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1.发明公开
公开(公告)号：EP1278789A1
公开(公告)日：2003-01-29
申请号：EP01936266.4
申请日：2001-04-23
IPC分类号： C08F297/02 , C08L53/00 , B60C1/00
CPC分类号： C08L53/00 , B60C1/0016 , C08F297/02 , Y02T10/862 , Y10T152/1081
摘要： The invention concerns block copolymers for forming an elastomer matrix of a crosslinkable rubber composition with reduced hysteresis, said rubber composition which is useable in crosslinked state in a tyre running tread, said running tread and the tyre comprising it exhibits reduced running resistance. The inventive copolymer with n blocks (n = 2 or 3), each of the blocks comprising a diene elastomer whereof the mol ratio of units derived from conjugated dienes is higher than 15 %, and one of said blocks forming a chain end of said copolymer consisting of a polyisoprene, respectively for n = 2 or n = 3, is such that: the mean mole weight Mn1 of said or each end polyisoprene block substantially ranges between 2500 and 20000 g/mol and the mean mole weight Mn2 of said copolymer block which is different from said or each end polyisoprene block ranges substantially between 80000 g/mol and 350000 g/mol.
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公开(公告)号：EP1204702A1
公开(公告)日：2002-05-15
申请号：EP01936381.1
申请日：2001-05-21
CPC分类号： C08L9/06 , B60C1/0016 , C08C19/26 , C08K3/013 , C08K3/36 , C08L19/006 , Y02T10/862 , C08L13/00 , C08L2666/08
摘要： The invention concerns a crosslinkable or crosslinked rubber composition having improved hysteretic properties when crosslinked useful for producing a tyre running tread, a method for preparing such a crosslinkable composition, such a running tread and a tyre exhibiting reduced rolling resistance. The inventive rubber composition is based on an elastomer matrix comprising at least a diene elastomer including a carboxylic acid function at one or at each of its two chain ends, and a reinforcing filler including an inorganic reinforcing filler, and is such that said diene elastomer has a mole weight higher than 80000 g/mol and it is present in major amount in said elastomer matrix.
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3.发明公开COMPOSITION POUR BANDE DE ROULEMENT DE PNEUMATIQUE ET SON PROCEDE DE PREPARATION 审中-公开轮胎胎面组合物和方法及其生产
公开(公告)号：EP1290083A1
公开(公告)日：2003-03-12
申请号：EP01943417.4
申请日：2001-05-21
CPC分类号： C08K3/36 , B60C1/0016 , C08C19/26 , C08C19/42 , C08L13/00 , Y02T10/862 , C08L13/02 , C08L2666/08
摘要： The invention concerns a crosslinkable or crosslinked rubber composition having improved hysteretic properties when crosslinked which is useful for forming a tyre running tread, a method for preparing said crosslinkable composition, such a running tread and a tyre having reduced rolling resistance. Said composition is characterised in that it consists of: at least a diene elastomer having a mol ratio of units derived from conjugate dienes higher than 30 % and comprising carboxylic acid functions along its chain, and a reinforcing inorganic filler.
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4.发明公开
公开(公告)号：EP1448647A2
公开(公告)日：2004-08-25
申请号：EP02783065.2
申请日：2002-10-31
IPC分类号： C08F297/02 , C08F297/04 , C08L53/00 , C08L53/02 , C08F36/04 , B60C1/00
CPC分类号： C08F297/046 , C08F297/02 , C08L53/00 , C08L53/02 , Y10S152/905
摘要： The invention relates to: a method of preparing a two-block copolymer which can be used in a sulphur-crosslinkable rubber composition having reduced hysterises in the crosslinked state; one such block copolymer in which one of the blocks comprises a polyisoprene and the other block comprises a diene elastomer other than polyisoprene; and said rubber composition which is intended for tyre treads. The inventive method of preparing said copolymer consists in copolymerising one or more monomers comprising a conjugated diene other than isoprene using a catalytic system containing: at least one hydrocarbon solvent; a compound A of a metal from group IIIA; a compound B of an alkaline-earth metal; and a polymer initiator C comprising a bond C-Li which is formed by a monolithiated polyisoprene that is intended to form said polyisoprene block, the number-average molecular weight Mn1 of said polyisoprene block having a value of between 2 500 and 20 000 g/mol. In this way, said method can be used to obtain the aforementioned copolymer in which the other block comprising the diene elastomer has a number-average molecular weight Mn2 of between 65 000 and 350 000 g/mol and a 1,4-trans chaining content that is equal to or greater than 70 %.
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5.发明授权COMPOSITION DE CAOUTCHOUC CONTENANT UN ELASTOMERE MODIFIE, SON PROCEDE DE PREPARATION ET PNEUMATIQUE LA CONTENANT 有权与改性弹性体，生产工艺THEREFOR和轮胎SO橡胶组合物
公开(公告)号：EP2593486B1
公开(公告)日：2016-03-23
申请号：EP11730681.1
申请日：2011-07-12
CPC分类号： C08L9/06 , B60C1/0016 , C08C19/22 , C08C19/28 , C08K3/36 , C08K5/32 , C08K5/3445 , C08K5/548 , Y02T10/862
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公开(公告)号：EP2547728B1
公开(公告)日：2014-07-02
申请号：EP11708261.0
申请日：2011-03-15
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7.发明公开PROCÉDÉ DE PRÉPARATION D'UN COPOLYMÈRE DIÉNIQUE À BLOC POLYÉTHER, COPOLYMÈRE DIÉNIQUE À BLOC POLYÉTHER, COMPOSITION DE CAOUTCHOUC RENFORCÉE ET PNEUMATIQUE 有权PROCESS用于产生具有与聚醚的聚醚嵌段共轭二烯共聚物的二烯共聚物，补强橡胶组合物和轮胎
公开(公告)号：EP2173789A1
公开(公告)日：2010-04-14
申请号：EP08761237.0
申请日：2008-06-19
IPC分类号： C08G81/02 , C08G65/336 , C08L53/02 , B60C1/00
CPC分类号： C08F297/02 , B60C1/0016 , C08C19/44 , C08F297/04 , C08F297/044 , C08G65/336 , C08G65/337 , C08G81/025 , C08K3/013 , C08L53/00 , C08L53/005 , C08L53/02 , C08L53/025 , C08L71/02 , C08L2205/05 , C08L2666/02 , C08L2666/04 , C08L2666/24 , C08L15/00
摘要： A process for preparing a functionalized or unfunctionalized diene block copolymer comprising at least one polyether block of number-average molecular weight approximately from 150 to 5000 g/mol linked to at least one block constituted of a diene elastomer via at least one silicon atom. The process allows a high degree of grafting of the polyether to the polymer chains. Also disclosed is a reinforced rubber composition, especially intended for the manufacture of tires, comprising such a diene block copolymer which is intended to interact with the reinforcing filler. Such a rubber composition has improved hysteresis properties in the vulcanized state, while retaining satisfactory processing properties in the non-vulcanized state.
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公开(公告)号：EP1730229B1
公开(公告)日：2008-09-03
申请号：EP05715288.6
申请日：2005-02-10
发明人： BRUNELET, Thierry , DINH, Martine , FAVROT, Jean-Michel , LABRUNIE, Philippe , LOPITAUX, Garance , ROYET, Jean-Gabriel
CPC分类号： C08K5/0008 , B60C1/00 , C08K3/013 , C08K5/01 , C08L21/00 , C08L47/00 , C08L2666/04
摘要： The inventive plasticising system is used for plasticising a dienic rubber compound is characterised in that it is based on a MES or TDAE oil and a polylimonene resin. Said rubber compound exhibits an improved abrasion and cut resistance and is based on at least one type of dienic elastomer, a reinforcing filler, a cross-linking system and a plasticising system comprising from 5 to 35 pce of the MES or TDAE oil and from 5 to 35 pce of polylimonene resin (pce=parts by weight per cent elastomer). Advantageously, said plasticising system also comprises a glycerol unsaturated fatty acid triester (C12-C22), preferably a glycerol trioleate. The inventive method for producing said compound, using the compound for producing a final or semi-final product for the gripping system of a motor vehicle with ground, in particular the tire or the thread thereof are also disclosed.
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9.发明公开ELASTOMÈRE DIÉNIQUE À IP FAIBLE FONCTIONNEL À FLUAGE À FROID AMÉLIORÉ ET COMPOSITION DE CAOUTCHOUC LE CONTENANT 有权功能DIEN弹性体低PI和改进冷流动性和橡胶组合物含
公开(公告)号：EP2643406A1
公开(公告)日：2013-10-02
申请号：EP11785442.2
申请日：2011-11-23
发明人： ABAD, Mathilde , DORATO, Margarita , FAVROT, Jean-Michel , SIMON, Nathalie , MARECHAL, Jean Marc , DE LANDTSHEER, Stéphanie
CPC分类号： C08L9/00 , C08C19/26 , C08C19/44 , C08L9/06 , C08L15/00 , C08L2666/08 , C08L2666/02
摘要： The invention relates to a functionalised diene elastomer consisting of a) a diene elastomer functionalised at the end of the chain or in the middle of the chain by a tin function, having a monomodal molecular mass distribution before functionalisation and a polydispersity index that is less than or equal to 1.3 before functionalisation, b) a diene elastomer that is star-branched with a tin compound and has a monomodal mass distribution before star formation and a polydispersity index that is less than or equal to 1.3 before star formation, and c) a non-functional tin diene elastomer at a rate of less than 15 weight % in relation to the total weight of the functionalised diene elastomer. Said diene elastomers a), b), and c) have the same nature before any functionalisation or star formation.
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10.发明公开ELASTOMÈRE DIÉNIQUE À BLOC POUR DES COMPOSITIONS DE CAOUTCHOUC UTILISABLES POUR DES PNEUMATIQUES 有权BLOCKDIENELASTOMERFÜRKAUTSCHUKZUSAMMENSETZUNGEN ZUR VERWENDUNGFÜRLUFTREIFEN
公开(公告)号：EP2643358A1
公开(公告)日：2013-10-02
申请号：EP11788125.0
申请日：2011-11-23
IPC分类号： C08C19/26 , C08C19/42 , C08C19/44 , C08F297/02 , C08L53/00
CPC分类号： C08F299/00 , B60C1/00 , C08C19/26 , C08C19/42 , C08C19/44 , C08F297/02 , C08F297/04 , C08L53/005 , C08L53/02
摘要： The invention relates to a block diene elastomer having the following formula: (I) where: n and m are each integers greater than or equal to 0, such that n+m≥1 and n+m ≤20; each block A consists of a polybutadiene; each block B consists of a diene elastomer, the molar level of units derived from conjugate dienes of which is greater than 15%, the blocks B being identical to one another; X is an organic or inorganic group, which can contain a function interacting with a reinforcing filler; the number-average molecular weight Mn1 of each Block A varies from 2500 to 20,000 g/mol; the number-average molecular weight Mn2 of each block B varies from 80,000 to 350,000 g/mol; and the chaining rate 1,2 in each block A is comprised between 1 and 20%.
摘要翻译： 本发明涉及对应于下式的嵌段二烯弹性体：其中：n和m各自为大于或等于0的整数，使得n +m≥1和n + m＆nlE; 20，每个A嵌段组成 的聚丁二烯，每个B嵌段由二烯弹性体组成，由共轭二烯衍生的单元的摩尔含量大于15％，B嵌段彼此相同，X是可以包含有机或无机基团 与增强填料相互作用的官能团，每个A嵌段的数均分子量Mn1为2500〜20000g / mol，每个B嵌段的数均分子量Mn2为80000〜350000 g / mol，每个A嵌段中1,2-键的含量为1〜20％。
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