公开(公告)号：EP1557406A1

公开(公告)日：2005-07-27

申请号：EP04257736.1

申请日：2004-12-13

申请人： Rohm and Haas Company

发明人： Bogan, Leonard Edward ,  Cavalcanti, Fernando A. P. ,  Chadda, Nitin ,  Chaturvedi, Sanjay ,  Gaffney, Anne Mae ,  Han, Scott ,  Klugherz, Peter D. ,  Martenak, Daniel ,  Silvano, Mark Anthony ,  Vickery, Elsie Mae ,  Zolotoroff, Donald L.

IPC分类号： C07C51/215 ,  C07C51/25 ,  C07C253/24 ,  C07C253/26 ,  C07C57/04 ,  C07C255/08

CPC分类号： C07C253/26 ,  C07C51/215 ,  C07C51/252 ,  C07C253/24 ,  Y02P20/52 ,  Y02P20/582 ,  C07C57/04 ,  C07C255/08

摘要： An improved process for the production of unsaturated carboxylic acids and unsaturated nitriles from their corresponding C 3 to C 5 alkanes, or mixtures of C 3 to C 5 alkanes and alkenes, that involves a multi-stage reaction system which employs both separation of the oxidation product from one or more intermediate effluent streams, as well as feeding additional oxygen to reaction zones subsequent to the first reaction zone.

摘要翻译： 一种用于从其相应的C3至C5烷烃或C3至C5烷烃和烯烃的混合物生产不饱和羧酸和不饱和腈的改进方法，涉及多级反应体系，该方法采用两步法将氧化产物从一种或 更多的中间流出物流，以及在第一反应区之后向反应区供给另外的氧。

公开(公告)号：EP1815907A2

公开(公告)日：2007-08-08

申请号：EP07250348.5

申请日：2007-01-29

申请人： Rohm and Haas Company

发明人： Cavalcanti, Fernando A.P. ,  Han, Scott ,  Klugherz, Peter D. ,  Lemonds, Andrew M. ,  Martenak, Daniel J. ,  Vickery, Elsie M. ,  Zolotorofe, Donald L.

IPC分类号： B01J23/28 ,  B01J23/652 ,  B01J23/92 ,  B01J23/96 ,  B01J27/057 ,  B01J37/02 ,  B01J38/08 ,  B01J38/16 ,  C07C51/215 ,  C07C253/24 ,  B01J23/30 ,  B01J38/04 ,  B01J38/06 ,  B01J37/34

CPC分类号： B01J23/002 ,  B01J23/28 ,  B01J23/30 ,  B01J23/6525 ,  B01J23/92 ,  B01J23/96 ,  B01J27/0576 ,  B01J27/30 ,  B01J35/002 ,  B01J37/0236 ,  B01J37/0238 ,  B01J37/342 ,  B01J38/04 ,  B01J38/06 ,  B01J38/08 ,  B01J38/16 ,  B01J2523/00 ,  C07C51/215 ,  C07C253/24 ,  Y02P20/52 ,  Y02P20/584 ,  C07C57/04 ,  B01J2523/55 ,  B01J2523/56 ,  B01J2523/64 ,  B01J2523/68 ,  B01J2523/824 ,  C07C255/08

摘要： A mixed metal oxide, which may be an orthorhombic phase material, is regenerated, selectively enriched or selectively poisoned as a catalyst to reduce catalyst aging for the production of unsaturated carboxylic acids, or unsaturated nitriles, from alkanes, or mixtures of alkanes and alkenes. Regeneration is effected by contacting said mixed metal oxide with a an oxidizing gas such as oxygen, air, steam and combinations thereof in a regenerator at a temperature of from 300°C to 600°C to form said regenerated catalyst.
The catalyst is enriched by re-metallizing the mixed metal oxide using a volatile organometallic compound.
Catalyst lifetime is extended by reversing flow direction of reactants.

摘要翻译： 可以是正交相材料的混合金属氧化物被再生，选择性地富集或选择性地中毒作为催化剂，以减少催化剂老化，用于从烷烃或烷烃和烯烃的混合物生产不饱和羧酸或不饱和腈。 在再生器中，在300℃至600℃的温度下，使所述混合金属氧化物与氧气，空气，蒸汽及其组合的氧化气体接触，以形成所述再生催化剂来进行再生。 通过使用挥发性有机金属化合物重新金属化混合的金属氧化物来富集催化剂。 通过反转反应物的流动方向来延长催化剂寿命。

公开(公告)号：EP1815907A3

公开(公告)日：2007-11-21

申请号：EP07250348.5

申请日：2007-01-29

申请人： Rohm and Haas Company

发明人： Cavalcanti, Fernando A.P. ,  Han, Scott ,  Klugherz, Peter D. ,  Lemonds, Andrew M. ,  Martenak, Daniel J. ,  Vickery, Elsie M. ,  Zolotorofe, Donald L.

IPC分类号： B01J23/28 ,  B01J23/652 ,  B01J23/92 ,  B01J23/96 ,  B01J27/057 ,  B01J37/02 ,  B01J38/08 ,  B01J38/16 ,  C07C51/215 ,  C07C253/24 ,  B01J23/30 ,  B01J38/04 ,  B01J38/06 ,  B01J37/34

CPC分类号： B01J23/002 ,  B01J23/28 ,  B01J23/30 ,  B01J23/6525 ,  B01J23/92 ,  B01J23/96 ,  B01J27/0576 ,  B01J27/30 ,  B01J35/002 ,  B01J37/0236 ,  B01J37/0238 ,  B01J37/342 ,  B01J38/04 ,  B01J38/06 ,  B01J38/08 ,  B01J38/16 ,  B01J2523/00 ,  C07C51/215 ,  C07C253/24 ,  Y02P20/52 ,  Y02P20/584 ,  C07C57/04 ,  B01J2523/55 ,  B01J2523/56 ,  B01J2523/64 ,  B01J2523/68 ,  B01J2523/824 ,  C07C255/08

摘要： A mixed metal oxide, which may be an orthorhombic phase material, is regenerated, selectively enriched or selectively poisoned as a catalyst to reduce catalyst aging for the production of unsaturated carboxylic acids, or unsaturated nitriles, from alkanes, or mixtures of alkanes and alkenes. Regeneration is effected by contacting said mixed metal oxide with a an oxidizing gas such as oxygen, air, steam and combinations thereof in a regenerator at a temperature of from 300°C to 600°C to form said regenerated catalyst.
The catalyst is enriched by re-metallizing the mixed metal oxide using a volatile organometallic compound.
Catalyst lifetime is extended by reversing flow direction of reactants.