METHYL METHACRYLATE PRODUCTION PROCESS
    1.
    发明公开
    METHYL METHACRYLATE PRODUCTION PROCESS 审中-公开
    VERFAHREN ZUR HERSTELLUNG VONMETHACRYLSÄUREMETHYLESTER

    公开(公告)号:EP2003114A1

    公开(公告)日:2008-12-17

    申请号:EP07740948.0

    申请日:2007-03-28

    CPC分类号: C07C67/38 C07C69/54

    摘要: A method of producing methyl methacrylate comprising the following steps:
    Thermal decomposition step: a hydrocarbon having 3 or more carbon atoms is thermally decomposed to obtain a decomposed gas having a total content of propyne and propadiene of 2 wt% or more,
    Separation step: mixed liquid rich in propyne and propadiene is separated from the decomposed gas obtained in the thermal decomposition step,
    Propyne purification step: the mixed liquid rich in propyne and propadiene obtained in the separation step is subjected to extractive distillation, for separation into purified propyne, and crude propadiene containing propadiene as the main component,
    Isomerization step: the crude propadiene obtained in the propyne purification step is isomerized in the presence of an isomerization catalyst, to obtain crude propyne containing propyne as the main component, and
    Carbonylation step: the purified propyne obtained in the propyne purification step is reacted with carbon monoxide and methanol in the presence of a group VIII metal catalyst system, to produce methyl methacrylate.

    摘要翻译: 一种生产甲基丙烯酸甲酯的方法,包括以下步骤:热分解步骤:将具有3个或更多个碳原子的烃热分解,得到丙炔和丙二烯的总含量为2重量%以上的分解气体,分离步骤:混合 从热分解步骤中得到的分解气体中分离富含丙炔和丙二烯的液体,丙炔纯化步骤:将在分离步骤中得到的富含丙炔和丙二烯的混合液进行萃取蒸馏,分离成纯化丙炔, 丙二烯含有丙二烯为主要成分,异构化步骤:丙炔纯化步骤中得到的粗制丙二烯在异构化催化剂存在下异构化,得到含有丙炔的粗制丙炔作为主要成分,羰基化步骤:将纯化的丙炔 丙炔纯化步骤与一氧化碳和甲醇反应, n存在第VIII族金属催化剂体系,生产甲基丙烯酸甲酯。

    METHOD FOR PRODUCING CHLORINE
    3.
    发明授权
    METHOD FOR PRODUCING CHLORINE 有权
    用于生产氯

    公开(公告)号:EP1170250B1

    公开(公告)日:2008-01-09

    申请号:EP00900806.1

    申请日:2000-01-19

    IPC分类号: C01B7/04 B01J23/46

    CPC分类号: C01B7/04 Y02P20/228

    摘要: In a method for producing chlorine comprising oxidizing hydrogen chloride present in a gas containing the hydrogen chloride using a gas containing oxygen in the presence of a catalyst, an improvement which comprises conducting the oxidation of the hydrogen chloride in a reaction region comprising at least two catalyst-packed layers connected in series and carrying out the temperature control of at least one reaction region using a heat exchange system is disclosed. This method enables the inhibition of formation of excess hot spots and effective utilization of the catalyst-packed layers, which results in maintaining stable activity of the catalyst and in the production of chlorine in high yield with good stability.

    CHEMICAL REACTION METHOD, CHEMICAL REACTION APPARATUS AND PRODUCTION METHOD

    公开(公告)号:EP4234521A2

    公开(公告)日:2023-08-30

    申请号:EP23171663.0

    申请日:2021-08-30

    IPC分类号: C07B61/00

    摘要: In a chemical reaction device (100) that improves an yield of a product and that causes a reaction, progress of which in a gaseous phase is restricted by a chemical equilibrium between a source material and the product, a cumulative value is not less than 500 mm 2 , the cumulative value being obtained by cumulatively adding, from one end to the other end of a cooling surface (53) in a height direction, products of (i) a distance L between (a) a surface of a catalyst layer (3) which surface is in contact with a transmission wall (40) and (b) an outer surface of the cooling surface (53) and (ii) a height H of the catalyst layer (3) corresponding to the outer surface having the distance L.

    DEHYDRATION METHOD
    5.
    发明公开
    DEHYDRATION METHOD 审中-公开
    ENTWÄSSERUNGSVERFAHREN

    公开(公告)号:EP1932822A1

    公开(公告)日:2008-06-18

    申请号:EP06797330.5

    申请日:2006-08-29

    IPC分类号: C07C37/02 C07C37/78 C07C39/04

    摘要: A dehydration method for removing water from a hydrolysis reaction mixture containing unreacted water generated when monochlorobenzene is hydrolyzed to produce phenol, the method for dehydrating the hydrolysis reaction mixture comprising the steps of supplying a hydrolysis reaction mixture to a distillation tower, supplying a liquid containing monochlorobenzene to the tower top portion of the distillation tower, and removing the substantially whole amount of the water in the hydrolysis reaction mixture together with monochlorobenzene from the tower top portion by distillation.

    摘要翻译: 一种脱水方法,用于从含有一氯苯水解产生苯酚的未反应水的水解反应混合物中除去水分,该水解反应混合物的脱水方法包括以下步骤:将水解反应混合物供入蒸馏塔,供给含有一氯苯 到蒸馏塔的塔顶部分,并通过蒸馏从塔顶部分与单氯苯一起除去水解反应混合物中的基本上全部量的水。

    METHOD FOR PRODUCING CHLORINE
    6.
    发明公开
    METHOD FOR PRODUCING CHLORINE 有权
    VERFAHREN ZUR CHLOR-HERSTELLUNG

    公开(公告)号:EP1170250A1

    公开(公告)日:2002-01-09

    申请号:EP00900806.1

    申请日:2000-01-19

    IPC分类号: C01B7/04 B01J23/46

    CPC分类号: C01B7/04 Y02P20/228

    摘要: A process for producing chlorine comprising the step of oxidizing hydrogen chloride in a gas containing hydrogen chloride with a gas containing oxygen in the presence of a catalyst, wherein the oxidation of hydrogen chloride is carried out in at least two reaction zones each comprising a catalyst-packed layer, which are arranged in series, and a temperature in at least one of said reaction zones is controlled with a heat exchange system. According to this process, the stable activity of the catalyst is maintained and chlorine can be stably obtained at a high yield since the excessive hot spot in the catalyst-packed layer is suppressed and the catalyst-packed layer can be effectively used.

    摘要翻译: 一种生产氯的方法,包括在催化剂存在下,用含有氧的气体在含有氯化氢的气体中氧化氯化氢的步骤,其中氯化氢的氧化在至少两个反应区进行,每个反应区包含催化剂 - 填充层,其串联布置,并且至少一个所述反应区域中的温度由热交换系统控制。 根据该方法,由于催化剂填充层中的过度热点被抑制并且可以有效地使用催化剂填充层,所以保持了催化剂的稳定活性,并以高产率稳定地获得氯。

    CHEMICAL REACTION METHOD, CHEMICAL REACTION APPARATUS AND PRODUCTION METHOD

    公开(公告)号:EP4234521A3

    公开(公告)日:2023-09-27

    申请号:EP23171663.0

    申请日:2021-08-30

    摘要: In a chemical reaction device (100) that improves an yield of a product and that causes a reaction, progress of which in a gaseous phase is restricted by a chemical equilibrium between a source material and the product, a cumulative value is not less than 500 mm 2 , the cumulative value being obtained by cumulatively adding, from one end to the other end of a cooling surface (53) in a height direction, products of (i) a distance L between (a) a surface of a catalyst layer (3) which surface is in contact with a transmission wall (40) and (b) an outer surface of the cooling surface (53) and (ii) a height H of the catalyst layer (3) corresponding to the outer surface having the distance L.