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    ALKALI RESISTANT CATALYST
    4.
    发明公开
    ALKALI RESISTANT CATALYST 审中-公开
    ALKALIBESTÄNDIGERKATALYSATOR

    公开(公告)号：EP2066445A1

    公开(公告)日：2009-06-10

    申请号：EP07801383.6

    申请日：2007-09-25

    申请人： Technical University of Denmark

    发明人： RASMUSSEN, Søren Birk ,  KUSTOV, Arkady ,  FEHRMANN, Rasmus ,  DUE-HANSEN, Johannes

    IPC分类号： B01J37/20 ,  B01J23/22 ,  B01J23/72 ,  B01J23/745 ,  B01D53/86

    CPC分类号： B01J37/20 ,  B01D53/8628 ,  B01D2251/2062 ,  B01D2255/20723 ,  B01D2255/2073 ,  B01D2255/20738 ,  B01D2255/20761 ,  B01D2255/20769 ,  B01D2255/9205 ,  B01D2255/9207 ,  B01J21/063 ,  B01J21/066 ,  B01J23/22 ,  B01J23/72 ,  B01J23/745 ,  B01J27/053

    摘要： The present invention concerns a process for selectively removing nitrogen oxides (NOx) from exhaust or flue gasses, especially from gases arising from the burning of biomass, combined biomass-fossil fuel and from waste incineration units, and a catalyst for this process. The process relates to the selective catalytic reduction (SCR) of NOx with ammonia as reductant which is the most common method to catalytically reduce NOx in flue gasses from stationary sources. SCR systems are designed to clean the nitrogen dioxide (NO 2 and nitrogen oxide (NO) out of flue gasses. The present invention relates to a process for the selective removal of nitrogen oxides in the presence of ammonia from gases containing a significant amount of alkali metal and/or alkali-earth compounds which process comprises using a catalyst combined of a) a formed porous superacidic support b) a metal oxide catalytic component deposited on said support selected from the group consisting of Cu, V, Fe, Cr, Mn, Mo and mixtures thereof. The support can e.g. be obtained by the adsorbing of sulfate ions onto amorphous or crystalline inorganic oxide of Zr, Ti, Fe, Sn, Si, Al, and Hf, followed by calcination in air.

    摘要翻译： 本发明涉及从废气或烟道气体，特别是从燃烧生物质，组合的生物质 - 化石燃料和废物焚烧装置产生的气体中选择性地除去氮氧化物（NOx）的方法和用于该方法的催化剂。 该方法涉及NOx与氨作为还原剂的选择性催化还原（SCR），这是从固定源催化还原烟气中的NOx的最常用方法。 SCR系统设计用于清除烟道气中的二氧化氮（NO 2和氮氧化物（NO）），本发明涉及一种在氨气存在下从含有大量碱的气体中选择性除去氮氧化物的方法 金属和/或碱土化合物，其包括使用以下组合的催化剂：a）形成的多孔超酸性载体b）沉积在所述载体上的金属氧化物催化组分，所述金属氧化物催化组分选自Cu，V，Fe，Cr，Mn， Mo及其混合物。 支持体例如 通过将硫酸根离子吸附到Zr，Ti，Fe，Sn，Si，Al和Hf的无定形或结晶无机氧化物上，然后在空气中煅烧而获得。

    PALLADIUM CATALYST SYSTEM COMPRISING ZWITTERION AND/OR ACID-FUNCTIONALIZED IONIC LIQUID
    6.
    发明公开
    PALLADIUM CATALYST SYSTEM COMPRISING ZWITTERION AND/OR ACID-FUNCTIONALIZED IONIC LIQUID 有权
    IT IT IT TEM IT IT IT IT IT IT IT IT IT IT IT IT IT IT IT IT IT IT IT IT IT IT IT IT

    公开(公告)号：EP2473277A1

    公开(公告)日：2012-07-11

    申请号：EP10747645.9

    申请日：2010-09-01

    申请人： Technical University of Denmark

    发明人： GARCIA SUAREZ, Eduardo J ,  RIISAGER, Anders ,  FEHRMANN, Rasmus ,  XIONG, Jianmin

    IPC分类号： B01J31/02 ,  C07C51/00

    CPC分类号： B01J31/0277 ,  B01J31/0225 ,  B01J31/0239 ,  B01J31/0271 ,  B01J31/0284 ,  B01J31/0285 ,  B01J31/24 ,  B01J2231/321 ,  B01J2531/824 ,  B01J2540/22 ,  C07C51/14 ,  C07C53/122

    摘要： The present invention concerns a catalyst system in particular a catalyst system comprising Palladium (Pd), a zwitterion and/or an acid-functionalized ionic liquid, and one or more phosphine ligands, wherein the Pd catalyst can be provided by a complex precursor, such as Pd(CH3COO)2, PdCI2, Pd(CH3COCHCOCH3), Pd (CF3COO)2, Pd(PPh3)4 or Pd2(dibenzylideneacetone)3. Such catalyst systems can be used for e.g. alkoxycarbonylation reactions, carboxylation reactions, and/or in a co-polymerization reaction, e.g. in the production of methyl propionate and/or propanoic acid, optionally in processes forming methyl methacrylate and/or methacrylic acid. Catalyst systems according to the invention are suitable for reactions forming separable product and catalyst phases and supported ionic liquid phase SILP applications.

    摘要翻译： 本发明涉及催化剂体系，特别是包括钯（Pd），两性离子和/或酸官能化的离子液体和一种或多种膦配体的催化剂体系，其中Pd催化剂可以由复合前体提供，例如 作为Pd（CH 3 COO）2，PdCl 2，Pd（CH 3 COCHCOCH 3），Pd（CF 3 COO）2，Pd（PPh 3）4或Pd 2（二亚苄基丙酮）3。 这样的催化剂体系可以用于例如 烷氧基羰基化反应，羧化反应和/或在共聚反应中，例如， 在丙酸甲酯和/或丙酸的生产中，任选地在形成甲基丙烯酸甲酯和/或甲基丙烯酸的方法中。 根据本发明的催化剂体系适用于形成可分离产物和催化剂相和支持的离子液相SILP应用的反应。