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公开(公告)号：EP2327729B1
公开(公告)日：2017-11-29
申请号：EP10197468.1
申请日：2003-03-04
IPC分类号： C08F30/02 , C09D143/02
CPC分类号： C09D143/02 , C08F30/02 , C09D133/04
摘要： A polymer composition is provided including copolymer particles bearing phosphorus acid groups dispersed in an aqueous medium, wherein the polymer composition is substantially-free of water soluble phosphorus acid compounds. Also provided is a monomer composition containing at least one phosphorus acid monomer and a method of preparing the polymer composition from the monomer composition. The monomer composition is substantially-free of inorganic phosphorus acid compounds. A method is provided for applying the polymer composition to a substrate. The polymer composition is useful as a coating composition to prepare coatings for metal substrates, which have improved solvent resistance.
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公开(公告)号：EP0810246B1
公开(公告)日：2004-07-28
申请号：EP97303350.9
申请日：1997-05-16
CPC分类号： C08G18/6225 , C08G18/6254 , C08G18/6266 , C08G2170/80
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公开(公告)号：EP1010706A3
公开(公告)日：2000-08-30
申请号：EP99309772.4
申请日：1999-12-06
发明人： Greenblatt, Gary David , Lange, Barry Clifford , Bowe, Michael Damian , Merritt, Richard Foster , Wilczynski, Robert , Larson, Gary Robert , Petrovich, Lori Marie , Whitman, David William
CPC分类号： C07C43/196 , C07C67/347 , C07C2603/68 , C08F2/02 , C08F2/18 , C08F20/04 , C08F290/046 , C08F2220/281 , C08K5/0016 , C08K5/0025 , C08L21/00 , C08L101/00 , C11D3/3757 , C08L2666/02 , C08L2666/04 , C07C69/604
摘要： A continuous process for oligomers which do not contain, as polymerized units, carboxylic acid-containing monomers and their salts, including the steps of: (1) forming a reaction mixture, substantially free of carboxylic acid-containing monomers and their salts, containing:(i) 0.5 to 99.95% by weight of the reaction mixture of at least one ethylenically unsaturated monomer; and(ii) 0.05 to 25% by weight, based on the weight of the ethylenically unsaturated monomer, of at least one free-radical initiator; and (2) continuously passing the reaction mixture through a heated zone wherein the reaction mixture is maintained at a temperature of at least 150°C and a pressure of at least 30 bars for from 0.1 seconds to 4 minutes to form terminally-unsaturated oligomers. In addition, processes for forming oligomers of vinyl acetate and oligomers of vinyl alcohol are disclosed. Mixtures of fully saturated and terminally unsaturated oligomers are also disclosed.
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公开(公告)号：EP0718380A2
公开(公告)日：1996-06-26
申请号：EP95308364.9
申请日：1995-11-22
发明人： Gebhard, Matthew Stewart , Devry, William Edward , Puschak, Caren Ann , Bacho, Anne Margaret , Larson, Gary Robert
IPC分类号： C09D5/06 , C09D133/06 , C09D175/04 , C09D201/00
CPC分类号： C09D133/06 , C08G18/10 , C08G18/4833 , C08L75/04 , C09D5/06 , Y10S524/902 , C08G18/283 , C08G18/2825 , C08L2666/02 , C08L2666/54 , C08L2666/14
摘要： The composition having wet state clarity includes an aqueous latex binder combination of polymer particles with a diameter of less than 80 nanometers and a thickener. When glitter flakes are dispersed in these novel compositions in their wet state, they glitter more than conventional glitter compositions. Thus, they are more appealing to a consumer or an artist than conventional glitter compositions that tend to be cloudy or dull in their wet state.
摘要翻译： 具有湿态澄清度的组合物包括直径小于80纳米的聚合物颗粒和增稠剂的含水胶乳粘合剂组合。 当闪光片以湿态分散在这些新型组合物中时，它们比传统的闪光组合物更闪亮。 因此，与传统的闪光组合物相比，它们对消费者或艺术家更具吸引力，而传统的闪光组合物在潮湿状态下倾向于混浊或无光泽。
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公开(公告)号：EP0676430A3
公开(公告)日：1996-06-05
申请号：EP95300970.1
申请日：1995-02-15
IPC分类号： C08G18/62 , C08G18/70 , C08F220/26 , C09D175/00
CPC分类号： C08G18/792 , C08G18/62 , C08G18/6225 , C08G18/706
摘要： A waterborne coating composition containing an aqueous dispersion of a polymerr bearing at least two active methylene groups and being substantially free from hydroxyl, primary amino, and secondary amino groups, and an aqueous dispersion of a polyisocyanate bearing at least two isocyanate groups is provided. Also provided is a method of improving the chemical resistance of a coating and a substrate coated with the waterborne coating composition.
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6.发明公开Method for reducing microfoam in a spray-applied waterborne thermoset composition 失效一种用于减少在水性热固性微泡沫方法喷雾的组合物
公开(公告)号：EP0694337A1
公开(公告)日：1996-01-31
申请号：EP95304516.8
申请日：1995-06-27
CPC分类号： B05D1/02 , C08F8/44 , C08F8/30 , C08F2220/1825 , C08F220/14
摘要： A method for reducing the amount of microfoam in a spray-applied clear waterborne thermoset composition is provided. The clear composition comprises an emulsion-polymerized addition polymer or a multi-staged emulsion-polymerized addition polymer with an average particle diameter greater than 120 nanometers and bearing at least two first reactive groups, and a reactive modifier bearing at least two reactive groups. The clear composition is spray-applied to a substrate and cured. Also provided are substrates bearing such spray-applied clear compositions and the emulsion-polymerized addition polymer.
摘要翻译： 本发明提供一种用于减少在喷涂的透明含水热固性组合物中微泡的量的方法。 将澄清的组合物的乳液聚合的加成聚合物或具有平均粒径大于120纳米米的多级乳液聚合加成聚合物与带有至少两个一级反应基，和反应性改性剂带有至少两个反应性基团的包括。 所述透明的组合物进行喷雾应用到基材和固化。 所以提供寻求喷涂的透明组合物和乳液聚合的加成聚合物基材轴承。
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公开(公告)号：EP1270687A3
公开(公告)日：2003-10-01
申请号：EP02254328.4
申请日：2002-06-20
发明人： Rosano, William Joseph , Larson, Gary Robert , Procopio, Leo Joseph , Dager, Albert Mulligan , Greenblatt, Gary David
CPC分类号： B82Y30/00 , C01P2002/84 , C01P2004/03 , C01P2004/20 , C01P2004/32 , C01P2004/38 , C01P2004/51 , C01P2004/61 , C01P2004/62 , C01P2004/64 , C01P2004/84 , C01P2006/33 , C01P2006/60 , C08F230/02 , C08K3/22 , C08K9/12 , C08L41/00 , C08L43/02 , C09C1/3669 , C09C1/3676 , C09C1/3684 , C09C1/3692 , C09D7/62 , C09D133/02
摘要： An aqueous composite particle composition containing composite particles and polyvalent metal ion is provided. The composite particles contain pigment particle with adsorbed polymer particles. The polymer particles contain pendant acid functional groups and has a molecular weight in a select range. Also provided are methods of preparing the aqueous composite particle composition. The aqueous composite particle composition is useful for preparing coating with high gloss and improved solvent resistance.
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8.发明授权Method for reducing microfoam in a spray-applied waterborne thermoset composition 失效一种用于微泡的水性热固性还原过程喷雾的组合物
公开(公告)号：EP0694337B2
公开(公告)日：2003-06-11
申请号：EP95304516.8
申请日：1995-06-27
CPC分类号： B05D1/02 , C08F8/44 , C08F8/30 , C08F2220/1825 , C08F220/14
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公开(公告)号：EP1270687A2
公开(公告)日：2003-01-02
申请号：EP02254328.4
申请日：2002-06-20
发明人： Rosano, William Joseph , Larson, Gary Robert , Procopio, Leo Joseph , Dager, Albert Mulligan , Greenblatt, Gary David
CPC分类号： B82Y30/00 , C01P2002/84 , C01P2004/03 , C01P2004/20 , C01P2004/32 , C01P2004/38 , C01P2004/51 , C01P2004/61 , C01P2004/62 , C01P2004/64 , C01P2004/84 , C01P2006/33 , C01P2006/60 , C08F230/02 , C08K3/22 , C08K9/12 , C08L41/00 , C08L43/02 , C09C1/3669 , C09C1/3676 , C09C1/3684 , C09C1/3692 , C09D7/62 , C09D133/02
摘要： An aqueous composite particle composition containing composite particles and polyvalent metal ion is provided. The composite particles contain pigment particle with adsorbed polymer particles. The polymer particles contain pendant acid functional groups and has a molecular weight in a select range. Also provided are methods of preparing the aqueous composite particle composition. The aqueous composite particle composition is useful for preparing coating with high gloss and improved solvent resistance.
摘要翻译： 提供含有复合粒子和多价金属离子的水性复合粒子组合物。 复合颗粒含有吸附聚合物颗粒的颜料颗粒。 聚合物颗粒含有侧链酸官能团并具有选择范围内的分子量。 还提供了制备水性复合颗粒组合物的方法。 水性复合颗粒组合物可用于制备具有高光泽度和改进的耐溶剂性的涂层。
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公开(公告)号：EP0687690B1
公开(公告)日：2001-09-05
申请号：EP95303941.9
申请日：1995-06-08
发明人： Freeman, Michael Bennett , Larson, Gary Robert , Merritt, Richard Foster , Paik, Yi Hyon , Shulman, Jan Edward , Swift, Graham , Wilczynski, Robert
IPC分类号： C08F2/38 , C08F220/04 , C11D3/37
CPC分类号： C11D3/3788 , C08F2/18 , C08F20/04 , C08F220/06 , C08F290/046 , C11D3/3757
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