摘要:
A copolycarbonate comprises first repeating units, second repeating units different from the first repeating units, and third repeating units different from the first and second repeating units; and wherein the first repeating units are phthalimidine carbonate units, the second repeating units are carbonate units of the formula (I) wherein Rc and Rd are each independently a C1-12 alkyl, C2-12 alkenyl, C3-8 cycloalkyl, or C1-12 alkoxy, each R6 is independently C1-3 alkyl or phenyl; Xa is a C6-12 polycyclic aryl, C3-18 mono- or polycycloalkylene, C3-18 mono- or polycycloalkylidene, -(Q1)x-G-(Q2)y- group wherein Q1 and Q2 are each independently a C1-3 alkylene, G is a C3-10 cycloalkylene, x is 0 or 1, and y is 1; and m and n are each independently 0 to 4; and the third repeating units are carbonate units (II) wherein Re and Rf are each independently C1-12 alkyl, C2-12 alkenyl, C3-8 cycloalkyl, or C1-12 alkoxy, a and b are each independently integers of 0 to 4, and Xb is a single bond, -0-, -S-, - S(0)-, -S(0)2-, -C(0)-, or C1-32 bridging hydrocarbon group, provided that Xb is not a phthalimidine group or Xa.
摘要:
A railway component comprises a polycarbonate composition comprising: a first polycarbonate selected from a linear polycarbonate homopolymer, a branched polycarbonate, a poly(carbonate-bisphenol arylate ester), a poly(aliphatic ester-carbonate), or a combination thereof; a second polymer different from the first polycarbonate, the second polymer comprising a poly(carbonate-siloxane) copolymer, a polydialkylsiloxane, a silicone graft copolymer, or a combination thereof, wherein siloxane units in the second polymer are present in an amount of 0.3 to 3 wt. %, based on the total weight of the composition; and 10 to 40 wt. % of glass fiber, based on the total weight of the polycarbonate composition.
摘要:
Metallized articles comprising polycarbonate compositions are disclosed. The compositions include at least one first polycarbonate useful for high heat applications; and a second Bisphenol A polycarbonate. The compositions can include one or more additives. The compositions can be used to prepare articles of manufacture, and in particular, automotive bezel.
摘要:
A composition comprises a first polycarbonate having a limited oxygen index of greater than 26% measured according to ISO 4589 on a 4 mm thick plaque, wherein an article molded from the first polycarbonate has a smoke density after 4 minutes (DS-4) of greater than 600 determined according to ISO 5659-2 on a 3 mm thick plaque at 50 kW/m2; and a second polymer different from the first polycarbonate, the second polymer comprising a poly(carbonate-siloxane) copolymer, a polydialkylsiloxane, or a combination comprising at least one of the foregoing; wherein an article molded from the second polymer has a smoke density after 4 minutes (DS-4) of greater than 600 determined according to ISO 5659-2 on a 3 mm thick plaque at 50 kW/m2; wherein an article molded from the composition has a smoke density after 4 minutes (DS-4) of smaller than 480 determined according to ISO 5659-2 on a 3 mm thick plaque at 50 kW/m2.
摘要:
A polycarbonate composition comprises: a first poly(carbonate-siloxane) copolymer, comprising a polysiloxane block with an average block length of 10 to 100, and a siloxane content from 5 wt% to 10 wt%; and a second poly(carbonate-siloxane) copolymer comprising a polysiloxane block with an average block length of 10 to 100, and a siloxane content from 30 wt% to 60 wt%; wherein the weight ratio of the first poly(carbonate-siloxane) copolymer to the second poly(carbonate-siloxane) copolymer is greater than or equal to 2 to less than 8; and a bisphenol A homopolycarbonate, wherein the polycarbonate composition has a total siloxane content of 2.5 wt% to 10 wt% based on the total weight of the composition; and a molded part of 1 mm thickness has a haze of less than 10% as measured by HazeGard (ASTM D1003-00).