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公开(公告)号：EP0026234A1
公开(公告)日：1981-04-08
申请号：EP80900609.1
申请日：1980-03-28
IPC分类号： C08L49/00 , C08F281/00 , C08F8/00 , C08K3/00 , C08K5/00
CPC分类号： C08L49/00 , C08K13/02 , H01L51/0041 , H01L51/42 , Y02E10/549 , Y02P70/521
摘要： A process for preparing organic semiconductor, which comprises doping an acetylene high polymer having a fibril structure with a specific electron-accepting compound. Conventional electron-accepting compounds are highly toxic and provide conductive acetylene high polymers which do not always exhibit a sufficiently high electric conductivity, which have a mechanical strength seriously reduced by the doping, and which have an insufficient heat resistance. The use of a specific, the low-toxic electron-accepting compound of the present invention provides a conductive acetylene high polymer having an enhanced electric conductivity and good flexibility and heat resistance. This conductive acetylene high polymer is a p-type semiconductor enabling to freely control the electric conductivity within the range of 10- 9 to 10 3 Ω- 1 .cm- 1 and is useful as a material for conductive materials, p-n heterojunction elements, and photo-electric transducers such as solar batteries, photosensors, etc.
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2.发明公开Process for molding an acetylene high polymer and process for fabrication thereof 失效用于模制乙炔高聚物的方法及其制造方法
公开(公告)号：EP0026235A1
公开(公告)日：1981-04-08
申请号：EP80900610.9
申请日：1980-03-28
CPC分类号： H01C7/005 , C08F38/02 , H01B1/125 , H01L51/0041 , H01L51/42
摘要： A process for preparing a gel-like composition of acetylene high polymer or porous acetylene high polymer. While conventional processes fail to produce acetylene high polymer moldings to any thickness and in any shape with a large mechanical strength, this process enables the production of acetylene high polymer moldings to any thickness and in any shape with a large mechanical strength. Acetylene high polymer moldings obtained by the fabrication of the gel-like composition and the porous acetylene polymer obtained by this process are p-type semiconductors having an electric conductivity of 10- 8 to 10- 5 Ω- 1 .cm- 1 and, since they possess photoconductivity, they can be utilized as photo-electric transducers such as electric resistance elements, heat- sensitive elements, solar batteries, photosensors, etc. The electric conductivity of the acetylene high polymer moldings can be controlled over a wide range of 10 -8 to 10 3 Ω- 1 .cm- 1 by doping with an electron-accepting or electron-donating compound, thus they can find wider applications as the aforesaid electron elements.
摘要翻译： 制备乙炔高聚物或多孔乙炔高聚物的凝胶状组合物的方法。 尽管传统方法不能将乙炔高聚物模制品生产成任何厚度和任何形状并具有较大的机械强度，但该方法能够将乙炔高聚物模制品制造成任何厚度和任何具有大机械强度的形状。 通过制造凝胶状组合物而获得的乙炔高聚物模制品和通过该方法获得的多孔乙炔聚合物是具有10 -8至10 -5Ω-1·cm -1的电导率的p型半导体，并且因为它们 具有光电导性，它们可以用作光电元件，如电阻元件，热敏元件，太阳能电池，光电传感器等。乙炔高分子模制品的电导率可以控制在宽范围10-8 通过掺杂受电子或供电子化合物而达到103Ω-1.cm-1，因此它们可以作为上述电子元件得到更广泛的应用。
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3.发明授权
公开(公告)号：EP0026235B1
公开(公告)日：1986-12-10
申请号：EP80900610.9
申请日：1980-03-28
CPC分类号： H01C7/005 , C08F38/02 , H01B1/125 , H01L51/0041 , H01L51/42
摘要： A process for preparing a gel-like composition of acetylene high polymer or porous acetylene high polymer. While conventional processes fail to produce acetylene high polymer moldings to any thickness and in any shape with a large mechanical strength, this process enables the production of acetylene high polymer moldings to any thickness and in any shape with a large mechanical strength. Acetylene high polymer moldings obtained by the fabrication of the gel-like composition and the porous acetylene polymer obtained by this process are p-type semiconductors having an electric conductivity of 10-8 to 10-5(Alpha)-1(Alpha)cm-1 and, since they possess photoconductivity, they can be utilized as photo-electric transducers such as electric resistance elements, heat-sensitive elements, solar batteries, photosensors, etc. The electric conductivity of the acetylene high polymer moldings can be controlled over a wide range of 10-8 to 103(Alpha)-1(Alpha)cm-1 by doping with an electron-accepting or electron-donating compound, thus they can find wider applications as the aforesaid electron elements.
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公开(公告)号：EP0026234B1
公开(公告)日：1984-07-11
申请号：EP80900609.1
申请日：1980-03-28
IPC分类号： C08L49/00 , C08F281/00 , C08F8/00 , C08K3/00 , C08K5/00
CPC分类号： C08L49/00 , C08K13/02 , H01L51/0041 , H01L51/42 , Y02E10/549 , Y02P70/521
摘要： A process for preparing organic semiconductor, which comprises doping an acetylene high polymer having a fibril structure with a specific electron-accepting compound. Conventional electron-accepting compounds are highly toxic and provide conductive acetylene high polymers which do not always exhibit a sufficiently high electric conductivity, which have a mechanical strength seriously reduced by the doping, and which have an insufficient heat resistance. The use of a specific, the low-toxic electron-accepting compound of the present invention provides a conductive acetylene high polymer having an enhanced electric conductivity and good flexibility and heat resistance. This conductive acetylene high polymer is a p-type semiconductor enabling to freely control the electric conductivity within the range of 10-9 to 103(Alpha)-1(Alpha)cm-1 and is useful as a material for conductive materials, p-n heterojunction elements, and photo-electric transducers such as solar batteries, photosensors, etc.
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