摘要:
The present invention relates to a metallic salt, a method of preparing the metallic salt, and an electrolyte and electrochemical device each including the metallic salt. A metallic salt including at least one anion having a heterocyclic aromatic structure represented by one of Formulae 1 to 3; and a metallic cation:
wherein, in Formulae 1 to 3, each X is independently N, P, or As, one of A 1 and A 2 is an electron-donating group, and the other one is an electron-withdrawing group, ring Ar 1 and ring Ar 2 are as defined herein, L is a linker group as defined herein, m is an integer from 1 to 5, and n is an integer from 0 to 5.
摘要:
An all-solid battery including a cathode including a cathode active material layer; an anode including an anode current collector, and an interlayer disposed on the anode current collector; and a solid electrolyte layer disposed between the cathode and the anode, the solid electrolyte layer including a porous first surface facing the anode, and an opposite second surface, wherein the interlayer of the anode faces the solid electrolyte layer, and the interlayer includes a water-soluble first layer and a second layer disposed on the first layer, the second layer facing the anode current collector, wherein the first layer includes a first binder on at least a portion of the porous first surface of the solid electrolyte layer, and wherein the second layer includes an organic second binder.
摘要:
An electrolyte for a lithium air battery includes a branched quaternary ammonium compound represented by Formula 1
wherein the definitions of A and R 1 -R 10 are disclosed herein. Also a lithium air battery including an anode, a cathode, and at least one selected from the herein-described electrolyte and a reaction product thereof. The lithium air battery including the electrolyte has an improved stability.
摘要:
The present invention relates to an oxide, a preparation method thereof, a solid electrolyte including the oxide, and an electrochemical device including the oxide. The oxide includes a compound represented by Formula 1, a compound represented by Formula 2, or a combination thereof:
Formula 1 Li 1-x+y-z Ta 2-x M x P 1-y Q y O 8-z X z
wherein, in Formula 1, M is an element having an oxidation number of 5+ or 6+, Q is an element having an oxidation number of 4+, X is a halogen atom, a pseudohalogen, or a combination thereof, 0≤x
Formula 2 Li 1-x+y Ta 2-x M x P 1-y Q y O 8 ·zLiX
wherein, in Formula 2, M is an element having an oxidation number of 5+ or 6+, Q is an element having an oxidation number of 4+, X is a halogen atom, a pseudohalogen or a combination thereof, 0≤x
摘要:
The present invention relates to an all-solid secondary battery, and a method of manufacturing the all-solid secondary battery. An all-solid secondary battery including: a cathode layer including a cathode active material layer; an anode layer; and a solid electrolyte layer including a solid electrolyte, wherein the solid electrolyte layer is disposed between the cathode layer and the anode layer, wherein the anode layer includes an anode current collector, a first anode active material layer in contact with the solid electrolyte layer, and a second anode active material layer disposed between the anode current collector and the first anode active material layer, wherein the first anode active material layer includes a first carbonaceous anode active material, the second anode active material layer includes a second carbonaceous anode active material, and a first intensity ratio of an intensity of a D band peak to an intensity of a G band peak in a Raman spectrum of the first carbonaceous anode active material is less than a second intensity ratio of an intensity of a D band peak to an intensity of a G band peak in a Raman spectrum of the second carbonaceous anode active material.
摘要:
An electrolyte for a lithium air battery includes a branched quaternary ammonium compound represented by Formula 1 wherein the definitions of A and R 1 -R 10 are disclosed herein. Also a lithium air battery including an anode, a cathode, and at least one selected from the herein-described electrolyte and a reaction product thereof. The lithium air battery including the electrolyte has an improved stability.