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1.发明公开
公开(公告)号：EP3119856A1
公开(公告)日：2017-01-25
申请号：EP15709702.3
申请日：2015-03-16
CPC分类号： C10G2/332 , B01J8/001 , B01J8/02 , B01J8/065 , B01J8/067 , B01J23/75 , B01J23/94 , B01J37/18 , B01J2208/00061 , B01J2208/00628 , B01J2208/00646 , B01J2208/00716 , B01J2219/002 , B01J2219/00213 , B01J2219/00231 , C07C1/04 , C07C1/045 , C07C1/0455 , C07C1/047 , C07C1/048 , C10G2/341
摘要： The invention relates to a method for start-up and operation of a Fischer-Tropsch reactor comprising the steps of: (a) providing a reactor with a fixed bed of reduced Fischer-Tropsch catalyst that comprises cobalt as catalytically active metal; (b) supplying a gaseous feed stream comprising carbon monoxide and hydrogen to the reactor, wherein the gaseous feed stream initially comprises a nitrogen-containing compound other than molecular nitrogen in an initial concentration in the range of from 0.1 to 50 ppmv based on the volume of the gaseous feed stream; (c) converting carbon monoxide and hydrogen supplied with the gaseous feed stream to the reactor into hydrocarbons at an initial reaction temperature, wherein the initial reaction temperature is set at a value of at least 200 °C and hydrocarbons are produced at a first yield; (d) maintaining the initial reaction temperature at the set value and maintaining the first yield by decreasing the concentration of the nitrogen-containing compound in the gaseous feed stream supplied to the reactor; (e) optionally increasing the reaction temperature after the concentration of the nitrogen-containing compound in the gaseous feed stream has decreased to a value below 100 ppbv.
摘要翻译： 本发明涉及用于启动和操作费 - 托反应器的方法，其包括以下步骤：（a）提供具有包含钴作为催化活性金属的还原费 - 托催化剂固定床的反应器; （b）将包含一氧化碳和氢气的气态进料流供应到反应器中，其中气态进料流最初包含除分子氮之外的初始浓度范围为0.1-50ppmv的含氮化合物，基于体积 的气体进料流; （c）在初始反应温度下将随气态进料流供应的一氧化碳和氢气转化成烃，其中初始反应温度设定在至少200℃的值，并以第一产率生产烃; （d）将初始反应温度保持在设定值并通过降低供给反应器的气体进料流中含氮化合物的浓度来保持第一收率; （e）在气体进料流中含氮化合物的浓度已经降低至低于100ppbv的值之后，任选地增加反应温度。
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公开(公告)号：EP3119517A1
公开(公告)日：2017-01-25
申请号：EP15710527.1
申请日：2015-03-19
发明人： CHETTOUF, Abderrahmane , DEN BREEJEN, Johan Peter , DOGTEROM, Ronald Jan , FLEYS, Matthieu Simon Henri
IPC分类号： B01J23/75 , B01J23/34 , B01J35/04 , B01J35/02 , F01N3/28 , C04B38/00 , C07C1/04 , C10G2/00 , B29C67/00 , B22F3/00
CPC分类号： B01J23/75 , B01J21/04 , B01J21/063 , B01J23/34 , B01J35/026 , B01J35/04 , B01J35/1028 , B01J37/0244 , B22F3/1055 , B22F3/24 , B22F5/10 , B29C64/124 , B29C64/153 , B33Y80/00 , C10G2/32 , C10G2/332 , C10G2/333 , C10G2/341 , F01N3/281 , Y02P10/295
摘要： The Fischer-Tropsch process can be used for the conversion of hydrocarbonaceous feed stocks into normally liquid and/or solid hydrocarbons. The feed stock (e.g. natural gas, associated gas and/or coal-bed methane, coal) is converted in a first step into a mixture of hydrogen and carbon monoxide (this mixture is often referred to as synthesis gas or syngas). The synthesis gas (or syngas) is then converted in one or more steps over a suitable catalyst at elevated temperature and pressure into paraffinic compounds ranging from methane to high molecular weight molecules comprising up to 200 carbon atoms, or, under particular circumstances, even more. The present invention relates to a catalyst, a method for manufacturing said catalyst. The present invention further relates to a catalyst obtainable by said method. The present invention further relates to a multi tubular reactor comprising said catalyst.
摘要翻译： 费 - 托法可用于将含烃原料转化成通常的液体和/或固体烃。 原料（例如天然气，伴生气和/或煤层气，煤）在第一步转化为氢和一氧化碳的混合物（该混合物通常被称为合成气或合成气）。 然后将合成气（或合成气）在一个或多个步骤中在合适的催化剂上在升高的温度和压力下转化成从包含至多200个碳原子的甲烷到高分子量分子的链烷烃化合物，或者在特定情况下甚至更多 。 本发明涉及催化剂，所述催化剂的制造方法。 本发明还涉及可通过所述方法获得的催化剂。 本发明还涉及包含所述催化剂的多管式反应器。
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公开(公告)号：EP4121205A1
公开(公告)日：2023-01-25
申请号：EP21710987.5
申请日：2021-03-15
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公开(公告)号：EP4243982A1
公开(公告)日：2023-09-20
申请号：EP21801575.8
申请日：2021-11-11
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