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    Pesticidal compounds
    1.
    发明公开
    Pesticidal compounds 失效
    的杀虫化合物。

    公开(公告)号：EP0622370A3

    公开(公告)日：1995-03-08

    申请号：EP94111438.1

    申请日：1988-07-21

    申请人： ROUSSEL UCLAF

    发明人： Weston, John Bernard ,  Larkin, John Patrick ,  Smith, Ian Harold

    IPC分类号： C07D493/08 ,  C07D495/08 ,  C07D497/08 ,  A01N43/90 ,  C07D305/06 ,  C07D305/08 ,  C07C323/12

    CPC分类号： C07D493/08 ,  A01N43/90 ,  A01N47/06 ,  A01N47/48 ,  A01N55/00 ,  A01N55/04 ,  C07C321/04 ,  C07D305/06 ,  C07D305/08 ,  C07D495/08 ,  C07D497/08

    摘要： New compounds of the formula (I):

    wherein R is a C 2-10 non-aromatic hydrocarbyl group optionally substituted by, or a methyl group substituted by cyano, halo, C 1-4 alkoxy optionally substituted by halo, or a group S(O) m R 3 , or R is phenyl optionally substituted by C 1-4 alkoxy, C 1-3 alkyl, C 2 - 4 alkynyl, halo, C 1-4 haloalkyl, cyano or a group S(O) m R 3 ;
    R 1 and R 2 may be the same or different, and each is hydrogen, halo, or a C 1 - 3 aliphatic group optionally substituted by halo, cyano, C 1-5 carbalkoxy, C 1-4 alkoxy, or a group S(O) m' R 4 , or R 1 and R and the carbon atoms to which they are attached form a C 5-7 carbocyclic ring optionally substituted by halo, or a C 1-3 aliphatic or alkoxy group; A is a C 5-8 non-aromatic hydrocarbyl group which contains one hetero atom selected from oxygen or sulphur and terminates in a C=C fragment adjacent to X; X is hydrogen; Y and Y1 are the same or different and are each selected from oxygen and S(O) n' and Z is CH 2 0 or CH 2 S-(O)n";
    the methods for their preparation, the compositions containing them and their use in the control of pests.

    Pesticidal compounds
    2.
    发明公开
    Pesticidal compounds 失效
    Pestizide Verbindungen。

    公开(公告)号：EP0622370A2

    公开(公告)日：1994-11-02

    申请号：EP94111438.1

    申请日：1988-07-21

    申请人： ROUSSEL UCLAF

    发明人： Weston, John Bernard ,  Larkin, John Patrick ,  Smith, Ian Harold

    IPC分类号： C07D493/08 ,  C07D495/08 ,  C07D497/08 ,  A01N43/90 ,  C07D305/06 ,  C07D305/08 ,  C07C323/12

    CPC分类号： C07D493/08 ,  A01N43/90 ,  A01N47/06 ,  A01N47/48 ,  A01N55/00 ,  A01N55/04 ,  C07C321/04 ,  C07D305/06 ,  C07D305/08 ,  C07D495/08 ,  C07D497/08

    摘要： New compounds of the formula (I):

    wherein R is a C 2-10 non-aromatic hydrocarbyl group optionally substituted by, or a methyl group substituted by cyano, halo, C 1-4 alkoxy optionally substituted by halo, or a group S(O) m R 3 , or R is phenyl optionally substituted by C 1-4 alkoxy, C 1-3 alkyl, C 2 - 4 alkynyl, halo, C 1-4 haloalkyl, cyano or a group S(O) m R 3 ;

    R 1 and R 2 may be the same or different, and each is hydrogen, halo, or a C 1 - 3 aliphatic group optionally substituted by halo, cyano, C 1-5 carbalkoxy, C 1-4 alkoxy, or a group S(O) m' R 4 , or R 1 and R and the carbon atoms to which they are attached form a C 5-7 carbocyclic ring optionally substituted by halo, or a C 1-3 aliphatic or alkoxy group;
    A is a C 5-8 non-aromatic hydrocarbyl group which contains one hetero atom selected from oxygen or sulphur and terminates in a C=C fragment adjacent to X;
    X is hydrogen;
    Y and Y1 are the same or different and are each selected from oxygen and S(O) n' and Z is CH 2 0 or CH 2 S-(O)n";

    the methods for their preparation, the compositions containing them and their use in the control of pests.

    摘要翻译： 式（I）的新化合物：其中R是任选被氰基取代的或被氰基取代的甲基，被任选被卤素取代的C 1-4烷氧基取代的C 2-10非芳族烃基或基团 S（O）m R 3或R为任选被C 1-4烷氧基，C 1-3烷基，C 2-4炔基，卤素，C 1-4卤代烷基，氰基或S（O）m R 3基团取代的苯基。 ; R 1和R 2可以相同或不同，各自为氢，卤素或任选被卤素，氰基，C 1-5烷氧基，C 1-4烷氧基或基团取代的C 1-3脂族基 S（O）m'R 4或R 1和R 1和它们所连接的碳原子形成任选被卤素取代的C 5-7碳环或C 1-3脂族或烷氧基; A是一个C5-8非芳族烃基，其含有一个选自氧或硫的杂原子，并终止于邻近X的C IDENTICAL C片段; X是氢; Y和Y1相同或不同，各自选自氧和S（O）n'，Z是CH 2 O或CH 2 S（O）n“; 其制备方法，含有它们的组合物及其在控制害虫中的用途。

    Pesticidal compounds
    3.
    发明公开
    Pesticidal compounds 失效
    杀虫剂化合物

    公开(公告)号：EP0243184A2

    公开(公告)日：1987-10-28

    申请号：EP87303585.1

    申请日：1987-04-23

    申请人： ROUSSEL-UCLAF

    发明人： Black, Malcolm Henry ,  Wyatt, John Anthony ,  Weston, John Bernard ,  Larkin, John Patrick ,  Smith, Ian Harold ,  Pulman, David Allen

    IPC分类号： C07D491/08 ,  C07F7/08 ,  A01N43/90 ,  C07D405/12

    CPC分类号： C07D405/12 ,  A01N43/90 ,  A01N47/16 ,  A01N55/00 ,  C07D491/08

    摘要： Pesticidal bicyclo-octanes are of the formula
    where R is a substituted or unsubstituted aliphatic or aromatic group, R' and R 3 are H or a substituted or unsubstituted aliphatic or aromatic group, R 2 is a substituted or unsubstituted heterocyclic group containing at least one ring nitrogen and is preferably a 3- or 4-pyridyl group, Z is CH 2 CH 2 , CH 2 O-CH 2 S or COCH 2 or CH(OR 5 )CH 2 where R 5 is H, alkyl, acyl or carbamoyl at Y and Y' are O or S(O)m where m is 0, 1 or 2.
    Various methods for their preparation are described.

    摘要翻译： 杀虫双环辛烷具有下式其中R是取代或未取代的脂族或芳族基团，R'和R3是H或取代或未取代的脂族或芳族基团，R2是取代或未取代的含至少一个环氮的杂环基 并且优选是3-或4-吡啶基，Z是CH 2 CH 2，CH 2 O-CH 2 S或COCH 2或CH（OR 5）CH 2，其中在Y和Y'处R5是H，烷基，酰基或氨基甲酰基是O或S（O）m 其中m是0,1或2.描述了其制备的各种方法。

    Pesticidal compounds
    6.
    发明公开
    Pesticidal compounds 失效
    Pestizide Verbindungen。

    公开(公告)号：EP0380312A1

    公开(公告)日：1990-08-01

    申请号：EP90300721.9

    申请日：1990-01-23

    申请人： ROUSSEL-UCLAF ,  THE REGENTS OF THE UNIVERSITY OF CALIFORNIA

    发明人： Larkin, John Patrick ,  Weston, John Bernard ,  Smith, Ian Harold ,  Palmer, Christopher John ,  Casida, John Edward

    IPC分类号： C07D493/08 ,  C07D497/08 ,  A01N43/32 ,  A61K31/335

    CPC分类号： C07D493/08 ,  A01N43/90 ,  A01N55/00 ,  C07D495/08 ,  C07D497/08

    摘要： The present invention provides novel compounds of the formula (I):
    wherein R is a phenyl group, substituted by 1 to 5 fluorine atoms and optionally substituted at the para position by methyl or chloro or R is a group
    being a three of four membered ring, where R⁴ is oxygen or a group CR⁷R⁸ wherein groups R⁷, R⁸ are the same or different and each is hydrogen, fluoro, chloro or bromo or methyl or ethyl optionally substituted by 1 to 3 fluoro atoms, and when
    is a three-membered ring R⁵ is a group CR 7a R 8a wherein R 7a , R 8a are the same or different and each is hydrogen, fluoro, chloro or bromo or methyl or ethyl optionally substituted by 1 to 3 fluoro atoms, or when
    is a four membered ring R⁵ is a group CR 7a R 8a CR⁹R¹⁰ wherein R 7a , R 8a are as hereinbefore defined and R⁹ and R¹⁰ are the same or different and each is hydrogen, fluoro, chloro or bromo or methyl or ethyl optionally substituted by 1 to 3 fluoro atoms; R⁶ is hydrogen, fluoro, chloro or methyl;
    R¹ and R² may be the same or different, and each is hydrogen, halo, or a C₁₋₃ aliphatic group optionally substituted by halo, cyano, C₂₋₅ carbalkoxy, C₁₋₄ alkoxy, or a group S(O) m R¹¹ wherein m is 0, 1 or 2 and R¹¹ is C₁₋₄ alkyl; cyano, gem dimethyl, or C₂₋₅ carbalkoxy; R³ contains between 3 and 18 carbon atoms and is a group R¹² wherein R¹² is a C₁₋₁₃ non-aromatic hydrocarbyl group, optionally substituted by a C₂₋₄ carbalkoxy or cyano group and/or by one or two hydroxy groups and/or by one to five halo atoms which are the same or different and/or by one to three groups R¹³ which are the same or different and each contains one to four hetero atoms, which are the same or different and are chosen from oxygen, sulphur, nitrogen and silicon, 1 to 10 carbon atoms and optionally 1 to 6 fluoro or chloro atoms or R³ is a 6-membered aromatic ring substituted by cyano and/or by one to five halo atoms and/or by one to three C₁₋₄ haloalkyl groups and/or by a group -C≡CH, C≡C-halo or -C≡C-R¹² wherein R¹² is as hereinbefore defined or -C≡C-R¹⁴ wherein R¹⁴ is a group S(O) q R¹⁵ wherein R¹⁵ is methyl, ethyl or trifluoromethyl or R¹⁴ is SiR¹⁶R¹⁷R¹⁸ wherein R¹⁶ and R¹⁷ are the same or different and are each C₁₋₄ aliphatic groups and R¹⁸ is a C₁₋₄ aliphatic group or phenyl provided that R¹⁶, R¹⁷ and R¹⁸ do not contain more than 10 carbon atoms in total; and Y, Y¹ and Y² are the same or different and are each selected from oxygen and S(O) t where t is 0, 1 or 2, processes for their preparation, formulations containing them and their use in controlling pest infestation.

    摘要翻译： 本发明提供新的式（I）化合物：其中R为苯基，被1至5个氟原子取代，并且在对位被甲基或氯取代，或R为基团CHEM 其中R 4为氧或基团CR 7 R 8，其中基团R 7，R 8相同或不同，各自为氢，氟，氯或 溴或甲基或乙基，其任选被1至3个氟原子取代，当为三元环时，R 5为基团CR 7a R 8a，其中R 7a，R 8a， 各自为氢，氟，氯或溴或任选被1至3个氟原子取代的甲基或乙基，或当为四元环时R 5为基团CR 7a 其中R 7a，R 8a如上所定义，R 9和R 1相同或不同，各自为氢 氟，氯或溴或任选被1至3个氟原子取代的甲基或乙基; R 6是氢，氟，氯或甲基; R 1和R 2可以相同或不同，各自为氢，卤素或任选被卤素，氰基，C 2-5烷氧基，C 1-4烷氧基或基团取代的C 1-3脂族基团 S（O）m R 1，其中m为0,1或2，R 1为C 1-4烷基; 氰基，二甲基或C 2-5烷氧基; R 3含有3至18个碳原子，并且是基团R 1，其中R 1 2是C 1-13非芳族烃基，任选被C 2-4烷氧基取代或 氰基和/或一个或两个羟基和/或一至五个相同或不同的卤素原子和/或一至三个相同或不同的基团R 1，3各自包含 1至4个相同或不同的杂原子，选自氧，硫，氮和硅，1至10个碳原子和任选1至6个氟或氯原子或R 3为6元芳环 被氰基和/或一至五个卤素原子和/或一至三个C 1-4卤代烷基和/或被基团取代-C取代基C，C-C或卤代C 1 -C 2烷基 其中R 1'如上文所定义或-C元素CR 1其中R 1是S（O）q R 5基团，其中R 1是 > 5是甲基，乙基或三氟甲基，或者R 1是SiR 1 R 6 R 7 R 8其中R 1和R 2都是R <1> <7> R 1相同或不同，并且各自为C 1-4脂族基团，并且R 1'为C 1-4脂族基团或苯基，条件是R 1，R 2，R 1， 总共不含10个以上碳原子; Y，Y 1和Y 2相同或不同，各自选自氧和S（O）t，其中t为0,1或2，其制备方法，含有它们的制剂及其用途 防治虫害。