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    ADIPIC ACID COMPOSITION
    1.
    发明公开
    ADIPIC ACID COMPOSITION 审中-公开
    脂肪酸组成

    公开(公告)号：EP2542519A1

    公开(公告)日：2013-01-09

    申请号：EP10812827.3

    申请日：2010-12-13

    申请人： Rennovia, Inc.

    发明人： BOUSSIE, Thomas, R. ,  DIAS, Eric, L. ,  FRESCO, Zachary, M. ,  MURPHY, Vincent, J. ,  SHOEMAKER, James ,  ARCHER, Raymond ,  JIANG, Hong

    IPC分类号： C07C55/14

    CPC分类号： C07C55/14 ,  C07C51/377 ,  C07C51/43 ,  C07D309/30 ,  C08G63/12 ,  C08G69/26 ,  C07C55/10

    摘要： Disclosed are compositions of matter comprising an adipic acid product of formula (1) wherein R is independently a salt-forming ion, hydrogen, hydrocarbyl, or substituted hydrocarbyl, and at least one constituent selected from the group consisting of formula (2) wherein R is as defined above and each of R1 is, independently, H, OH, acyloxy or substituted acyloxy provided, however, that at least one of R1 is OH, and formula (3) wherein R is as above defined and R1 is OH, acyloxy or substituted acyloxy. Also disclosed are compositions of matter comprising at least about 99 wt% adipic acid and least two constituents selected from the group consisting of formula (2) and formula (3), above.

    摘要翻译： 公开了包含式（1）的己二酸产物的组合物，其中R独立地为成盐离子，氢，烃基或取代的烃基，和至少一种选自式（2）的成分，其中R 如上所定义且每个R 1独立地为H，OH，酰氧基或取代的酰氧基，然而，提供了至少一个R 1为OH和式（3）其中R如上所定义且R 1为OH，酰氧基 或取代的酰氧基。 还公开了包含至少约99重量％的己二酸和选自以上式（2）和式（3）的至少两种成分的物质组合物。

    CONVERSION OF FRUCTOSE-CONTAINING FEEDSTOCKS TO HMF-CONTAINING PRODUCT
    2.
    发明公开
    CONVERSION OF FRUCTOSE-CONTAINING FEEDSTOCKS TO HMF-CONTAINING PRODUCT 审中-公开
    HMW-HALTIGES PRODUKT中的UMWANDLUNG VON FRUKTOSEHALTIGEN EINSATZSTOFFEN

    公开(公告)号：EP3099670A2

    公开(公告)日：2016-12-07

    申请号：EP15703214.5

    申请日：2015-01-27

    申请人： Rennovia Inc.

    发明人： BOUSSIE, Thomas, R. ,  DIAS, Eric, L. ,  MURPHY, Vincent, J. ,  SHOEMAKER, James, A.

    IPC分类号： C07D307/46

    CPC分类号： C07D307/46 ,  B01D61/027 ,  B01D61/145 ,  B01D2311/02 ,  B01D2311/25 ,  C07D307/50

    摘要： The present invention relates generally to processes for converting fructose-containing feedstocks to a product comprising 5-(hydroxymethyl)furfural (HMF) and water in the presence of water, solvent and an acid catalyst. In some embodiments, the conversion of fructose to HMF is controlled at a partial conversion endpoint characterized by a yield of HMF from fructose that does not exceed about 80 mol %. In these and other embodiments, the processes provide separation techniques for separating and recovering the product, unconverted fructose, solvent and acid catalyst to enable the effective recovery and reutilization of reaction components.

    摘要翻译： 本发明一般涉及在水，溶剂和酸催化剂的存在下将含果糖的原料转化成包含5-（羟甲基）糠醛（HMF）和水的产物的方法。 在一些实施方案中，将果糖转化成HMF的部分转化终点被控制，其特征在于果糖的HMF的产率不超过约80mol％。 在这些和其它实施方案中，该方法提供了用于分离和回收产物，未转化的果糖，溶剂和酸催化剂的分离技术，以使得能够有效地回收和再利用反应组分。

    PROCESS FOR PRODUCTION OF HEXAMETHYLENEDIAMINE FROM 5 - HYDROXYMETHYLFURFURAL
    7.
    发明公开
    PROCESS FOR PRODUCTION OF HEXAMETHYLENEDIAMINE FROM 5 - HYDROXYMETHYLFURFURAL 审中-公开
    VERFAHREN ZUR HERSTELLUNG VON HEXAMETHYLENDIAMIN AUS 5-羟基甲基纤维素

    公开(公告)号：EP2804848A1

    公开(公告)日：2014-11-26

    申请号：EP13701538.4

    申请日：2013-01-11

    申请人： Rennovia, Inc.

    发明人： DIAS, Eric, L. ,  SHOEMAKER, James, A. W. ,  BOUSSIE, Thomas, R. ,  MURPHY, Vincent, J.

    IPC分类号： C07C211/12 ,  C07C209/16 ,  C07C29/17 ,  C07C31/20 ,  C07C31/22 ,  C07D307/12

    CPC分类号： C07C29/157 ,  C07C29/132 ,  C07C29/141 ,  C07C29/175 ,  C07C209/16 ,  C07D307/46 ,  C07D307/48 ,  C07D307/50 ,  C07C31/20 ,  C07C31/22 ,  C07C211/12

    摘要： Processes are disclosed for the conversion of a carbohydrate source to hexamethylenediamine (HMDA) and to intermediates useful for the production of hexamethylenediamine and other industrial chemicals. HMDA is produced by direct reduction of a furfural substrate to 1,6-hexanediol in the presence of hydrogen and a heterogeneous reduction catalyst comprising Pt or by indirect reduction of a furfural substrate to 1,6-hexanediol wherein 1,2,6-hexanetriol is produced by reduction of the furfural substrate in the presence of hydrogen and a catalyst comprising Pt and 1,2,6-hexanediol is then converted by hydrogenation in the presence of a catalyst comprising Pt to 1,6 hexanediol, each process then proceding to the production of HMDA by known routes, such as amination of the 1,6 hexanediol. Catalysts useful for the direct and indirect production of 1,6-hexanediol are also disclosed.

    摘要翻译： 公开了用于将碳水化合物源转化为六亚甲基二胺（HMDA）的方法和用于生产六亚甲基二胺和其它工业化学品的中间体。 HMDA通过在氢存在下将糠醛底物直接还原为1,6-己二醇和通过Pt的多相还原催化剂或通过将糠醛底物间接还原成1,6-己二醇来制备，其中1,2,6-己三醇 通过在氢存在下还原糠醛底物而制备，然后在包含Pt至1,2,6-己二醇的催化剂存在下，通过氢化将包含Pt和1,2,6-己二醇的催化剂转化，然后进行至 通过已知途径生产HMDA，如1,6己糖胺化。 还公开了可用于直接和间接生产1,6-己二醇的催化剂。