Polypropylene resin composition
    9.
    发明公开
    Polypropylene resin composition 审中-公开
    聚丙烯树脂组合物

    公开(公告)号:EP0926195A1

    公开(公告)日:1999-06-30

    申请号:EP98124590.5

    申请日:1998-12-23

    IPC分类号: C08L53/02 C08L53/00 C08K3/34

    摘要: This invention provides polypropylene resin compositions exhibiting a strongly improved balance of physical properties in comparison to related polypropylene materials. The materials can be used in both interior and exterior parts of automobiles, have excellent thin-wall moldability and can effectively reduce generation of flow marks. Particularly, it provides a polypropylene resin composition which comprises specified amounts of (A) a specific ethylene-propylene block copolymer, (B) a specific thermoplastic elastomer and (C) talc, wherein it has specified values of physical properties measured by ASTM and has a degree of b-axis orientation of 720 or more which is calculated from the ratio of differential peak intensities measured by wide-angle X-ray diffraction of the central area of an ASTM No. 1 dumbbell prepared by injection molding.

    摘要翻译: 与有关的聚丙烯材料相比,本发明提供了聚丙烯树脂组合物,其物理性能的平衡显着改善。 该材料可用于汽车内外部件,具有优异的薄壁成型性,可有效减少流痕的产生。 特别是提供含有特定量的(A)特定的乙烯 - 丙烯嵌段共聚物,(B)特定的热塑性弹性体和(C)滑石的聚丙烯树脂组合物,其特征在于, 根据通过注射成型制备的ASTM 1号哑铃的中心区域的广角X射线衍射测量的差分峰值强度的比率计算720或更高的b轴取向度。

    Thermoplastic resin composition improved in terms of prevention of mold contamination
    10.
    发明公开

    公开(公告)号:EP0791630A1

    公开(公告)日:1997-08-27

    申请号:EP97301120.8

    申请日:1997-02-21

    摘要: A thermoplastic resin composition improved in terms of prevention of mold contamination, comprising the following components (A) to (G):

    component (A): 55 to 75% by weight of a propylene-ethylene block copolymer including a propylene homopolymer moiety having a melt flow rate of 15 to 50 g/10 min. and an isotactic pentad fraction of at least 0.97, said block copolymer having a melt flow rate of 10 to 30 g/10 min. and an ethylene content of 2 to 6% by weight,
    component (B): 0 to 10% by weight of an ethylene-propylene copolymer rubber having a melting temperature of 30 to 60°C and a melt flow rate of 0.2 to 2 g/10 min.,
    component (C): 5 to 15% by weight of an ethylene-α-olefin copolymer rubber having a melting temperature of 60 to 100°C and a melt flow rate of 0.3 to 2 g/10 min.,
    component (D): 15 to 25% by weight of a talc having an average particle diameter of up to 5 µm and a specific surface area of at least 3.5 m 2 /g,
    the total amount of components (A) to (D) being 100% by weight,
    component (E): 0.05 to 2 parts by weight of a hindered amine having a structure represented by the following formula (I):

    component (F): 0.01 to 1 part by weight of a triaryl phosphite, and
    component (G): 0.05 to 4 parts by weight of a metal salt represented by the following general formula (VIII):

            (RCOO) 2 X     (VIII)

    wherein R is a monovalent hydrocarbon group having a molecular weight of 290 to 500, and X is zinc, magnesium or calcium,
    the respective amounts of components (E) to (G) being based on 100 parts by weight of the sum of components (A) to (D).

    摘要翻译: 含有以下组分(A)至(G)的组分(A):55至75重量%的包含丙烯均聚物部分的丙烯 - 乙烯嵌段共聚物,其具有 熔体流动速率为15〜50g / 10min。 并且全同立构五单元组分数至少为0.97,所述嵌段共聚物的熔体流动速率为10至30g / 10min。 乙烯含量为2〜6重量%,成分(B):0〜10重量%的熔融温度为30〜60℃,熔体流动速率为0.2〜2g的乙烯 - 丙烯共聚物橡胶 / 10分钟,成分(C):5〜15重量%的熔融温度为60〜100℃,熔体流动速率为0.3〜2g / 10分钟的乙烯-α-烯烃共聚物橡胶, 成分(D):15〜25重量%的平均粒径为5μm以下,比表面积为3.5m 2 / g以上的滑石,成分(A)〜 (D)为100重量%,成分(E):0.05〜2重量份具有下述式(I)所示结构的受阻胺:成分(F):0.01〜1重量份 的亚磷酸三芳酯和组分(G):0.05至4重量份由以下通式(VIII)表示的金属盐:(RCOO)2 X其中R是分子量为290至500的一价烃基 , X为锌,镁或钙,组分(E)至(G)的相应量基于组分(A)至(D)的总和的100重量份。