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21 条记录 (耗时 0.015 秒)

    CONVERSION OF SOLID BIOMASS INTO A LIQUID HYDROCARBON MATERIAL
    4.
    发明公开
    CONVERSION OF SOLID BIOMASS INTO A LIQUID HYDROCARBON MATERIAL 有权
    将固体生物质转化为液态烃材料

    公开(公告)号：EP3164471A1

    公开(公告)日：2017-05-10

    申请号：EP15732258.7

    申请日：2015-06-29

    申请人： Shell Internationale Research Maatschappij B.V.

    发明人： URADE, Vikrant Nanasaheb ,  CHILKOOR SOUNDARARAJAN, Laxmi Narasimhan ,  GOPAL, Srikant ,  PANCHAGNULA, Madhusudhan Rao ,  DEL PAGGIO, Alan Anthony

    IPC分类号： C10K1/00 ,  C10K3/04 ,  C10G1/06 ,  C10G1/08 ,  C10G1/10 ,  C10G3/00

    CPC分类号： C10G1/002 ,  C10G1/06 ,  C10G1/086 ,  C10G1/10 ,  C10G3/45 ,  C10G3/46 ,  C10G3/47 ,  C10G3/48 ,  C10G3/50 ,  C10G3/52 ,  C10G2300/1003 ,  C10G2300/1011 ,  C10G2300/1014 ,  C10K1/002 ,  C10K1/004 ,  C10K3/04 ,  Y02P30/20

    摘要： The present invention provides a process for producing liquid hydrocarbon products from a solid biomass feedstock, said process comprising the steps of: a) providing in a first hydropyrolys is reactor vessel a first hydropyrolysis catalyst composition, said composition comprising one or more active metals selected from cobalt, molybdenum, nickel, tungsten, ruthenium, platinum, palladium, iridium and iron on an oxide support, wherein the active metals are present in a partially sulfided form to the extent that the first hydropyrolysis catalyst composition contains sulfur in an amount of from 10 to 90% of a full stoichiometric amount; b) contacting the solid biomass feedstock with said first hydropyrolysis catalyst composition and molecular hydrogen in said first hydropyrolysis reactor vessel at a temperature in the range of from 350 to 600°C and a pressure in the range of from 0.50 to 7.50MPa, to produce a product stream comprising partially deoxygenated hydropyrolysis product, H2O, H2, CO2, CO, C1 - C3 gases, char and catalyst fines; c) removing said char and catalyst fines from said product stream; d) hydroconverting said partially deoxygenated hydropyrolysis product in a hydroconversion reactor 25 vessel in the presence of one or more hydroconversion catalyst and of the H2O, CO2, CO, H2, and C1 - C3 gas generated in step a), to produce a vapour phase product comprising substantially fully deoxygenated hydrocarbon product, H2O, CO, CO2, and C1 – C3 gases.

    摘要翻译： 本发明提供了一种由固体生物质原料生产液体烃产物的方法，所述方法包括以下步骤：a）在第一加氢精制反应器中提供第一加氢热解催化剂组合物，所述组合物包含一种或多种选自 钴，钼，镍，钨，钌，铂，钯，铱和铁，其中活性金属以部分硫化的形式存在，使得第一加氢热解催化剂组合物含有10 至完整化学计量的90％; b）使所述固体生物质原料与所述第一加氢热解催化剂组合物和分子氢在所述第一加氢热解反应器容器中在350-600℃的温度范围和0.50-7.50MPa的压力下接触，以产生 包含部分脱氧的加氢热解产物，H 2 O，H 2，CO 2，CO，C 1 -C 3气体，焦炭和催化剂细粒的产物流; c）从所述产品物流中除去所述焦炭和催化剂细粒; d）在加氢转化反应器容器中，在一种或多种加氢转化催化剂和步骤a）中产生的H 2 O，CO 2，CO，H 2和C 1 -C 3气体的存在下，将所述部分脱氧的加氢热解产物进行加氢转化， 包含基本上完全脱氧的烃产物，H 2 O，CO，CO 2和C 1 -C 3气体的产物。

    CONVERSION OF BIOMASS OR RESIDUAL WASTE MATERIAL TO BIOFUELS
    7.
    发明公开
    CONVERSION OF BIOMASS OR RESIDUAL WASTE MATERIAL TO BIOFUELS 审中-公开
    将生物质或残留废弃物转化为生物燃料

    公开(公告)号：EP3289047A1

    公开(公告)日：2018-03-07

    申请号：EP16718350.8

    申请日：2016-04-25

    申请人： Shell Internationale Research Maatschappij B.V.

    发明人： URADE, Vikrant Nanasaheb ,  DEL PAGGIO, Alan Anthony ,  CHILKOOR SOUNDARARAJAN, Laxmi Narasimhan

    IPC分类号： C10G1/06 ,  C10G1/08 ,  C10G3/00 ,  C10G1/00

    CPC分类号： C10G1/06 ,  C10G1/002 ,  C10G1/086 ,  C10G3/50 ,  C10G2300/1003 ,  C10G2300/1011 ,  C10G2300/1014 ,  C10G2300/1018 ,  Y02P30/20

    摘要： The present invention provides a process for producing liquid hydrocarbon products from solid biomass and/or residual waste feedstocks, said process comprising the steps of: a) a first stage of hydropyrolysing the solid feedstock in a hydropyrolysis reactor vessel in the presence of molecular hydrogen and one or more deoxygenation catalysts, producing a product stream comprising partially deoxygenated hydropyrolysis product, H2O, H2, CO2, CO, C1-C3 gases, char and catalyst fines; b) removing said char and catalyst fines from said product stream; c) a second stage of hydroconverting said partially deoxygenated hydropyrolysis product in a hydroconversion reactor vessel in the presence of one or more hydroconversion catalysts and of the H2O, CO2, CO, H2, and C1-C3 gas generated in step a), producing a vapour phase product comprising substantially fully deoxygenated hydrocarbon product, H2O, CO, CO2, and C1-C3 gases; d) condensing the vapour phase product of step d) to 20 provide a liquid phase product comprising substantially fully deoxygenated C4+ hydrocarbon liquid and aqueous material and separating said liquid phase product from a gas phase product comprising H2, CO, CO2, and C1-C3 gases; e) removing the aqueous material from the substantially fully deoxygenated C4+ hydrocarbon liquid; and f) a third stage comprising combining an aliphatic hydrocarbon precursor or an aromatic hydrocarbon precursor with at least a portion of the substantially fully deoxygenated C4+ hydrocarbon liquid and co-processing the resultant liquid in a hydroprocessing reactor vessel in the presence of hydrogen and one or more hydroprocessing catalysts.

    CONVERSION OF SOLID BIOMASS INTO A LIQUID HYDROCARBON MATERIAL
    8.
    发明公开
    CONVERSION OF SOLID BIOMASS INTO A LIQUID HYDROCARBON MATERIAL 审中-公开
    将固体生物质转化为液态烃材料

    公开(公告)号：EP3164470A1

    公开(公告)日：2017-05-10

    申请号：EP15732252.0

    申请日：2015-06-29

    申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V.

    发明人： URADE, Vikrant Nanasaheb ,  CHILKOOR SOUNDARARAJAN, Laxmi Narasimhan ,  PANCHAGNULA, Madhusudhan Rao ,  DEL PAGGIO, Alan Anthony

    IPC分类号： C10K1/00 ,  C10K3/04 ,  C10G1/06 ,  C10G1/08 ,  C10G1/10 ,  C10G3/00

    CPC分类号： C10G1/002 ,  C10G1/02 ,  C10G1/06 ,  C10G1/086 ,  C10G1/10 ,  C10G3/42 ,  C10G3/45 ,  C10G3/47 ,  C10G3/48 ,  C10G3/50 ,  C10G3/52 ,  C10G2300/1003 ,  C10G2300/1014 ,  C10G2300/202 ,  C10K1/004 ,  C10K3/04 ,  Y02P30/20

    摘要： The present invention provides a process for producing liquid hydrocarbon products from a solid biomass feedstock, said process comprising the steps of: a) providing in a first hydropyrolysis reactor vessel a first hydropyrolysis catalyst composition, said composition comprising one or more active metals selected from cobalt, molybdenum, nickel, tungsten, ruthenium, platinum, palladium, iridium and iron on an oxide support, wherein at least a portion of the active metals are present in fully reduced metallic form; b) contacting the solid biomass feedstock with said first hydropyrolysis catalyst composition and molecular hydrogen in said first hydropyrolysis reactor vessel at a temperature in the range of from 350 to 600°C and a pressure in the range of from 0.50 to 7.50MPa, to produce a product stream comprising partially deoxygenated hydropyrolysis product, H2O, H2, CO2, CO, C1 - C3 gases, char and catalyst fines; c) removing said char and catalyst fines from said product stream; d) hydroconverting said partially deoxygenated hydropyrolysis product in a hydroconversion reactor vessel in the presence of one or more hydroconversion catalyst and of the H2O, CO2, CO, H2, and C1 - C3 gas generated in step a), to produce a vapour phase product comprising substantially fully deoxygenated hydrocarbon product, H2O, CO, CO2, and C1 – C3 gases.

    摘要翻译： 本发明提供由固体生物质原料生产液态烃产物的方法，所述方法包括以下步骤：a）在第一加氢热解反应器容器中提供第一加氢热解催化剂组合物，所述组合物包含一种或多种选自钴 ，钼，镍，钨，钌，铂，钯，铱和铁，其中至少一部分活性金属以完全还原的金属形式存在; b）使所述固体生物质原料与所述第一加氢热解催化剂组合物和分子氢在所述第一加氢热解反应器容器中在350-600℃的温度范围和0.50-7.50MPa的压力下接触，以产生 包含部分脱氧的加氢热解产物，H 2 O，H 2，CO 2，CO，C 1 -C 3气体，焦炭和催化剂细粒的产物流; c）从所述产品物流中除去所述焦炭和催化剂细粒; d）在加氢转化反应器容器中，在一种或多种加氢转化催化剂和步骤a）中产生的H 2 O，CO 2，CO，H 2和C 1 -C 3气体的存在下，将所述部分脱氧的加氢热解产物进行加氢转化以产生气相产物 包含基本完全脱氧的烃产物，H 2 O，CO，CO 2和C 1 -C 3气体。

    A PROCESS FOR CONVERTING ONE OR MORE C3-C12 OXYGENATES
    9.
    发明公开
    A PROCESS FOR CONVERTING ONE OR MORE C3-C12 OXYGENATES 有权
    VERFAHREN ZUR UMWANDLUNG EINES ODER MEHRERER C3-C12-OXYGENATE

    公开(公告)号：EP2938707A1

    公开(公告)日：2015-11-04

    申请号：EP13814923.2

    申请日：2013-12-19

    申请人： Shell Internationale Research Maatschappij B.V.

    发明人： URADE, Vikrant Nanasaheb ,  DEL PAGGIO, Alan Anthony ,  CHILKOOR SOUNDARARAJAN, Laxmi Narasimhan ,  PANCHAGNULA, Madhusudhan Rao

    IPC分类号： C10G29/20 ,  C10G29/22 ,  C10G3/00 ,  C07C1/20 ,  C07C2/00

    摘要： A process for converting one or more C3-C12 oxygenates comprising: 1) contacting a feed comprising C3-C12 oxygenates with hydrogen in the presence of a sulphided hydrogenation catalyst to produce a partially hydrogenated effluent; 2) contacting the partially hydrogenated effluent with hydrogen at a hydrogen partial pressure of at least 0.1 MegaPascal in the presence of a sulphided carbon-carbon coupling catalyst to produce a conversion product; 3) optionally contacting at least part of the conversion product with hydrogen in the presence of a sulphided hydrotreating catalyst and/or a sulphided hydroisomerization catalyst to produce a conversion product; and 4) optionally purifying the conversion product, optionally hydrotreated and/or hydroisomerized, conversion product to obtain a final product, wherein the carbon-carbon coupling catalyst comprises at least 60 wt % of a zeolite and in the range from 0.1 wt % to 10 wt % of a hydrogenation metal, based on the total weight of the carbon-carbon coupling catalyst.

    摘要翻译： 一种用于转化一种或多种C 3 -C 12含氧化合物的方法，包括：1）在硫化氢化催化剂存在下使包含C 3 -C 12含氧化合物的进料与氢接触以产生部分氢化的流出物; 2）在硫化碳 - 碳偶联催化剂存在下，使部分氢化流出物与氢气分压至少为0.1兆帕，以产生转化产物; 3）任选地在硫化加氢处理催化剂和/或硫化加氢异构化催化剂的存在下使至少部分转化产物与氢接触以产生转化产物; 和4）任选地纯化转化产物，任选地加氢处理和/或加氢异构化的转化产物以获得最终产物，其中碳 - 碳偶联催化剂包含至少60重量％的沸石，并且在0.1重量％至10重量％的范围内 重量％的氢化金属，基于碳 - 碳偶联催化剂的总重量。