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    Process for producing amide by liquid phase rearrangement of oxime
    3.
    发明公开
    Process for producing amide by liquid phase rearrangement of oxime 失效
    Verfahren zur Herstellung von Amid dir Oximumlagerung inflüssigerPhase。

    公开(公告)号：EP0515063A1

    公开(公告)日：1992-11-25

    申请号：EP92304140.4

    申请日：1992-05-08

    申请人： SUMITOMO CHEMICAL COMPANY LIMITED ,  Izumi, Yusuke

    发明人： Izumi, Yusuke ,  Sato, Hiroshi ,  Yoshioka, Hiroshi ,  Nomura, Yoshisaburou

    IPC分类号： C07C231/10 ,  C07D201/04

    CPC分类号： C07D201/04 ,  C07C231/10

    摘要： A process for producing an amide which comprises subjecting an oxime to liquid phase rearrangement in the presence of phosphorus pentoxide and at least one compound selected from the group consisting of N,N-dialkyl amides, N-alkyl cyclic amides and dialkyl sulfoxides and optionally a fluorine-containing strong said or its derivative. Said process can rearrange an oxime to a corresponding amide in a good yield under mild reaction conditions in the presence of a less stoichiometric amount of a catalyst.

    摘要翻译： 一种酰胺的制备方法，其包括在五氧化二磷和至少一种选自N，N-二烷基酰胺，N-烷基环状酰胺和二烷基亚砜的化合物的存在下，使肟进行液相重排， 含氟强力或其衍生物。 所述方法可以在较少化学计量的催化剂存在下，在温和的反应条件下将肟重排为相应的酰胺，产率良好。