公开(公告)号：EP1320569B1

公开(公告)日：2007-04-18

申请号：EP01965275.9

申请日：2001-09-12

申请人： Société de Technologie Michelin ,  MICHELIN Recherche et Technique S.A.

发明人： BELIN, Laure ,  BLANCHARD, Christiane ,  PAGANO, Salvatore ,  THONIER, Christel

IPC分类号： C08K5/544 ,  C08L9/00 ,  B60C1/00

CPC分类号： C08K5/5442 ,  B60C1/0016 ,  C08K3/013 ,  C08L9/00

摘要： The invention concerns an elastomeric composition based on at least an isoprene elastomer, a reinforcing inorganic filler and, as coupling agent (inorganic filler/isoprene elastomer), a citraconimido-alkoxysilane, in particular a N-[(alkyl(C1-C3)-alkoxy(C1-C3)silyl)]-citracominide. The isoprene elastomer is in particular natural rubber and the reinforcing inorganic filler is a siliceous or aluminous filler of the highly dispersible type. The invention also concerns a method for preparing such a composition. The invention further concerns the use of said composition for making tyres or semi-finished products for tyres, in particular running treads for heavy vehicle tyres.

公开(公告)号：EP1499671A1

公开(公告)日：2005-01-26

申请号：EP03725031.3

申请日：2003-04-15

申请人： Société de Technologie Michelin ,  MICHELIN RECHERCHE ET TECHNIQUE S.A.

发明人： BELIN, Laure ,  PAGANO, Salvatore ,  ROY, Vanessa

IPC分类号： C08K5/549 ,  C08F36/04 ,  B60C1/00

CPC分类号： C08K5/548 ,  B60C1/00 ,  B60C1/0008 ,  B60C1/0016 ,  B60C1/0025 ,  B60C5/02 ,  B60C5/16 ,  B60C2015/0614 ,  C08F36/04 ,  C08K5/549 ,  C08L21/00

摘要： A rubber composition based on at least one diene elastomer, a reinforcing agent and a polysulphide siloxane corresponding to general formal (I) wherein the number x, either as a proper number or improper number, is equal to or greater than 2; the radicals Z, are identical or different, and are divalent bonding groups preferably comprising 1-18 carbon atoms; the radicals R, are identical or different, and are hydrocarbon groups preferably comprising 1-18 carbon atoms. The inventive composition can be used in the production of a finished good or a semi-finished good for an automotive vehicle ground link such as a tyre

摘要翻译： 基于至少一种二烯弹性体，增强剂和对应于通式（I）的多硫化物硅氧烷的橡胶组合物，其中x为适当数目或不适当数目，等于或大于2; 基团Z相同或不同，并且是优选包含1-18个碳原子的二价键合基​​团; 基团R 1相同或不同，并且是优选包含1-18个碳原子的烃基。 本发明的组合物可用于制造汽车车辆地面连接件如轮胎的成品或半成品

公开(公告)号：EP2379633A1

公开(公告)日：2011-10-26

申请号：EP09795434.1

申请日：2009-12-18

申请人： Société de Technologie MICHELIN ,  MICHELIN Recherche et Technique S.A.

发明人： BELIN, Laure ,  LONGCHAMBON, Karine ,  ARAUJO DA SILVA, José, Carlos

IPC分类号： C08K5/548

CPC分类号： C08K3/0033 ,  B60C1/0016 ,  C08K3/013 ,  C08K5/548 ,  Y10T152/10819 ,  C08L21/00

摘要： The invention relates to a rubber composition free of zinc or containing less than 0.5 pce of zinc, which can be used for manufacturing tyres, made of at least: a dienic elastomer; a sulphur-based cross-linking system; an inorganic filler as a reinforcing filler; a blocked mercaptosilane with the following general formula (I): (R
3 O) R
2 R
1 -Si - Z- S -C (=O) - A, where: R
1 and R
2 , identical or different, are a monovalent hydrocarbon group selected from among linear or branched alkyls, cycloalkyls or aryls, having 1 to 18 carbon atoms; R
3 is a monovalent hydrocarbon group selected from among linear or branched alkyls, having 1 to 4 carbon atoms; A is hydrogen or a monovalent hydrocarbon group selected from among linear or branched alkyls, cycloalkyls or aryls, having 1 to 18 carbon atoms; and Z is a divalent bonding group comprising 1 to 18 carbon atoms.

公开(公告)号：EP2212379A2

公开(公告)日：2010-08-04

申请号：EP08848650.1

申请日：2008-11-14

申请人： Société de Technologie MICHELIN ,  MICHELIN Recherche et Technique S.A.

发明人： ARAUJO DA SILVA, José, Carlos ,  BELIN, Laure ,  LONGCHAMBON, Karine ,  SEEBOTH, Nicolas

IPC分类号： C08L21/00 ,  C08K9/06 ,  C08K5/54

CPC分类号： C08K5/5419 ,  B60C1/0016 ,  C08K9/06 ,  C08L21/00

摘要： The invention relates to a rubber composition that can especially be used for producing tyres or semi-finished products for tyres such as tyre treads, said composition being based on at least one dienic elastomer, a reinforcing inorganic load, a coupling agent and a hydroxysilane of formula (I) : R1 (R2)n Si (OH)3-n wherein n is equal to 0, 1 or 2; R1 is a hydrocarbonated group comprising at least 4 carbon atoms; and R2 is an alkyl comprising between 1 and 4 carbon atoms, the R2 alkyls being the same or different if n is equal to 2.

摘要翻译： 本发明涉及一种橡胶组合物，其特别可以用于生产轮胎如轮胎胎面的轮胎或半成品，所述组合物基于至少一种二烯弹性体，增强无机负载，偶联剂和 式（I）：R 1（R 2）n Si（OH）3-n其中n等于0,1或2; R1是含有至少4个碳原子的烃化基团; 并且R 2是包含1至4个碳原子的烷基，如果n等于2，则R 2烷基相同或不同。

公开(公告)号：EP1664180A1

公开(公告)日：2006-06-07

申请号：EP04765167.4

申请日：2004-09-14

申请人： Société de Technologie Michelin ,  MICHELIN RECHERCHE ET TECHNIQUE S.A.

发明人： ARAUJO DA SILVA, José, Carlos ,  BELIN, Laure ,  BLANCHARD, Christiane

IPC分类号： C08K5/3415 ,  C08L21/00

CPC分类号： B60C1/00 ,  C08K5/3415 ,  C08L21/00

摘要： The invention relates to a rubber composition which can be used for the production of tyres. The inventive composition is based on at least one diene elastomer, a reinforcing filler, a curing system and, by way of an anti-reversion agent, a citraconimido-maleimide composition having formula (I) (R hydrocarbon radical). The invention also relates to the use of one such composition for the production of a finished or semi-finished product which is made from rubber and which is intended for a motor vehicle road-holding system, in particular a tyre.

公开(公告)号：EP2379568A1

公开(公告)日：2011-10-26

申请号：EP09797037.0

申请日：2009-12-18

申请人： Société de Technologie MICHELIN ,  MICHELIN Recherche et Technique S.A.

发明人： SEEBOTH, Nicolas ,  LONGCHAMBON, Karine ,  BELIN, Laure ,  ARAUJO DA SILVA, José Carlos

IPC分类号： C07F7/18 ,  C08K3/36

CPC分类号： C07F7/184

摘要： The invention relates to a blocked mercaptosilane with the following general formula (I): (HO)
2 R
1 - Si - Z - S - C (= O) - A, where: R
1 is a monovalent hydrocarbon group selected from among linear or branched alkyls, cycloalkyls or aryls, having 1 to 18 carbon atoms; A is hydrogen or a monovalent hydrocarbon group selected from among linear or branched alkyls, cycloalkyls or aryls, having 1 to 18 carbon atoms; Z is a divalent bonding group comprising 1 to 18 carbon atoms.

摘要翻译： 本发明涉及具有以下通式（I）的封端巯基硅烷：其中：R 1是选自以下通式（I）的一价烃基： 或具有1至18个碳原子的支化烷基，环烷基或芳基; A是氢或选自具有1-18个碳原子的直链或支链烷基，环烷基或芳基的一价烃基; Z是包含1至18个碳原子的二价键合基​​团。

公开(公告)号：EP1326871B1

公开(公告)日：2006-02-01

申请号：EP01986691.2

申请日：2001-10-09

申请人： Société de Technologie Michelin ,  MICHELIN RECHERCHE ET TECHNIQUE S.A.

发明人： TARDIVAT, Jean-Claude ,  BELIN, Laure ,  BLANCHARD, Christine

IPC分类号： C07F7/08 ,  C08K5/31 ,  C08K5/548

CPC分类号： C07F7/0836 ,  C08K5/548 ,  C08L21/00

摘要： The invention concerns monohydroxysilane polysulphide, of formula (F) wherein: the radicals R, identical or different, are hydrocarbon groups comprising preferably 1 to 15 carbon atoms; the radicals R', identical or different, are divalent binding groups preferably comprising 1 to 18 carbon atoms; x is not less than 2. Said hydroxysilane is in particular a bis(propyldimethylsilanol) sulphide. The method for obtaining said hydroxysilane consists in subjecting to alcoholysis and/or hydrolysis a halogenated organosilane, followed by a sulphidizing step. The invention also concerns the use of said hydroxysilane as coupling agent.

公开(公告)号：EP1499669B1

公开(公告)日：2006-01-11

申请号：EP03725030.5

申请日：2003-04-15

申请人： Société de Technologie Michelin ,  MICHELIN RECHERCHE ET TECHNIQUE S.A.

发明人： BELIN, Laure ,  BLANCHARD, Christiane

IPC分类号： C08K5/00 ,  C08J3/00 ,  C08L9/00 ,  C07F7/08

CPC分类号： C07F7/0843 ,  C08K5/548 ,  C08K5/549 ,  C08L21/00

摘要： The invention relates to polysulphide siloxanes of general formula (I), where x = a whole or fractional number equal to or greater than 2, Z, independently = divalent linking groups and R independently = hydrocarbon groups. The invention further relates to use of said compound as cross-linking agent for diene elastomers, particularly in a rubber compound for tyres.

公开(公告)号：EP2379634A1

公开(公告)日：2011-10-26

申请号：EP09796714.5

申请日：2009-12-18

申请人： Société de Technologie MICHELIN ,  MICHELIN Recherche et Technique S.A.

发明人： CAMBON, Stéphanie ,  LONGCHAMBON, Karine ,  ARAUJO DA SILVA, José, Carlos ,  BELIN, Laure

IPC分类号： C08K5/548

CPC分类号： C08K5/548 ,  B60C1/0016 ,  C08K3/013 ,  C08L21/00

摘要： The invention relates to a rubber compound containing no or less than 0.5 phr zinc, which can be used for the manufacture of tyres, the compound being based on at least: a diene elastomer; a sulphur-based crosslinking system; an inorganic filler as reinforcing filler; and a blocked mercaptosilane of the following general formula (I) in which formula (I): R
1 which are the same or different, each represent a monovalent hydrocarbon group chosen from alkyls, whether linear or branched, cycloalkyls or aryls, having 1 to 18 carbon atoms; A represents hydrogen or a monovalent hydrocarbon group chosen from alkyls, whether linear or branched, cycloalkyls or aryls, having 1 to 18 carbon atoms; Z represents a divalently bonded group having 1 to 18 carbon atoms; and n is an integer equal to 0, 1 or 2.

公开(公告)号：EP1863871B1

公开(公告)日：2009-08-12

申请号：EP06723456.7

申请日：2006-03-15

申请人： Société de Technologie Michelin ,  Michelin Recherche et Technique S.A.

发明人： BELIN, Laure ,  GANDON-PAIN, Sylvie ,  ARAUJO DA SILVA, José Carlos ,  LAFFARGUE, Géraldine

IPC分类号： C08K5/3415 ,  B60C1/00 ,  C07D207/44 ,  C07D403/10

CPC分类号： C07D207/452 ,  B60C1/00 ,  C08K5/3415 ,  C08L21/00

摘要： The invention relates to a rubber composition which can be used for the production of tyres. The inventive composition is based on at least one diene elastomer, a reinforcing filler, a curing system and, by way of an anti-reversion agent, an itaconimido-maleimide composition having formula (I) (R hydrocarbon radical). The invention also relates to the use of one such composition for the production of a finished or semi-finished product which is made from rubber and which is intended for a motor vehicle road-holding system, in particular a tyre.