摘要:
A process is described for the contemporaneous preparation of mesitylene and durene, characterized in that mesitylene and durene are obtained exclusively starting from pseudo-cumene without the use of any further chemical compound, operating in continuous, at a temperature ranging from 210 to 400°C, at a pressure ranging from 1 to 50 bar, with a weight space velocity ranging from 0.1 to 20 hours -1 and in the presence of a catalyst based on crystalline metal-silicates in acid form. After the recovery of mesitylene and durene from the reaction raw product, some of the remaining components of the raw product itself are recycled and fed to the reactor together with the pseudo-cumene.
摘要:
A process is described for the contemporaneous preparation of mesitylene and durene, characterized in that mesitylene and durene are obtained exclusively starting from pseudo-cumene without the use of any further chemical compound, operating in continuous, at a temperature ranging from 210 to 400°C, at a pressure ranging from 1 to 50 bar, with a weight space velocity ranging from 0.1 to 20 hours -1 and in the presence of a catalyst based on crystalline metal-silicates in acid form. After the recovery of mesitylene and durene from the reaction raw product, some of the remaining components of the raw product itself are recycled and fed to the reactor together with the pseudo-cumene.
摘要:
A process is described for the synthesis of mesitylene, characterized in that mesitylene is obtained starting exclusively from pseudocumene, without the use of any other chemical compound, operating in continuous, at a temperature ranging from 225 to 400°C, at a pressure ranging from 1 to 50 bar, at a weight space velocity ranging from 0.1 to 10 hours -1 , and in the presence of a catalyst containing a zeolite selected from ZSM-5 zeolite having a crystal lattice based on silicon oxide and aluminum oxide, and ZSM-5 zeolite modified by the partial or total substitution of Si with a tetravalent element such as Ti or Ge and/or the partial or total substitution of Al with other trivalent elements, such as Fe, Ga or B.
摘要:
The present invention relates to a process for the transalkylation of hydrocarbons in the presence of a new zeolite having a beta-type crystalline structure, characterized by a distribution of the Lewis acid sites and Brønsted acid sites corresponding to a molar ratio [Lewis sites]/[Brønsted sites] equal to or higher than 1.5. This new zeolite is useful in preparation processes of alkylated aromatic hydrocarbons through the transalkylation of aromatic compounds. The preparation method of the new zeolite is also object of the present invention.
摘要:
A process is described for the preparation of phenol by the selective hydroxylation of benzene under depletive conditions, characterized in that the above-mentioned reactions are carried out in the presence of a catalyst based on multicomponent metal oxides comprising at least one metal selected from the groups VB, VIB, VIII, IB, IIB, IVA, VA.
摘要:
The present invention relates to a new zeolite having a beta-type crystalline structure, characterized by a distribution of the Lewis acid sites and Brønsted acid sites corresponding to a molar ratio [Lewis sites]/[Brønsted sites] equal to or higher than 1.5. This new zeolite is useful in preparation processes of alkylated aromatic hydrocarbons through the alkylation and/or transalkylation of aromatic compounds. The preparation method of the new zeolite is also object of the present invention.