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1.发明公开MEMBRANE WITH A STABLE NANOSIZED MICROSTRUCTURE AND METHOD FOR PRODUCING SAME 有权在纳米尺寸的稳定微结构及其制造方法REED
公开(公告)号：EP2183043A1
公开(公告)日：2010-05-12
申请号：EP08785755.3
申请日：2008-08-29
CPC分类号： B01D67/0046 , B01D53/228 , B01D53/8668 , B01D69/10 , B01D69/145 , B01D71/024 , B01D2257/7022 , B01D2313/42 , B01D2325/10 , B01J23/002 , B01J23/83 , B01J23/86 , B01J23/8892 , B01J35/0033 , B01J35/023 , B01J35/065 , B01J37/0219 , B01J37/0244 , B01J2523/00 , C01B13/0255 , B01J2523/24 , B01J2523/3706 , B01J2523/842 , B01J2523/845 , B01J2523/3712 , B01J2523/375 , B01J2523/847 , B01J2523/47 , B01J2523/56 , B01J2523/36 , B01J2523/48 , B01J2523/72
摘要： The present invention provides a membrane, comprising in this order a first catalyst layer, an electronically and ionically conducting layer having a nanosized microstructure, and a second catalyst layer, characterized in that the electronically and ionically conducting layer is formed from an electrolyte material, a grain growth inhibitor and/or grain boundary modifier, and a method for producing same.
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公开(公告)号：EP2269252A1
公开(公告)日：2011-01-05
申请号：EP09721717.8
申请日：2009-03-18
CPC分类号： H01M4/8885 , H01M4/8621 , H01M4/8657 , H01M4/8892 , H01M4/9025 , H01M4/905 , H01M8/1226 , H01M8/1286 , Y02P70/56 , Y10T29/49108 , Y10T29/49115 , Y10T428/24942
摘要： The present invention provides an all ceramics solid oxide cell, comprising an anode layer, a cathode layer, and an electrolyte layer sandwiched between the anode layer and the cathode layer, wherein the electrolyte layer comprises doped zirconia and has a thickness of from 40 to 300 μm; wherein the anode layer and the cathode layer both comprise doped ceria or both comprise doped zirconia; and wherein the multilayer structure formed of the anode layer, the electrolyte layer and the cathode layer is a symmetrical structure. The present invention further provides a method of producing said solid oxide cell.
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公开(公告)号：EP2188038A1
公开(公告)日：2010-05-26
申请号：EP08785754.6
申请日：2008-08-29
CPC分类号： B01D53/228 , B01D67/0046 , B01D67/0088 , B01D69/141 , B01D71/025 , B01D2256/12 , B01D2256/16 , B01D2325/10 , C01B3/503 , C01B13/0255
摘要： The present invention provides a membrane structure, comprising in said order a first electronically conducting layer, an ionically conducting layer, and a second electronically conducting layer, characterized in that the first and second electronically conducting layers are internally short circuited. The present invention further provides a method of producing the above membrane structure, comprising the steps of : providing a ionically conducting layer; applying at least one layer of electronically conducting material on each side of said ionically conducting layer; sintering the multilayer structure; and impregnating the electronically conducting layers with a catalyst material or catalyst precursor material.
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4.发明授权REVERSIBLE SOLID OXIDE FUEL CELL STACK AND METHOD FOR PREPARING SAME 有权可逆固体氧化物燃料电池组AND METHOD FOR THE PRODUCTION
公开(公告)号：EP1920492B1
公开(公告)日：2016-02-24
申请号：EP06791772.4
申请日：2006-08-31
发明人： LARSEN, Peter, Halvor , SMITH, Anders , MOGENSEN, Mogens , LINDEROTH, Soeren , HENDRIKSEN, Peter, Vang
CPC分类号： H01M8/243 , H01M4/861 , H01M4/8885 , H01M4/9033 , H01M4/905 , H01M8/0276 , H01M8/2404 , H01M8/2435 , H01M8/2483 , H01M8/2484 , H01M2008/1293 , Y02E60/50 , Y02E60/525 , Y02P70/56
摘要： A reversible SOFC monolithic stack is provided which comprises: 1) a first component which comprises at least one porous metal containing layer (1) with a combined electrolyte and sealing layer on the porous metal containing layer (1); wherein the at least one porous metal containing layer (1) hosts an electrode; 2) a second component comprising at least one porous metal containing layer (1) with a combined interconnect and sealing layer on the porous metal containing layer; wherein the at least one porous metal containing layers hosts an electrode. Further provided is a method for preparing a reversible solid oxide fuel cell stack. The obtained solid oxide fuel cell stack has improved mechanical stability and high electrical performance, while the process for obtaining same is cost effective.
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公开(公告)号：EP1844517A2
公开(公告)日：2007-10-17
申请号：EP06706590.4
申请日：2006-02-02
CPC分类号： H01M8/0243 , H01M4/8885 , H01M4/9025 , H01M4/905 , H01M8/023 , H01M8/0232 , H01M8/1253 , H01M8/126 , H01M8/184 , H01M2008/1293 , Y02E60/525 , Y02E60/528 , Y02P70/56 , Y10T29/49115
摘要： The present invention provides a method for producing a reversible solid oxide fuel cell, comprising the steps of: - providing a metallic support layer; - forming a cathode precursor layer on the metallic support layer; - forming an electrolyte layer on the cathode precursor layer; - sintering the obtained multilayer structure; - impregnating the cathode precursor layer so as to form a cathode layer; and - forming an anode layer on top of the electrolyte layer. Furthermore, a reversible SOFC is provided which is obtainable by said method. The method advantageously allows for a greater choice of anode materials, resulting in more freedom in cell design, depending on the desired application.
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6.发明授权METHOD OF PRODUCING METAL TO GLASS, METAL TO METAL OR METAL TO CERAMIC CONNECTIONS 有权PROCESS带玻璃金属，金属化合物与金属或金属陶瓷的制备
公开(公告)号：EP1844512B1
公开(公告)日：2017-04-19
申请号：EP05822618.4
申请日：2005-12-23
CPC分类号： C03C27/042 , B32B2311/00 , C03C8/24 , C03C29/00 , C04B37/025 , C04B2237/10 , C04B2237/343 , C04B2237/40 , H01M8/0282 , H01M2008/1293 , Y02P70/56
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7.发明公开METHOD OF PRODUCING METAL TO GLASS, METAL TO METAL OR METAL TO CERAMIC CONNECTIONS 有权PROCESS带玻璃金属，金属化合物与金属或金属陶瓷的制备
公开(公告)号：EP1844512A1
公开(公告)日：2007-10-17
申请号：EP05822618.4
申请日：2005-12-23
CPC分类号： C03C27/042 , B32B2311/00 , C03C8/24 , C03C29/00 , C04B37/025 , C04B2237/10 , C04B2237/343 , C04B2237/40 , H01M8/0282 , H01M2008/1293 , Y02P70/56
摘要： A method of manufacturing metal to glass, metal to metal and metal to ceramic connections to be used in SOFC applications, said connections being produced as a mixture of a base glass powder and a metal oxide powder. As a result, the inherent properties of the glass used in the composite seals may be altered locally in the metal-coating interface by adding e.g. MgO in order to control the viscosity and wetting, and at the same time maintain the bulk properties such as high coefficient of thermal expansion of the basic glass towards the seal components.
摘要翻译： 在SOFC应用中使用的制造金属与玻璃，金属与金属和金属陶瓷的连接的方法，所述被生产作为连接和碱玻璃粉末的混合物中的金属氧化物粉末。 其结果是，在复合密封件所使用的玻璃的固有性质可以被本地存储在金属 - 涂层界面通过添加E.G.改变 的MgO，以控制粘度和润湿，并在同一时间保持整体性质：如向密封部件的基本玻璃的热膨胀系数高。
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公开(公告)号：EP1844510A1
公开(公告)日：2007-10-17
申请号：EP06706509.4
申请日：2006-01-31
CPC分类号： H01M4/8605 , H01M4/8652 , H01M4/8885 , H01M4/9033 , H01M8/1226 , H01M8/1253 , H01M2004/028 , Y02E60/525 , Y02P70/56
摘要： The present invention provides a method of producing a solid oxide fuel cell, comprising the steps of: forming an anode support layer; applying an anode layer on the anode support layer; applying an electrolyte layer on the anode layer; and sintering the obtained structure; wherein the anode support layer and/or the anode layer comprises a composition comprising doped zirconia, doped ceria and/or a metal oxide with an oxygen ion or proton conductivity, NiO and at least one oxide selected from the group consisting of AI2O3, TiO2, Cr2O3, Sc2O3, VOx, TaOx, MnOx, NbOx, CaO, Bi2O3, LnOx, MgCr2O4, MgTiO3, CaAI2O4, LaAIO3, YbCrO3, ErCrO4, NiTiO3, NiCr2O4, and mixtures thereof. According to the invention, a combination of nickel coarsening prevention due to specific Ni-particle growth inhibitors, and, at the same time, a strengthening of the ceramic structure of the anode support layer and/or the anode layer is achieved.
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9.发明授权MEMBRANE WITH A STABLE NANOSIZED MICROSTRUCTURE AND METHOD FOR PRODUCING SAME 有权在纳米尺寸的稳定微结构及其制造方法REED
公开(公告)号：EP2183043B1
公开(公告)日：2013-07-31
申请号：EP08785755.3
申请日：2008-08-29
IPC分类号： B01D67/00 , B01D53/22 , B01D53/86 , B01D69/10 , B01D69/14 , B01D71/02 , B01J23/00 , B01J23/83 , B01J23/86 , B01J23/889 , B01J35/00 , B01J35/02 , B01J37/02 , B01J35/06 , C01B13/02
CPC分类号： B01D67/0046 , B01D53/228 , B01D53/8668 , B01D69/10 , B01D69/145 , B01D71/024 , B01D2257/7022 , B01D2313/42 , B01D2325/10 , B01J23/002 , B01J23/83 , B01J23/86 , B01J23/8892 , B01J35/0033 , B01J35/023 , B01J35/065 , B01J37/0219 , B01J37/0244 , B01J2523/00 , C01B13/0255 , B01J2523/24 , B01J2523/3706 , B01J2523/842 , B01J2523/845 , B01J2523/3712 , B01J2523/375 , B01J2523/847 , B01J2523/47 , B01J2523/56 , B01J2523/36 , B01J2523/48 , B01J2523/72
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公开(公告)号：EP1844517B1
公开(公告)日：2010-04-21
申请号：EP06706590.4
申请日：2006-02-02
CPC分类号： H01M8/0243 , H01M4/8885 , H01M4/9025 , H01M4/905 , H01M8/023 , H01M8/0232 , H01M8/1253 , H01M8/126 , H01M8/184 , H01M2008/1293 , Y02E60/525 , Y02E60/528 , Y02P70/56 , Y10T29/49115
摘要： The present invention provides a method for producing a reversible solid oxide fuel cell, comprising the steps of: - providing a metallic support layer; - forming a cathode precursor layer on the metallic support layer; - forming an electrolyte layer on the cathode precursor layer; - sintering the obtained multilayer structure; - impregnating the cathode precursor layer so as to form a cathode layer; and - forming an anode layer on top of the electrolyte layer. Furthermore, a reversible SOFC is provided which is obtainable by said method. The method advantageously allows for a greater choice of anode materials, resulting in more freedom in cell design, depending on the desired application.
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