公开(公告)号：EP2953195A4

公开(公告)日：2016-08-17

申请号：EP14746144

申请日：2014-01-31

申请人： TANAKA PRECIOUS METAL IND

发明人： ISHIDA MINORU ,  MATSUTANI KOICHI

IPC分类号： H01M4/90 ,  B01J23/89 ,  B01J37/02 ,  B01J37/08 ,  H01M4/88 ,  H01M4/92 ,  H01M8/10

CPC分类号： H01M4/921 ,  B01J35/0033 ,  H01M4/9083 ,  H01M4/92 ,  H01M4/926 ,  H01M8/1018 ,  H01M2004/8689 ,  H01M2008/1095

摘要： The invention is a catalyst for solid polymer fuel cell having catalyst particles composed of platinum, cobalt and magnesium supported on a carbon powder carrier, in which a composition ratio (molar ratio) among platinum, cobalt and magnesium in the catalyst particles is Pt : Co : Mg = 1 : 0.4 to 0.5 : 0.00070 to 0.00095. This catalyst is manufactured by supporting cobalt and magnesium on a platinum catalyst and then conducting a heat treatment and a treatment to be brought into contact with an oxidizing solution, the feature of the catalyst manufactured in this manner includes a peak position of a main peak appearing between 2¸ = 40° and 42° in X-ray diffraction analysis, and the peak position is shifted to from 41.0° to 41.5°.

摘要翻译： 本发明是一种固体聚合物燃料电池的催化剂，其具有负载在碳粉末载体上的由铂，钴和镁构成的催化剂颗粒，其中催化剂颗粒中铂，钴和镁的组成比（摩尔比）为Pt：Co ：Mg = 1：0.4〜0.5：0.00070〜0.00095。 该催化剂通过在铂催化剂上负载钴和镁，然后进行热处理和与氧化溶液接触的处理来制造，以这种方式制造的催化剂的特征包括出现主峰的峰位置 在X射线衍射分析中在2θ= 40°和42°之间，峰值位置从41.0°移动到41.5°。

公开(公告)号：EP3179545A4

公开(公告)日：2018-01-03

申请号：EP15829740

申请日：2015-07-21

申请人： TANAKA PRECIOUS METAL IND

发明人： ISHIDA MINORU ,  MATSUTANI KOICHI

IPC分类号： H01M4/90 ,  H01M4/86 ,  H01M4/88 ,  H01M4/92 ,  H01M8/10 ,  H01M8/1018

CPC分类号： H01M4/926 ,  H01M4/86 ,  H01M4/8663 ,  H01M4/88 ,  H01M4/90 ,  H01M4/92 ,  H01M8/10 ,  H01M8/1018 ,  H01M2004/8689 ,  H01M2008/1095 ,  Y02P70/56

摘要： The present invention provides a catalyst for a solid polymer fuel cell, having excellent initial activity and good durability and a production method thereof. The present invention is a catalyst for a solid polymer fuel cell, including catalyst particles composed of platinum or a platinum alloy supported on a carbon powder carrier, the catalyst having sulfo groups (-SO 3 H) at least on the catalyst particles, and the catalyst further having a fluorine compound having a C-F bond supported at least on the catalyst particles. It is preferred in the catalyst of the present invention that sulfur content is 800 ppm or more and 5000 ppm or less based on the mass of the whole catalyst and the amount of the fluorine compound is 3 mass% or more and 24 mass% or less based on the mass of the whole catalyst.

公开(公告)号：EP2990104A4

公开(公告)日：2016-04-13

申请号：EP14787852

申请日：2014-04-14

申请人： NISSAN MOTOR ,  TANAKA PRECIOUS METAL IND

发明人： OHMA ATSUSHI ,  AKIZUKI KEN ,  ONO YOSHITAKA ,  MASHIO TETSUYA ,  MATSUTANI KOICHI

IPC分类号： H01M4/86 ,  H01M4/88 ,  H01M4/90 ,  H01M4/92 ,  H01M8/10 ,  H01M8/1018

CPC分类号： H01M4/9075 ,  H01M4/885 ,  H01M4/8885 ,  H01M4/8892 ,  H01M4/9083 ,  H01M4/92 ,  H01M4/925 ,  H01M4/926 ,  H01M2008/1095 ,  H01M2250/20 ,  Y02T90/32

摘要： [Object] Provided is a catalyst having a high catalytic activity. [Solving Means] Disclosed is a catalyst comprising a catalyst support and a catalyst metal supported on the catalyst support, wherein the catalyst support includes pores having a radius of less than 1 nm and pores having a radius of 1 nm or more, a surface area formed by the pores having a radius of less than 1 nm is equal to or larger than a surface area formed by the pores having a radius of 1 nm or more, and an average particle diameter of the catalyst metal is 2.8 nm or more.

公开(公告)号：EP3032623A4

公开(公告)日：2017-01-25

申请号：EP14834719

申请日：2014-08-01

申请人： TANAKA PRECIOUS METAL IND

发明人： ISHIDA MINORU ,  MATSUTANI KOICHI

IPC分类号： H01M4/90 ,  B01J23/89 ,  H01M4/88 ,  H01M4/92 ,  H01M8/10

CPC分类号： H01M4/8652 ,  B01J23/8913 ,  B01J27/02 ,  B01J35/0033 ,  H01M4/9041 ,  H01M4/9083 ,  H01M4/921 ,  H01M4/923 ,  H01M4/926 ,  H01M2004/8689 ,  H01M2008/1095

摘要： The present invention aims to provide a catalyst that makes it possible to reduce an amount of solid electrolyte mixed and improve initial performance of a fuel cell, and also a method for producing the catalyst. The present invention relates to a catalyst for a solid polymer fuel cell, which has sulfo groups (-SO 3 H) on catalyst particles. In TEM-EDX analysis, a ratio (I S /I Pt ) of a sulfur peak intensity (I S ) to a platinum peak intensity (I Pt ) on the catalyst particles is within a range of 0.0044 or more and 0.0090 or less. The catalyst makes it possible to reduce the amount of solid electrolyte added and also a fuel cell with excellent initial performance, and thus contributes to a practical use of a fuel cell.

摘要翻译： 本发明的目的在于提供一种能够减少固体电解质的混合量，提高燃料电池的初期性能的催化剂，以及催化剂的制造方法。 本发明涉及一种在催化剂颗粒上具有磺基（-SO 3 H）的固体高分子型燃料电池用催化剂。 在TEM-EDX分析中，催化剂粒子上的硫峰强度（I S）与铂峰强度（I Pt）的比（I S / I Pt）在0.0044以上且0.0090以下的范围内。 催化剂使得可以减少添加的固体电解质的量以及具有优异的初始性能的燃料电池，从而有助于实际使用燃料电池。

公开(公告)号：EP2866287A4

公开(公告)日：2015-12-23

申请号：EP13809878

申请日：2013-06-19

申请人： TANAKA PRECIOUS METAL IND

发明人： ISHIDA MINORU ,  MATSUTANI KOICHI

IPC分类号： H01M4/90 ,  H01M4/86 ,  H01M4/88 ,  H01M4/92 ,  H01M8/10

CPC分类号： H01M4/9083 ,  H01M4/8642 ,  H01M4/8652 ,  H01M4/8657 ,  H01M4/8825 ,  H01M4/8882 ,  H01M4/921 ,  H01M4/926 ,  H01M2008/1095

摘要： The present invention is a catalyst for a solid polymer fuel cell including: catalyst particles of platinum, cobalt and manganese; and a carbon powder carrier supporting the catalyst particles, wherein the component ratio (molar ratio) of the platinum, cobalt and manganese of the catalyst particles is of Pt : Co : Mn = 1 : 0.06 to 0.39 : 0.04 to 0.33, and wherein in an X-ray diffraction analysis of the catalyst particles, the peak intensity ratio of a Co-Mn alloy appearing around 2¸ = 27° is 0.15 or less on the basis of a main peak appearing around 2¸ = 40°. It is particularly preferred that the catalyst have a peak ratio of a peak of a CoPt 3 alloy and an MnPt 3 alloy appearing around 2¸ = 32° of 0.14 or more on the basis of a main peak.

公开(公告)号：EP3032623B1

公开(公告)日：2018-01-10

申请号：EP14834719

申请日：2014-08-01

申请人： TANAKA PRECIOUS METAL IND

发明人： ISHIDA MINORU ,  MATSUTANI KOICHI

IPC分类号： H01M4/90 ,  B01J23/89 ,  H01M4/88 ,  H01M4/92 ,  H01M8/10

CPC分类号： H01M4/8652 ,  B01J23/8913 ,  B01J27/02 ,  B01J35/0033 ,  H01M4/9041 ,  H01M4/9083 ,  H01M4/921 ,  H01M4/923 ,  H01M4/926 ,  H01M2004/8689 ,  H01M2008/1095

摘要： The present invention aims to provide a catalyst that makes it possible to reduce an amount of solid electrolyte mixed and improve initial performance of a fuel cell, and also a method for producing the catalyst. The present invention relates to a catalyst for a solid polymer fuel cell, which has sulfo groups (-SO 3 H) on catalyst particles. In TEM-EDX analysis, a ratio (I S /I Pt ) of a sulfur peak intensity (I S ) to a platinum peak intensity (I Pt ) on the catalyst particles is within a range of 0.0044 or more and 0.0090 or less. The catalyst makes it possible to reduce the amount of solid electrolyte added and also a fuel cell with excellent initial performance, and thus contributes to a practical use of a fuel cell.

公开(公告)号：EP2958173A4

公开(公告)日：2016-10-05

申请号：EP14751518

申请日：2014-02-12

申请人： TANAKA PRECIOUS METAL IND

发明人： ISHIDA MINORU ,  NAKAJIMA HITOSHI ,  MATSUTANI KOICHI

IPC分类号： H01M4/92 ,  H01M8/1018

CPC分类号： H01M4/926 ,  H01M4/8842 ,  H01M4/8882 ,  H01M4/8892 ,  H01M4/921 ,  H01M2008/1095

摘要： Provided is a catalyst for solid polymer fuel cell that exhibits excellent initial activity and favorable durability and a method for manufacturing the same. The invention is a catalyst for solid polymer fuel cell which is formed by supporting catalyst particles including platinum, cobalt and manganese on a carbon powder carrier, wherein a composition ratio (molar ratio) among platinum, cobalt and manganese in the catalyst particles is Pt : Co : Mn = 1 : 0.06 to 0.39 : 0.04 to 0.33, a peak intensity ratio of a Co-Mn alloy appearing in the vicinity of 2¸ = 27° is 0.15 or less with respect to a main peak appearing in the vicinity of 2¸ = 40° in X-ray diffraction analysis of the catalyst particles, and a fluorine compound having a C-F bond is supported at least on the surface of the catalyst particles. The amount of the fluorine compound supported is preferably from 3 to 20% with respect to the entire mass of the catalyst.

摘要翻译： 提供了表现出优异的初始活性和良好的耐久性的固体高分子型燃料电池用催化剂及其制造方法。 本发明是一种固体高分子型燃料电池用催化剂，其通过在碳粉载体上担载铂，钴，锰等催化剂粒子而形成，其中，催化剂粒子中的铂，钴，锰的组成比（摩尔比）为Pt： Co：Mn = 1：0.06〜0.39：0.04〜0.33，出现在2π= 27°附近的Co-Mn合金的峰强度比相对于出现在2附近的主峰为0.15以下 催化剂颗粒的X射线衍射分析中的¸= 40°，至少在催化剂颗粒的表面上负载具有CF键的氟化合物。 相对于催化剂的总质量，氟化合物的负载量优选为3〜20％。

公开(公告)号：EP2650956A4

公开(公告)日：2016-06-01

申请号：EP11847629

申请日：2011-12-02

申请人： TANAKA PRECIOUS METAL IND

发明人： TADA TOMOYUKI ,  MATSUTANI KOICHI ,  KAIEDA TAKESHI ,  HAYAKAWA KATSUICHIRO ,  NAKAJIMA HITOSHI

IPC分类号： H01M8/1018 ,  H01M4/92

CPC分类号： H01M4/926 ,  H01M4/8882 ,  H01M4/9083 ,  H01M2008/1095 ,  Y02E60/50

摘要： The present invention provides a catalyst for a polymer electrolyte fuel cell including catalyst particles made of platinum supported on a carbon powder carrier, wherein the carbon powder carrier includes 0.7 to 3.0 mmol/g (based on the weight of the carrier) of a hydrophilic group bonded thereto; and the platinum particles have an average particle size of 3.5 to 8.0 nm and the platinum specific surface area based on CO adsorption (COMSA) of 40 to 100 m 2 /g. The catalyst for a polymer electrolyte fuel cell according to the present invention is a catalyst excellent in initial activity and satisfactory in durability.

摘要翻译： 本发明提供了一种用于固体高分子型燃料电池的催化剂，其包括负载在碳粉载体上的由铂制成的催化剂颗粒，其中所述碳粉载体包含0.7-3.0mmol / g（基于载体的重量）的亲水基团 与之结合; 并且铂颗粒的平均粒度为3.5〜8.0nm，基于CO吸附的铂比表面积（COMSA）为40〜100m 2 / g。 本发明的固体高分子型燃料电池用催化剂是初期活性优异，耐久性良好的催化剂。