Copolymers of ethylene and an alpha-olefin and catalytic production thereof
    1.
    发明公开
    Copolymers of ethylene and an alpha-olefin and catalytic production thereof 失效
    乙烯和乙烯烯烃的共聚物及其催化生产

    公开(公告)号:EP0346098A3

    公开(公告)日:1991-04-17

    申请号:EP89305752.1

    申请日:1989-06-07

    IPC分类号: C08F210/02 C08F4/68

    CPC分类号: C08F210/00 C08F4/68

    摘要: Ethylene (35-60 mols) and a C 3-10 a-olefin (65-40 mols) are copolymerized at a temperature of 40 to 80°C with a catalyst of (a) an oxyvanadium compound, (b) an organoaluminium compound and (c) a halogenated hydrocarbon ester, e.g. a perchlorocrotonic acid ester, in a mol ratio of (b) to (a) of ≧ 2.5 and of (c) to (a) of ≧ 1.5, in a hydrocarbon solvent. The polymer has a molar ratio of ethylene: a-olefin of 88:12 - 98:2, a number average mol. wt. of 35,000 - 80,000 and a ratio of wt. number average mol wt. of 1.8:1 - 3.0:1 determined by GPC. It has good transparency and is moldable to a film which is heat-sealable at low temperature.

    Polypropylene laminated film
    2.
    发明公开
    Polypropylene laminated film 失效
    Schichtfilm aus聚丙烯。

    公开(公告)号:EP0659552A1

    公开(公告)日:1995-06-28

    申请号:EP94309384.9

    申请日:1994-12-15

    IPC分类号: B32B27/32 C08L23/16

    摘要: A polypropylene laminated film containing a crystalline polypropylene layer and, laminated on at least one side of the layer of the crystalline polypropylene, a layer of a copolymer of propylene and at least one α-olefin of from 4 to 10 carbon atoms having a specific composition, melt flow rate and molecular weight distribution in which the α-olefin content in the cold xylene soluble portion of the random copolymer is less than 1.7 times the α-olefin content in the copolymer and the random copolymer satisfies the mathematical expression, B ≦ 1.05A - 10,
    wherein A is a weight percentage of the content of said at least one α-olefin having from 4 to 10 carbon atoms in the random copolymer and B is a weight percentage of the cold xylene soluble portion in the random copolymer, is superior in low temperature heat sealability and hot tack property and moreover has a good transparency, blocking resistance and printability, wherein the random copolymer is obtained by gas phase polymerization substantially in the absence of a liquid medium, and using a catalyst system comprising (i) a solid catalyst component containing magnesium, titanium and a halogen as essential constituents, (ii) an organoaluminum compound and (iii) an electron donative compound.

    摘要翻译: 一种聚丙烯层压膜,其含有结晶聚丙烯层,层压在该结晶聚丙烯层的至少一侧上,具有丙烯与至少一种具有特定组成的4-10个碳原子的至少一种α-烯烃的共聚物层 ,熔体流动速率和分子量分布,其中无规共聚物的冷二甲苯可溶部分中的α-烯烃含量小于共聚物中α-烯烃含量的1.7倍,无规共聚物满足数学表达式, 其中A是无规共聚物中所述至少一种具有4至10个碳原子的α-烯烃的含量的重量百分比,B是无规共聚物中冷二甲苯可溶部分的重量百分比,在低温下是优异的 热封性和热粘性,而且具有良好的透明性,耐粘连性和可印刷性,其中无规共聚物由气相聚 并且使用包含(i)含有镁,钛和卤素作为必要组分的固体催化剂组分的催化剂体系,(ii)有机铝化合物和(iii)给电子化合物。

    Copolymers of ethylene and an alpha-olefin and catalytic production thereof
    3.
    发明公开
    Copolymers of ethylene and an alpha-olefin and catalytic production thereof 失效
    Ethylen-alpha-Olefincopolytere und katalytisches Verfahren zur Herstellung derselben。

    公开(公告)号:EP0346098A2

    公开(公告)日:1989-12-13

    申请号:EP89305752.1

    申请日:1989-06-07

    IPC分类号: C08F210/02 C08F4/68

    CPC分类号: C08F210/00 C08F4/68

    摘要: Ethylene (35-60 mols) and a C 3-10 a-olefin (65-40 mols) are copolymerized at a temperature of 40 to 80°C with a catalyst of (a) an oxyvanadium compound, (b) an organoaluminium compound and (c) a halogenated hydrocarbon ester, e.g. a perchlorocrotonic acid ester, in a mol ratio of (b) to (a) of ≧ 2.5 and of (c) to (a) of ≧ 1.5, in a hydrocarbon solvent.
    The polymer has a molar ratio of ethylene: a-olefin of 88:12 - 98:2, a number average mol. wt. of 35,000 - 80,000 and a ratio of wt. number average mol wt. of 1.8:1 - 3.0:1 determined by GPC. It has good transparency and is moldable to a film which is heat-sealable at low temperature.

    摘要翻译: 乙烯(35-60摩尔)和C 3-10α-烯烃(65-40摩尔)在40至80℃的温度下与(a)氧化钒化合物的催化剂共聚合,(b)有机铝 化合物和(c)卤代烃酯,例如 (b)至(a)的摩尔比为> / = 2.5,(c)至(a)的摩尔比为> / = 1.5的全氯巴豆酸酯。 该聚合物的乙烯:α-烯烃的摩尔比为88:12-98:2,数均分子量。 重量。 为35,000〜80,000,重量比为 数均分子量 为1.8:1 - 3.0:1。 它具有良好的透明度,并且对于在低温下可热封的膜是可模塑的。