摘要:
Ethylene (35-60 mols) and a C 3-10 a-olefin (65-40 mols) are copolymerized at a temperature of 40 to 80°C with a catalyst of (a) an oxyvanadium compound, (b) an organoaluminium compound and (c) a halogenated hydrocarbon ester, e.g. a perchlorocrotonic acid ester, in a mol ratio of (b) to (a) of ≧ 2.5 and of (c) to (a) of ≧ 1.5, in a hydrocarbon solvent. The polymer has a molar ratio of ethylene: a-olefin of 88:12 - 98:2, a number average mol. wt. of 35,000 - 80,000 and a ratio of wt. number average mol wt. of 1.8:1 - 3.0:1 determined by GPC. It has good transparency and is moldable to a film which is heat-sealable at low temperature.
摘要:
A polypropylene laminated film containing a crystalline polypropylene layer and, laminated on at least one side of the layer of the crystalline polypropylene, a layer of a copolymer of propylene and at least one α-olefin of from 4 to 10 carbon atoms having a specific composition, melt flow rate and molecular weight distribution in which the α-olefin content in the cold xylene soluble portion of the random copolymer is less than 1.7 times the α-olefin content in the copolymer and the random copolymer satisfies the mathematical expression, B ≦ 1.05A - 10, wherein A is a weight percentage of the content of said at least one α-olefin having from 4 to 10 carbon atoms in the random copolymer and B is a weight percentage of the cold xylene soluble portion in the random copolymer, is superior in low temperature heat sealability and hot tack property and moreover has a good transparency, blocking resistance and printability, wherein the random copolymer is obtained by gas phase polymerization substantially in the absence of a liquid medium, and using a catalyst system comprising (i) a solid catalyst component containing magnesium, titanium and a halogen as essential constituents, (ii) an organoaluminum compound and (iii) an electron donative compound.
摘要:
Ethylene (35-60 mols) and a C 3-10 a-olefin (65-40 mols) are copolymerized at a temperature of 40 to 80°C with a catalyst of (a) an oxyvanadium compound, (b) an organoaluminium compound and (c) a halogenated hydrocarbon ester, e.g. a perchlorocrotonic acid ester, in a mol ratio of (b) to (a) of ≧ 2.5 and of (c) to (a) of ≧ 1.5, in a hydrocarbon solvent. The polymer has a molar ratio of ethylene: a-olefin of 88:12 - 98:2, a number average mol. wt. of 35,000 - 80,000 and a ratio of wt. number average mol wt. of 1.8:1 - 3.0:1 determined by GPC. It has good transparency and is moldable to a film which is heat-sealable at low temperature.
摘要:
A polypropylene composition which contains a polypropylene and one or more ingredients selected from an antistatic agent and a surface-treated or untreated fine powdery silica gives a propylene stretched film having a well-balanced transparency, slip property and blocking resistance.