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公开(公告)号:EP3428232A1
公开(公告)日:2019-01-16
申请号:EP16893242.4
申请日:2016-08-30
发明人: LU, Changli , YUAN, Zhimin , CAI, Tongmin , HUANG, Xianbo , ZENG, Xiangbin , JIAO, Jian , YUAN, Renxu , ZHONG, Yuke , XIONG, Kai , YANG, Hui , MAI, Kaijin , DONG, Xueteng
IPC分类号: C08L67/02 , C08K5/156 , C08G63/183
摘要: The present invention discloses a PBAT resin composition comprising: (a) Poly (butyleneadipate-co-terephthalate); (b) a cyclic esterified product having a structure represented by the formula (I)
Wherein the content by weight of the cyclic esterified product is from 10 ppm to 2000 ppm, based on the total weight of the PBAT resin composition. In the present invention, the service life of the PBAT resin composition can be greatly extended by adding cyclic esterified product in the PBAT resin composition and controlling the content of the cyclic esterified product in the composition in the range of 10 ppm to 2000 ppm. And after boiled for 240 hours in 95% ethanol at 40°C,the film produced from blowing or the articles produced from injection have less surface precipitates, with excellent surface appearance properties.-
公开(公告)号:EP3260496A1
公开(公告)日:2017-12-27
申请号:EP17762458.2
申请日:2017-02-24
申请人: Kingfa Sci. & Tech. Co., Ltd. , Zhuhai Wango Chemical Co., Ltd. , Tianjin Kingfa New Material Co., Ltd.
发明人: LU, Changli , YUAN, Zhimin , CAI, Tongmin , HUANG, Xianbo , ZENG, Xiangbin , JIAO, Jian , YUAN, Renxu , ZHONG, Yuke , XIONG, Kai , YANG, Hui , MAI, Kaijin , DONG, Xueteng
CPC分类号: C08L67/02 , C08K5/1535 , C08K5/156 , C08K13/02 , C08L3/02 , C08L25/14 , C08L67/04 , C08L2201/06 , C08L2201/08 , C08L2205/02 , C08L2205/03
摘要: The present invention discloses a biodegradable polyester composition, wherein based on a total weight of the biodegradable polyester composition, a weight content of a cyclic ester compound having a structure shown as formula (I) is 100ppm-950ppm;
and based on the total weight of the biodegradable polyester composition, a weight content of tetrahydrofuran is 3ppm-200ppm. In the present invention, by adding the cyclic ester compound and tetrahydrofuran into the composition and controlling the content of the cyclic ester compound and the content of tetrahydrofuran in a certain range in the composition, an anti-thermal oxidative aging property of the biodegradable polyester composition can be greatly improved. Besides, after being digested with 95% ethanol at 40°C for 240 hours, a film prepared by blow molding or a part prepared by injection molding has little precipitate separating out of the surface and has an excellent surface appearance property. Also, poor printing of the biodegradable polyester composition during printing process can be greatly improved and the film shows excellent printing performance.摘要翻译: 本发明公开了一种生物可降解聚酯组合物,其中基于生物可降解聚酯组合物的总重量,具有式(I)所示结构的环状酯化合物的重量含量为100ppm-950ppm; 并且基于生物可降解聚酯组合物的总重量,四氢呋喃的重量含量为3ppm-200ppm。 在本发明中,通过在组合物中添加环状酯化合物和四氢呋喃,并且在组合物中将环状酯化合物的含量和四氢呋喃的含量控制在一定范围内,可生物降解聚酯组合物的抗热氧化老化性 可以大大提高。 此外,用95%乙醇在40℃下消化240小时后,通过吹塑或通过注塑制备的部件制备的膜具有很少的从表面析出的沉淀,并具有优异的表面外观性能。 而且,印刷过程中可生物降解的聚酯组合物的印刷不良可以大大改善,并且该膜显示出优异的印刷性能。
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公开(公告)号:EP3260497A1
公开(公告)日:2017-12-27
申请号:EP17762459.0
申请日:2017-02-24
申请人: Kingfa Sci. & Tech. Co., Ltd. , Zhuhai Wango Chemical Co., Ltd. , Tianjin Kingfa New Material Co., Ltd.
发明人: LU, Changli , YUAN, Zhimin , CAI, Tongmin , HUANG, Xianbo , ZENG, Xiangbin , JIAO, Jian , YUAN, Renxu , ZHONG, Yuke , XIONG, Kai , YANG, Hui , MAI, Kaijin , DONG, Xueteng
IPC分类号: C08L67/02 , C08L67/04 , C08L3/02 , C08L25/14 , C08K5/1535 , C08K5/07 , C08K13/02 , C08K3/34 , C08K3/26
CPC分类号: C08L67/02 , C08J5/18 , C08J2367/02 , C08J2403/02 , C08J2425/14 , C08J2467/04 , C08K3/26 , C08K3/34 , C08K5/07 , C08K5/1535 , C08K13/02 , C08L3/02 , C08L25/14 , C08L67/04 , C08L2201/06 , C08L2203/16 , C08L2205/02 , C08L2205/03 , C08L2205/035
摘要: The present invention discloses a biodegradable polyester composition, wherein based on a total weight of the biodegradable polyester composition, a weight content of tetrahydrofuran is 3ppm-200ppm; and based on the total weight of the biodegradable polyester composition, a weight content of cyclopentanone is 0.5ppm-85ppm. In the present invention, by adding tetrahydrofuran and cyclopentanone into the composition and controlling the content of tetrahydrofuran and the content of cyclopentanone in a certain range in the composition, poor printing of the biodegradable polyester composition during the printing process can be hugely improved, neither the ink stripping off the film material, nor excessive ink adhering to the film material, so that the film shows excellent printing performance. Moreover, a lubrication degree of a film of biodegradable polyester during a blow molding process can be improved. When a velocity of film blowing is 176 Kg/h, a range of a film thickness is less than 0.2µm and a relative deviation of the film thickness is less than 1%. Bubble stability and continuity of film blowing are guaranteed.
摘要翻译: 本发明公开了一种生物可降解聚酯组合物,其中基于生物可降解聚酯组合物的总重量,四氢呋喃的重量含量为3ppm-200ppm; 基于生物可降解聚酯组合物的总重量,环戊酮的重量含量为0.5ppm-85ppm。 在本发明中,通过向组合物中加入四氢呋喃和环戊酮,并且在组合物中控制四氢呋喃的含量和环戊酮的含量在一定范围内,可以极大地提高印刷过程中生物可降解聚酯组合物的印刷不良, 油墨剥离膜材料,也不会有过多的油墨粘附到膜材料上,使得膜显示出优异的印刷性能。 此外,可以改善吹塑成型过程中生物可降解聚酯膜的润滑程度。 当吹膜速度为176Kg / h时,膜厚的范围小于0.2μm,膜厚的相对偏差小于1%。 泡沫稳定性和吹膜连续性得到保证。
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