公开(公告)号：EP2173731B1

公开(公告)日：2011-10-26

申请号：EP08778059.9

申请日：2008-07-04

Applicant: Sumitomo Chemical Company, Limited

Inventor： MIZUNO, Masahiko ,  NARAHARA, Hideo

IPC: C07D301/12 ,  C07D303/04

CPC classification number: C07D301/12

Abstract: A method is for producing propylene oxide, the method including the steps of: reacting hydrogen peroxide with propylene either in an acetonitrile solvent or in a mixture of solvents which include acetonitrile and water, in presence of a titanosilicate catalyst, whereby a reaction mixture containing propylene oxide is obtained; separating the reaction mixture obtained in the reacting into a gas and a reaction liquid; and distilling the reaction liquid obtained in the separating, whereby the reaction liquid is separated into a column top liquid containing propylene oxide, and a column bottom liquid including acetonitrile or a combination of acetonitrile and water, in combination with other steps. This enables industrially efficient production of propylene oxide with use of acetonitrile.

公开(公告)号：EP2014719A1

公开(公告)日：2009-01-14

申请号：EP07741660.0

申请日：2007-04-10

Applicant: Sumitomo Chemical Company, Limited ,  Sumika Chemtex Company, Limited

Inventor： OKUBO, Yoshihito ,  KUSUNOKI, Kazutaka ,  MITSUTAKE, Tatsuo ,  NARAHARA, Hideo ,  HIKASA, Tadashi

IPC: C08L51/06 ,  C08J3/05 ,  C08L23/20

CPC classification number: C08L23/04 ,  B32B9/005 ,  B32B9/045 ,  B32B15/085 ,  B32B21/08 ,  B32B23/08 ,  B32B27/08 ,  B32B27/32 ,  B32B2307/306 ,  B32B2307/50 ,  B32B2307/714 ,  C08F255/00 ,  C08F255/02 ,  C08F285/00 ,  C08J3/05 ,  C08J2323/04 ,  C08J2351/06 ,  C08L51/06 ,  C08L53/00 ,  C08L2666/02 ,  C09J151/06 ,  C09J153/00 ,  Y10T428/31692 ,  Y10T428/31699 ,  Y10T428/31786 ,  Y10T428/3179 ,  Y10T428/3188 ,  Y10T428/31902 ,  Y10T428/31913 ,  Y10T428/31938 ,  C08L2666/24 ,  C08L2666/04

Abstract: An emulsion comprising a dispersoid dispersed in water together with an emulsifier, wherein
the dispersoid is an olefin copolymer containing a structural unit derived from ethylene, linear α-olefin, or ethylene and linear α-olefin, and a structural unit derived from the following vinyl compound (I), or an olefin copolymer modified material obtained by further graft-polymerizing unsaturated carboxylic acids to the olefin copolymer,
and the volume-based median diameter of the dispersoid contained in the emulsion is 0.01 to 1 µm.

        CH 2 =CH-R     (I)

(wherein, R in the vinyl compound (I) represents a secondary alkyl group, tertiary alkyl group or alicyclic hydrocarbon group.).

Abstract translation: 一种包含分散在水中的分散质与乳化剂的乳液，其中分散质是含有衍生自乙烯，线性α-烯烃或乙烯的结构单元和线性α-烯烃的烯烃共聚物，以及衍生自以下乙烯基 化合物（I）或通过将不饱和羧酸进一步接枝聚合到烯烃共聚物中而获得的烯烃共聚物改性物质，并且乳液中所含的分散质的基于体积的中值粒径为0.01〜1μm。 ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒCH2 = CH-R€ƒ€ƒ€ƒ（I）（其中，乙烯基化合物（I）中的R表示仲烷基 ，叔烷基或脂环族烃基）。

公开(公告)号：EP2177514A1

公开(公告)日：2010-04-21

申请号：EP08790963.6

申请日：2008-07-08

Applicant: Sumitomo Chemical Company, Limited

Inventor： NARAHARA, Hideo ,  HATANO, Ryo ,  KANAZAWA, Hideo

IPC: C07D301/06 ,  B01J29/89 ,  C07D301/08 ,  C07D303/04 ,  C07B61/00

CPC classification number: C07D301/06 ,  B01J21/18 ,  B01J23/44 ,  B01J29/89 ,  B01J35/0006 ,  B01J2229/20 ,  C07D301/08 ,  C07D303/04

Abstract: The present invention provides an apparatus for producing an epoxy compound derived from an olefin by causing a reaction of hydrogen, oxygen, and the olefin in a liquid solvent in the presence of a catalyst in a reactor, wherein a vapor phase in the reactor contains an inert gas; hydrogen, an oxygen-containing gas with an oxygen concentration of at least 90% by volume, and the olefin are supplied to the vapor phase and/or liquid phase of the reactor to cause a reaction; and there exist a means for taking out the liquid phase containing the reaction product from the reactor.

Abstract translation: 本发明提供了一种用于通过在反应器中在催化剂存在下在液体溶剂中引起氢，氧和烯烃的反应来制备衍生自烯烃的环氧化合物的装置，其中反应器中的气相含有 惰性气体 氢气，氧浓度为至少90体积％的含氧气体，并将烯烃供应到反应器的气相和/或液相以引起反应; 并且存在从反应器中取出含有反应产物的液相的方法。

公开(公告)号：EP2173731A2

公开(公告)日：2010-04-14

申请号：EP08778059.9

申请日：2008-07-04

Applicant: Sumitomo Chemical Company, Limited

Inventor： MIZUNO, Masahiko ,  NARAHARA, Hideo

IPC: C07D301/12 ,  C07D303/04

CPC classification number: C07D301/12

Abstract: A method is for producing propylene oxide, the method including the steps of: reacting hydrogen peroxide with propylene either in an acetonitrile solvent or in a mixture of solvents which include acetonitrile and water, in presence of a titanosilicate catalyst, whereby a reaction mixture containing propylene oxide is obtained; separating the reaction mixture obtained in the reacting into a gas and a reaction liquid; and distilling the reaction liquid obtained in the separating, whereby the reaction liquid is separated into a column top liquid containing propylene oxide, and a column bottom liquid including acetonitrile or a combination of acetonitrile and water, in combination with other steps. This enables industrially efficient production of propylene oxide with use of acetonitrile.

Abstract translation: 一种生产环氧丙烷的方法，该方法包括以下步骤：在钛硅酸盐催化剂存在下，使过氧化氢与丙烯在乙腈溶剂中或在包括乙腈和水的溶剂混合物中反应，由此得到含有丙烯 氧化物; 将反应得到的反应混合物分离成气体和反应液; 通过将分离得到的反应液蒸馏分离为含有环氧丙烷的塔顶液和含有乙腈或乙腈和水的组合的塔底液并进行其他工序。 这使得能够在工业上有效地使用乙腈生产环氧丙烷。