MICROWAVE PLASMA BIOMASS ENTRAINED FLOW GASIFIER AND PROCESS
    4.
    发明授权
    MICROWAVE PLASMA BIOMASS ENTRAINED FLOW GASIFIER AND PROCESS 有权
    微波等离子体生物质气流床气化炉及工艺

    公开(公告)号:EP2799522B1

    公开(公告)日:2017-09-20

    申请号:EP12863948.1

    申请日:2012-10-26

    摘要: A microwave plasma biomass entrained flow gasifier comprising a gasifier body (8), a fuel inlet arranged at the lower part of the gasifier body (8), a synthetic gas outlet at the top part of the gasifier body (8), and a slag discharge outlet (10) at the bottom part of the gasifier body (8). Arranged outside the gasifier body (8) is a fuel preprocessing system, comprising a fuel crushing apparatus (1), a sieving apparatus (2) arranged downstream to the fuel crushing apparatus (1), a particle diameter-qualified fuel chamber (3) and a particle diameter-unqualified fuel chamber (4) arranged in parallel and downstream to the sieving apparatus (2), and a gasifier-front chamber arranged downstream to the particle diameter-qualified fuel chamber (3), where the gasifier-front chamber (5) is connected at the bottom part thereof to the gasifier body (8) via a burner. Arranged at the synthesis gas outlet (9) at the top part of the gasifier is a synthesis gas monitoring unit (12). Also provided is a process utilizing the gasifier for biomass entrained flow gasification. The process comprises: 1) a biomass fuel is preprocessed; 2) a microwave plasma working gas is introduced into a plasma generator, excited into plasma then injected into the gasifier; 3) biomass fuel powdery particles are injected into the gasifier via the burner, while at the same time, an oxidizer is fed into the system via an oxygen/steam inlet, injected into the gasifier simultaneously with the biomass fuel, the biomass fuel is subjected to a thermochemical reaction within the gasifier; 4) the temperature and content of the synthesis gas are monitored for implementing adjustments in oxygen flow rate, steam flow rate, and microwave power; the temperature at the synthesis gas outlet is between 900°C and 1200°C; finally, the synthesis gas is drawn out from the synthesis gas outlet at the top part, while at the same time a liquid slag is discharged via the slug discharge outlet.

    摘要翻译: 本发明公开了一种微波等离子体生物质夹带流气化炉,包括气化炉体(8),设置在气化炉体(8)下部的燃料入口,气化炉体(8)顶部的合成气出口,炉渣 排气口10位于气化器本体8的底部。 燃料预处理系统包括燃料破碎装置(1),布置在燃料破碎装置(1)下游的筛分装置(2),颗粒直径合格的燃料室(3) (2)平行且下游布置的粒径不合格燃料室(4)以及布置在粒径合格燃料室(3)下游的气化器前室,其中气化器前室 (5)的底部通过燃烧器连接到气化器本体(8)。 合成气监测单元(12)设置在气化器顶部的合成气出口(9)处。 还提供了利用气化器进行生物质夹带气流的方法。 该过程包括:1)对生物质燃料进行预处理; 2)将微波等离子体工作气体引入等离子体发生器,激发成等离子体,然后注入气化器; 3)通过燃烧器将生物质燃料粉末颗粒注入气化器中,同时经由氧气/蒸汽入口将氧化剂供给到系统中,与生物质燃料同时注入到气化器中,生物质燃料经受 到气化器内的热化学反应; 4)监测合成气的温度和含量,以实施氧气流量,蒸汽流量和微波功率的调整; 合成气出口处的温度在900℃和1200℃之间; 最后,合成气从顶部的合成气出口排出,同时液渣通过排渣口排出。

    ULTRA HIGH PRESSURE COOLING AND PURIFICATION PROCESS AND APPARATUS FOR OIL PRODUCTION BIOMASS SYNGAS
    6.
    发明公开
    ULTRA HIGH PRESSURE COOLING AND PURIFICATION PROCESS AND APPARATUS FOR OIL PRODUCTION BIOMASS SYNGAS 审中-公开
    超高压冷却和净化生产生物质合成气的方法和设备

    公开(公告)号:EP3315588A1

    公开(公告)日:2018-05-02

    申请号:EP16813569.7

    申请日:2016-04-15

    摘要: An ultra high pressure cooling and purification process and apparatus for an oil production biomass syngas, the process comprising: (1) performing two-stage waste heat recovery and cyclone dust removal processing, with by-products of high pressure and low pressure steam, (2) removing a portion of heavy tar precipitated out from the biomass syngas by cooling in a second stage indirect heat exchange process, (3) further removing dust and lowering a temperature using a washing solution, (4) conducting deep removal of dust and coke using a moist air flow, and purging to remove remaining small amounts of dust and tar fog in the biomass syngas, and causing the pressure thereof to drop to 0.3-1 MPa, so as to obtain a biomass syngas having respective dust and tar fog contents of less then 10 mg/Nm3, and a temperature of

    摘要翻译: 一种用于采油生物质合成气的超高压冷却和净化工艺及设备,所述工艺包括:(1)利用高压和低压蒸汽的副产品进行两阶段余热回收和旋风除尘处理,( 2)通过在第二阶段间接热交换过程中冷却从生物质合成气中除去部分重质焦油,(3)使用洗涤溶液进一步除去灰尘并降低温度,(4)深度除去灰尘和焦炭 使用潮湿的空气流,并吹扫以去除生物质合成气中残留的少量灰尘和焦油雾,并使其压力降至0.3-1MPa,从而获得具有相应灰尘和焦油雾含量的生物质合成气 小于10mg / Nm 3,温度<45℃。 该设备主要由集成热交换和除尘装置,填料塔洗涤器和湿式静电除尘器组成。 本发明通过优化工艺方案设计,控制合适的工艺参数,实现了生物质合成气的阶梯式冷却,分阶段回收废热,分阶段除尘,达到了脱焦,冷却,净化的目的。

    STRUCTURED IRON-BASED CATALYST FOR PRODUCING A-OLEFIN FROM SYNTHESIS GAS AND PREPARATION METHOD AND USE
    8.
    发明公开
    STRUCTURED IRON-BASED CATALYST FOR PRODUCING A-OLEFIN FROM SYNTHESIS GAS AND PREPARATION METHOD AND USE 审中-公开
    结构化催化剂对铁基由合成气生产烯烃和方法及用途

    公开(公告)号:EP3135371A1

    公开(公告)日:2017-03-01

    申请号:EP15782614.0

    申请日:2015-02-06

    摘要: A structured iron-based catalyst for producing an α-olefin from a synthesis gas and a preparation method and use. The catalyst comprises an active component iron, auxiliary agents and a carrier, wherein the auxiliary agents comprise a first auxiliary agent which is a transition metal or a transition metal oxide and a second auxiliary agent which is a metal oxide. The content of the active component iron is 50.0%-99.8%, the content of the first auxiliary agent is 0-5.0%, the content of the second auxiliary agent is 0-10% and the balance is the carrier which is silicon dioxide. A precursor of the active component iron, a precursor of the first auxiliary agent and the carrier silicon dioxide are made into mono-dispersed particles using a heat dispersing method, and then impregnated with a solution of a precursor of the second auxiliary agent to obtain the structured iron-based catalyst. The above-mentioned structured iron-based catalyst is used for producing an α-olefin from a synthesis gas. Since the mono-dispersed structured iron-based catalyst can generate an active centre suitable for the generation of the α-olefin, it thus has good selectivity.

    摘要翻译: 结构化的铁基催化剂用于从合成气±烯烃及其制备方法和用途生产。 活性组分的铁,助剂和载体,worin辅助剂包含第一辅助剂的所有这是一种过渡金属或过渡金属氧化物和第二辅助剂全部是金属氧化物的催化剂包括。 活性成分的铁的含量为50.0%-99.8%,第一辅助剂的含量为0-5.0%,第二辅助剂的含量为0-10%,余量为载体所有这些是二氧化硅。 活性组分的铁的前体,所述第一辅助剂和载体的二氧化硅的前体被制成使用热分散法单分散性颗粒,然后与第二辅助剂的前体的溶液,以获得浸渍过的 结构化的铁基催化剂。 上述结构化铁基催化剂用于在从合成气±烯烃制造。 由于单分散结构的铁基催化剂可在适合于烯烃±的产生活性中心生成,因此,它具有良好的选择性。

    OPTIMIZED INTEGRATED SYSTEM FOR SOLAR-BIOMASS HYBRID ELECTRICITY GENERATION
    9.
    发明公开
    OPTIMIZED INTEGRATED SYSTEM FOR SOLAR-BIOMASS HYBRID ELECTRICITY GENERATION 审中-公开
    优化整合系统ZUR HYBRIDEN SOLAR-BIOMASSENSTROMERZEUGUNG

    公开(公告)号:EP3130770A1

    公开(公告)日:2017-02-15

    申请号:EP15777409.2

    申请日:2015-02-06

    摘要: An optimized integrated system for solar-biomass hybrid electricity generation. A heat transfer oil outputted from a solar farm (1 and 2) of a solar thermal boiler system flows sequentially through a solar thermal evaporator (6) and a solar thermal heater (5) then back to a heat transfer oil storage tank (4) and is then delivered via a circulation oil pump (3) to the solar farm to complete a heat transfer oil circulation. Solar thermal steam produced by the solar thermal evaporator is delivered to a biomass boiler system (9) via a steam header (7). Auxiliary steam produced by a coal-fired or gas-fired or oil-fired auxiliary boiler (8) also is mixed with the solar thermal steam and delivered to the biomass boiler system via the steam header. The solar thermal mixed steam and steam produced by a biomass boiler itself are delivered to a turbo generator (10) to drive an electric generator (11) into generating electricity. The system simplifies solar thermal power generation system and equipment configurations, provides stable electricity generation, high thermal efficiency, and extended service life.

    摘要翻译: 一个优化的太阳能 - 生物质混合发电综合系统。 从太阳能热水锅炉系统的太阳能农场(1和2)输出的传热油依次通过太阳能热蒸发器(6)和太阳能热能加热器(5),然后返回到传热储油罐(4) 然后通过循环油泵(3)输送到太阳能农场,以完成传热油循环。 由太阳能热蒸发器产生的太阳能热蒸汽通过蒸汽集管(7)输送到生物质锅炉系统(9)。 由燃煤或燃气或燃油辅助锅炉(8)生产的辅助蒸汽也与太阳能热蒸汽混合并通过蒸汽集管输送到生物质锅炉系统。 由生物质锅炉本身产生的太阳能热混合蒸汽和蒸汽被输送到涡轮发电机(10)以驱动发电机(11)发电。 该系统简化了太阳能热发电系统和设备配置,提供稳定的发电,高热效率和延长的使用寿命。