摘要:
A process for efficiently producing at low cost a raw alloy for nanocomposite magnets which is mainly amorphous. The process comprises preparing a molten alloy represented by Fe¿100-x-y-z?RxQyMz (wherein R is at least one of praseodymium, neodymium, dysprosium, and terbium; Q is at least one of boron and carbon; M is at least one of cobalt, aluminum, silicon, titanium, vanadium, chromium, manganese, nickel, copper, gallium, zirconium, niobium, molybdenum, silver, platinum, gold, and lead; 1 ≤ x
摘要:
An iron-based rare-earth nanocomposite magnet according to the present invention includes an Nd 2 Fe 14 B phase and an α-Fe phase and has a composition represented by the compositional formula: T 100-x-y-z-n (B 1-q C q ) x R y Ti z M n , where T is at least one transition metal element selected from the group consisting of Fe, Co and Ni and always including Fe, R is at least one rare-earth element including substantially no La or Ce, and M is at least one metal element selected from the group consisting of Al, Si, V, Cr, Mn, Cu, Zn, Ga, Zr, Nb, Mo, Ag, Hf, Ta, W, Pt, Au and Pb, and the mole fractions x, y, z, n and q satisfy the inequalities of: 4 at%≦x≦10 at%, 6 at%≦y≦10 at%, 0.05 at%≦z≦5 at%, 0 at%≦n≦10 at%, and 0.05≦q≦0.5, respectively. The magnet includes 5 vol% to 60 vol% of α-Fe phase with an average crystal grain size of 1 nm to 50 nm and 40 vol% to 90 vol% of Nd 2 Fe 14 B phase with an average crystal grain size of 5 nm to 100 nm. A non-magnetic phase including at least Ti and C (carbon) is present on the grain boundary between the α-Fe and Nd 2 Fe 14 B phases.
摘要翻译:一种铁基稀土类纳米复合磁体雅丁到本发明包括的Nd 2 Fe 14 B相和在±-Fe相,并具有由组成式表示的组成:T 100-xyzn(B 1-中,Q c q)的 X RŸ钛Z M n,其中T是选自Fe,Co和Ni中始终包含的Fe中选择的至少一种过渡金属元素,R是实质上不含有La和Ce和的至少一种稀土类元素 M是选自铝,硅,钒,铬,锰,铜,锌,镓,锆,铌,钼,银,铪,钽,W,Pt,Au和铅中选出的至少一种金属元素,和 摩尔分数X,Y,Z,n和q分别满足的不等式:4在%‰| X‰| 10原子%,6在%‰|ý‰| 10原子%00:05在%‰|ž‰| 5 原子%,0原子%‰|ñ‰| 10原子%,和0.05‰‰| q | 0.5。 所述磁体包括±-Fe相的5体积%至60体积%在1纳米至50纳米和40体积%的平均晶粒尺寸为的Nd 2 Fe 14 B相的90%(体积)与5平均结晶粒径 纳米至100纳米。一种非磁性相包含至少Ti和C(碳)存在于±-Fe和Nd 2 Fe 14 B系相之间的晶界上。
摘要:
A nanocomposite magnet has a composition represented by (Fe1-mTm) 100-x-y-z-n QxRyTizMn, where T is at least one of Co and Ni, Q is at least one of B and C, R is at least one rare earth element that always includes at least one of Nd and Pr and optionally includes Dy and/or Tb, and M is at least one element selected from the group consisting of Al, Si, V, Cr, Mn, Cu, Zn, Ga, Zr, Nb, Mo, Ag, Hf, Ta, W, Pt, Au and Pb. The mole fractions x, y, z, m and n satisfy 10 at%
摘要:
A method for producing an iron base rare earth alloy nanocomposite magnet powder, which comprises quenching by the atomizing method a molten alloy having the empirical formula represented by (Fe1-mTm)100-x-y-zQxRyTizMn , wherein T represents one or more elements selected from the group consisting of Co and Ni, Q represents at least one element selected from the group consisting of B and C, R represents at least one element selected from the group consisting of the rare earth elements and yttrium, M represents at least one element selected from the group consisting of Nb, Zr, Mo, Ta and Hf, and numbers x, y, z, m and n concerning a composition proportion satisfy 10
摘要:
A method of easily producing a permanent magnet having magnetic characteristics better than those of bonded magnets, capable of assuming arbitrary thickness and shape, and suitable for use in a magnetic circuit for an acceleration sensor or the like. The method comprises quenching an alloy melt of a specific composition containing not more than 6 at% of a rare earth element and 15 to 30 at% of boron under specific melt-quenching conditions to make a quenched thin amorphous alloy belt having an average thickness of 10 to 200 mu m, cutting or punching the quenched thin alloy band, and subjecting the belt to heat-treatment to crystallize the structure so that the mean grain size may be 10 to 50 nm, thereby to produce a permanent magnet having the above-mentioned average thickness and hard magnetic characteristics of iHc >/= 2 kOe and Br >/= 8 kG. Two or more such thin magnets are stacked and bonded together with an inorganic adhesive to produce a laminated permanent magnet having arbitrary thickness and shape, and exhibiting high performance without the need of cutting.
摘要:
To make a raw alloy, consisting mostly of amorphous structure, highly productively and at a reduced cost for a nanocomposite magnet, a molten alloy represented by Fe 100-x-y-z R x Q y M z (where R is at least one element selected from Pr, Nd, Dy and Tb; Q is B and/or C; M is at least one element selected from Co, Al, Si, Ti, V, Cr, Mn, Ni, Cu, Ga, Zr, Nb, Mo, Ag, Pt, Au and Pb; and 1 at%≦x
摘要翻译:为了制造主要由无定形结构组成的原料合金,以高成本且成本低廉的纳米复合磁体,以Fe100-xy-zRxQyMz(其中R为选自Pr,Nd,Dy和 Tb; Q为B和/或C; M为选自Co,Al,Si,Ti,V,Cr,Mn,Ni,Cu,Ga,Zr,Nb,Mo,Ag,Pt,Au和 Pb;和1原子%x <6原子%,15原子%,y = 30原子%,0原子%z = 7原子%)。 该熔融合金通过带钢铸造工艺快速冷却,其中将合金进料到冷却辊上,以3m / s的圆周速度旋转至小于20m / s,以每单位接触宽度0.2的进料速率 kg / min / cm〜5.2kg / min / cm。 以这种方式,可以获得包含至少60体积%的非晶相的合金。