摘要:
A surface-treated carbon black for reinforcing a rubber is produced by a process comprising the surface-treating reaction step of dispersing a carbon black for the reinforcement of rubber in water and making amorphous silica adhere to the surface of the carbon black through the reaction of a metal salt of silicic acid with acid, and the aging step subsequent to the reaction step of keeping the pH of the resulting system at 7 or below.
摘要:
A process for the production of modified polymers which comprises reacting a polymer with a tetramethylpiperidinyloxy (TEMPO) derivative having a functional group (A) in the presence of a radical initiator to prepare a polymer grafted with the functional group (A), adding an additive at need, and then reacting the resulting polymer with a compound having a functional group (B) reactive with the functional group (A) and which enables easy introduction of various compounds having functional groups into nonpolar polymers at a low cost.
摘要:
A block copolymer (1) comprising a block of a conjugated diene polymer and a block of a random copolymer of a conjugated diene with an aromatic vinyl, (2) having a weight ratio of the polymer block A to the copolymer B of (5 : 95) to (95 : 5), (3) having a content of the bound aromatic vinyl in the copolymer block B of 1 to 50 % by weight, (4) having a weight-average molecular weight (Mw) of 100,000 to 5,000,000, and (5) having at least two transition points present in the range of from -150 to +150 °C as measured with a differential scanning calorimeter, a process for preparing the same, a rubber composition comprising the same, and a pneumatic tire made therefrom.
摘要:
A process for producing a modified polymer improved in adhesiveness and processability, which comprises causing a polymer, e.g., an elastomer, to generate a carbon radical and, after or simultaneously with the radical generation, reacting the polymer with a compound having in the molecule a free radical stably present at ordinary temperature in the presence of oxygen to thereby incorporate into the polymer an organic group derived from the compound having the free radical.
摘要:
A rubber composition having improved properties containing a starting rubber (e.g., diene rubber) and a polysiloxane having the following alkoxysilyl group (I) and/or acyloxysilyl group (II) and having an average degree of polymerization of 3 to 10,000:
≡ Si - OR 1
≡ Si - OCOR 2 wherein, R 1 is a substituted or unsubstituted monovalent hydrocarbon group having 1 to 18 carbon atoms or an organic group containing an ether bond and R 2 is hydrogen or a hydrocarbon group having 1 to 21 carbon atoms.
摘要:
To modify a diene-based rubber whereby the dispersibility of silica and the abrasion resistance or heat buildup resistance are improved. A modified diene-based rubber obtained by adding and reacting, to a diene-based rubber (A), a compound (B) having, in the molecule thereof, a nitroxide free radical stable at an ordinary temperature and in the presence of oxygen, a radical initiator (C) and a radical polymerizable monomer (D) having a functional group in the molecule thereof and a rubber composition and pneumatic tire containing the same.
摘要:
A filler for reinforcing rubbers, prepared by depositing an alkoxysilyl compound on a particulate filler whose surface layer is made of at least both carbon black and silica.
摘要:
A process for producing surface-treated carbon black for rubber reinforcement characterized by providing carbon black and organosiloxane together; and then heating the mixture to a temperature of 60 DEG C to 200 DEG C to deposit a silicon dioxide residue on the surface of the carbon black and a rubber composition using the same.
摘要:
A pneumatic tire having an air-barrier layer comprising a lowly permeable thermoplastic elastomer composition comprising a barrier resin composition in a thermoplastic elastomer composed of a thermoplastic resin composition as a continuous phase and a rubber composition as a dispersed phase, wherein the barrier resin composition has such a phase structure as dispersed in a flat form in the thermoplastic elastomer, has excellent flexibility and gas permeation resistance, and enables a reduction in the weight of the tire.