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12 条记录 (耗时 0.01 秒)

    Process for the production of mesitylene
    1.
    发明公开
    Process for the production of mesitylene 审中-公开
    生产均三甲苯的方法

    公开(公告)号：EP1452513A2

    公开(公告)日：2004-09-01

    申请号：EP04075564.7

    申请日：2004-02-23

    申请人： Polimeri Europa S.p.A. ,  ENITECNOLOGIE S.p.A.

    发明人： Dalloro, Leonardo ,  Cesana, Alberto ,  Buzzoni, Roberto ,  Rivetti, Franco ,  Fois, Giovanni Antonio ,  Rizzo Caterina ,  Arrigoni Virginio

    IPC分类号： C07C5/27 ,  C07C15/02 ,  B01J29/90

    CPC分类号： C07C5/2737 ,  C07C2529/40 ,  C07C15/02

    摘要： A process is described for the synthesis of mesitylene, characterized in that mesitylene is obtained starting exclusively from pseudocumene, without the use of any other chemical compound, operating in continuous, at a temperature ranging from 225 to 400°C, at a pressure ranging from 1 to 50 bar, at a weight space velocity ranging from 0.1 to 10 hours -1 , and in the presence of a catalyst containing a zeolite selected from ZSM-5 zeolite having a crystal lattice based on silicon oxide and aluminum oxide, and ZSM-5 zeolite modified by the partial or total substitution of Si with a tetravalent element such as Ti or Ge and/or the partial or total substitution of Al with other trivalent elements, such as Fe, Ga or B.

    摘要翻译： 描述了一种合成均三甲苯的方法，其特征在于，在没有使用任何其它化学化合物的情况下，仅从假枯烯开始，在225-400℃的温度范围内，在从 1至50巴，重量空速为0.1至10小时-1，并且在含有选自具有基于氧化硅和氧化铝的晶格的ZSM-5沸石的沸石和ZSM- 5分子筛，其通过Si与四价元素如Ti或Ge的部分或全部取代和/或Al与其它三价元素如Fe，Ga或B的部分或全部取代来改性。

    Process for the production of mesitylene and durene
    3.
    发明公开
    Process for the production of mesitylene and durene 审中-公开
    生产均三甲苯和杜烯的方法

    公开(公告)号：EP1460051A2

    公开(公告)日：2004-09-22

    申请号：EP03079068.7

    申请日：2003-12-15

    申请人： Polimeri Europa S.p.A. ,  Enitechnologie S.p.A.

    发明人： Dalloro, Leonardo ,  Cesana, Alberto ,  Buzzoni, Roberto ,  Rivetti, Franco ,  Rizzo, Caterina ,  Arrigoni, Virginio ,  Perego, Carlo

    IPC分类号： C07C5/27 ,  C07C6/12

    CPC分类号： C07C6/123 ,  C07C5/2737 ,  C07C15/02

    摘要： A process is described for the contemporaneous preparation of mesitylene and durene, characterized in that mesitylene and durene are obtained exclusively starting from pseudo-cumene without the use of any further chemical compound, operating in continuous, at a temperature ranging from 210 to 400°C, at a pressure ranging from 1 to 50 bar, with a weight space velocity ranging from 0.1 to 20 hours -1 and in the presence of a catalyst based on crystalline metal-silicates in acid form. After the recovery of mesitylene and durene from the reaction raw product, some of the remaining components of the raw product itself are recycled and fed to the reactor together with the pseudo-cumene.

    摘要翻译： 描述了同时制备均三甲苯和均四甲苯的方法，其特征在于均三甲苯和均四甲苯由纯假异丙苯开始而不使用任何其它化学化合物，在210-400℃的温度下连续操作 在1-50巴的压力下，重量空速为0.1-20小时-1，并且在基于酸形式的结晶金属硅酸盐的催化剂存在下进行。 从反应粗产物中回收均三甲苯和杜烯后，粗产物本身的一些剩余组分被再循环并与假枯烯一起进料到反应器中。

    Integrated process for the preparation of phenol from benzene with recycling of the by-products
    4.
    发明公开
    Integrated process for the preparation of phenol from benzene with recycling of the by-products 有权
    用于生产苯酚的苯与再循环的综合方法的副产物

    公开(公告)号：EP1424320A1

    公开(公告)日：2004-06-02

    申请号：EP03078648.7

    申请日：2003-11-20

    申请人： Polimeri Europa S.p.A.

    发明人： Bianchi, Daniele ,  Bortolo, Rossella ,  Buzzoni, Roberto ,  Cesana, Alberto ,  Dalloro, Leonardo ,  D'Aloisio, Rino

    IPC分类号： C07C37/60 ,  C07C39/04

    CPC分类号： C07C37/60 ,  B01J29/89 ,  B01J2229/30 ,  Y02P20/125 ,  Y02P20/52 ,  C07C39/04

    摘要： The invention relates to a process for the preparation of phenol comprising the following phases:

    1) preparation in continuous of phenol by means of the direct oxidation of benzene with hydrogen peroxide operating with an H 2 O 2 /benzene ratio ranging from 10 to 70%, in a three-phase reaction system comprising a first liquid phase consisting of benzene and an organic solvent, a second liquid phase consisting of water, a solid phase consisting of an activated catalyst based on titanium silicalite TS-1;
    2) separation of the phenol and non-reacted benzene from the reaction mixture of the oxidation section (1), by means of fractionated distillation;
    3) separation of the solvent and by-products from the mixture coming from the distillation tail (2), by means of basic extraction;
    4) transformation of the by-products obtain in section (3) to phenol by means of hydrodeoxygenation with hydrogen operating in continuous, in aqueous solution, at a temperature ranging from 250 to 500°C, at pressures of 1-100 bar and in the presence of a catalyst based on elements of group VIB or their mixtures or group VIII of the periodic table or their mixtures;
    5) recycling of the phenol obtained in section (4) to the distillation section (2).

    摘要翻译： 本发明涉及一种用于苯酚的制备，其包括以下阶段：1）在连续的苯酚制备通过与过氧化氢与H 2 O 2 /苯比从10到70％范围内操作苯的直接氧化的手段，在 包含第一液体相由苯和溶剂有机三相反应系统中，第二液相由水，基于钛硅酸盐精简版TS-1的固相选自由活化的催化剂; 2）从氧化段（1）通过分馏的装置的反应混合物中的苯酚和未反应的苯的分离; 3）中的溶剂和副产物从混合物从蒸馏尾部（2）的到来，通过碱性萃取的手段分离; 4）的副产物的转化中获得部分（3）通过苯酚与连续操作氢，在wässrige溶液中，在以在1-100巴的压力和250至500℃的温度下加氢脱氧手段 一催化剂的存在下根据第VIB族或它们的混合物或周期表或它们的混合物的第VIII族元素; 5）在第（4）中得到的蒸馏段的苯酚再循环（2）。

    Process for the preparation of MFI-Type zeolitic catalysts
    5.
    发明公开
    Process for the preparation of MFI-Type zeolitic catalysts 有权
    Verfahren zur Herstellung von Zeolithkatalysatoren des MFI-Typs

    公开(公告)号：EP1314475A1

    公开(公告)日：2003-05-28

    申请号：EP02079730.4

    申请日：2002-11-13

    申请人： Polimeri Europa S.p.A.

    发明人： Balducci, Luigi ,  Dalloro, Leonardo ,  Cesana, Alberto ,  Buzzoni, Roberto

    IPC分类号： B01J29/40 ,  B01J29/04 ,  B01J29/06 ,  C07C231/10

    CPC分类号： B01J29/035 ,  B01J29/40 ,  B01J37/0072 ,  B01J37/033 ,  B01J2229/42

    摘要： The present invention relates to a process for the preparation of zeolitic catalysts of the MFI type in spheroidal form.
    The process consists in emulsifying and consolidating in paraffinic hydrocarbons, in the presence of a non-ionic surface-active agent or a suitable combination of a non-ionic surface-active agent and a cationic surface-active agent, a dispersion of particles of zeolitic material of the MFI type in a silica sol.

    摘要翻译： 本发明涉及一种以球形形式制备MFI型沸石催化剂的方法。 该方法包括在非离子表面活性剂或非离子表面活性剂和阳离子表面活性剂的合适组合的存在下在链烷烃中乳化和固结，沸石颗粒的分散体 二氧化硅溶胶中MFI型材料。