pipe axis.
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公开(公告)号：EP3081674B1
公开(公告)日：2018-03-28
申请号：EP14869821.0
申请日：2014-12-11
摘要： An electroplating apparatus (1) applies an electroplated coating to a female thread (20b) formed on a pipe end portion (20a) of a steel pipe (20). The electroplating apparatus (1) includes an inner seal member (2), a capsule (3), a discharge outlet (3c), an opening (3b), a cylindrical insoluble anode (4), a plating solution supply tube (5a), and a plurality of nozzles (5b). The inner seal member (2) divides the interior of the steel pipe (20) at a location longitudinally inward of a region on which the female thread is formed (20b). The capsule (3) is attached to the pipe end portion (20a). The discharge outlet (3c) is designed to discharge a plating solution inside the capsule (3) therefrom. The opening (3b) facilitates discharge of the plating solution inside the capsule (3). The anode (4) is disposed in the inside of the pipe end portion (20a). The supply tube (5a) projects from a leading end of the anode (4). The nozzles (5b) eject a plating solution between the outer peripheral surface of the anode (4) and the inner peripheral surface of the pipe end portion (20a). The anode (4) has a configuration that does not allow ingress of the plating solution thereto.
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8.发明授权
公开(公告)号：EP2248927B1
公开(公告)日：2015-07-08
申请号：EP09705046.2
申请日：2009-01-26
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公开(公告)号：EP2868777A1
公开(公告)日：2015-05-06
申请号：EP13812612.3
申请日：2013-06-24
摘要： An electro plating device includes a pipe inside seal mechanism which occludes an inner channel of a steel pipe,a tubular insoluble electrode which is disposed in a pipe end so as to be opposite to a female screw, a plating solution feed mechanism which includes a plurality of nozzles which extend radially with a pipe axis of the steel pipe as a center, and a pipe end seal mechanism which accommodates the nozzles thereinside and is mounted to the pipe end, when viewed in the pipe axial direction, a tip of each of the nozzles is positioned between the female screw and the insoluble electrode, and each of the nozzles injects the plating solution toward a direction which intersects an extension direction of the nozzle, the direction being a rotational direction of a clockwise direction or a counterclockwise direction in which the pipe axis is the center.
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