公开(公告)号：EP2246389A4

公开(公告)日：2014-07-02

申请号：EP09706654

申请日：2009-01-29

申请人： ZEON CORP

发明人： TSUKADA AKIRA ,  EJIRI KAZUHIRO ,  KATANO CHIKARA

IPC分类号： C08L9/04 ,  B32B25/04 ,  F16L11/06

CPC分类号： C08L79/04 ,  B32B1/08 ,  B32B25/04 ,  B32B25/08 ,  B32B25/14 ,  B32B27/06 ,  B32B27/304 ,  B32B27/308 ,  B32B2270/00 ,  B32B2307/306 ,  B32B2307/308 ,  B32B2307/536 ,  B32B2307/54 ,  B32B2307/714 ,  B32B2307/7265 ,  B32B2597/00 ,  B32B2605/00 ,  C08K3/013 ,  C08K3/04 ,  C08K5/11 ,  C08K5/5419 ,  C08K2201/016 ,  C08L9/02 ,  C08L27/06 ,  C08L33/00 ,  F16L11/06 ,  F16L2011/047 ,  Y10T428/1393 ,  C08L33/20 ,  C08L9/04 ,  C08L2666/04

摘要： A nitrile copolymer latex composition containing a latex of a nitrile copolymer rubber (A) having ±,²-ethylenically unsaturated nitrile monomer units in 10 to 75 wt%, conjugated diene monomer units in 5 to 89.9 wt%, and cationic monomer units and/or monomer units able to form cations in 0.1 to 20 wt%, an inorganic filler (B) having an aspect ratio of 30 to 2,000, and a plasticizer (C) having an SP value by the HOY method of 8 to 10.2 (cal/cm 3 ) 1/2 , wherein a content of said plasticizer (C) is 0.1 to 200 parts by weight with respect to said nitrile copolymer rubber (A) as 100 parts by weight is provided.

公开(公告)号：EP1479721A4

公开(公告)日：2005-11-16

申请号：EP03703095

申请日：2003-01-30

申请人： ZEON CORP

发明人： TSUKADA AKIRA ,  NOMOTO HIROFUMI

IPC分类号： C08L9/02 ,  C08F265/08 ,  C08K3/00 ,  C08K3/22 ,  C08K3/26 ,  C08K3/34 ,  C08K5/09 ,  C08K5/098 ,  C08K5/14 ,  C08L15/00

CPC分类号： C08K3/22 ,  C08C19/02 ,  C08K3/013 ,  C08K3/26 ,  C08K3/34 ,  C08K5/098 ,  C08K5/14 ,  C08L15/005 ,  C08L9/02

摘要： A rubber composition comprising (A) 100 weight parts of a nitrile group-containing copolymer rubber having an iodine value of not larger than 100 and comprising 10-60% by weight of alpha , beta -ethylenically unsaturated nitrile monomer units, and (B) 3-200 weight parts of an acid-acceptor selected from zeolite compounds, hydrotalcite compounds and aluminum hydroxide gel, and optionally (C) 3-100 weight parts of a metal salt of alpha , beta -ethylenically unsaturated carboxylic acid. A vulcanizable rubber composition comprising this rubber composition and (D) 0.2-10 weight parts of an organic acid vulcanizing agent gives a rubber vulcanizate having good resistance to deteriorated oil.

公开(公告)号：EP3124532A4

公开(公告)日：2017-11-22

申请号：EP15768962

申请日：2015-03-24

申请人： ZEON CORP

发明人： TSUKADA AKIRA ,  NAKAMURA TADASHI

IPC分类号： C08L9/02 ,  B32B25/14 ,  C08C19/02 ,  C08F220/46 ,  C08F220/48 ,  C08K3/00 ,  C08K3/04 ,  C08K3/22 ,  C08K3/34 ,  C08K7/00 ,  C08L27/06 ,  C08L33/04 ,  C08L33/18 ,  C08L35/04 ,  F16L11/04

CPC分类号： C08F220/46 ,  B32B25/14 ,  B32B2305/30 ,  B32B2305/72 ,  B32B2307/7265 ,  B32B2439/00 ,  B32B2581/00 ,  B32B2597/00 ,  C08C19/02 ,  C08F220/48 ,  C08F2500/17 ,  C08F2800/20 ,  C08F2810/20 ,  C08K3/013 ,  C08K3/04 ,  C08K3/22 ,  C08K3/346 ,  C08K2003/2296 ,  C08K2201/016 ,  C08L9/02 ,  C08L9/04 ,  C08L27/06 ,  C08L33/04 ,  C08L33/18 ,  C08L35/04 ,  F16L11/04 ,  C08L33/10

摘要： A nitrile copolymer rubber composition comprising a nitrile copolymer rubber (A) containing 35 to 80 wt% of ±,²-ethylenically unsaturated nitrile monomer units (a1), 19.5 to 64.5 wt% of conjugated diene monomer units (a2), and 0.5 to 20 wt% of ±,²-ethylenically unsaturated carboxylic acid monomer units (a3) and an inorganic filler (B) with an aspect ratio of 30 to 2,000, wherein a content of the inorganic filler (B) with respect to 100 parts by weight of the nitrile copolymer rubber (A) is 1 to 200 parts by weight is provided.

公开(公告)号：EP2937382A4

公开(公告)日：2016-08-24

申请号：EP13865172

申请日：2013-12-19

申请人： ZEON CORP

发明人： TSUKADA AKIRA

IPC分类号： C08L9/02 ,  C08F220/44 ,  C08K7/02 ,  C08L1/02 ,  C08L15/00 ,  C08L27/06 ,  C08L33/06 ,  C08L33/20

CPC分类号： C08L33/20 ,  C08F220/44 ,  C08F236/12 ,  C08L1/02 ,  C08L9/02 ,  C08L15/005 ,  C08F236/06 ,  C08F226/06

摘要： A nitrile copolymer rubber composition containing a nitrile copolymer rubber (A) which contains ±,²-ethylenically unsaturated nitrile monomer units (a1) 15 to 80 wt%, conjugated diene monomer units (a2) 20 to 85 wt%, and cationic monomer units and/or monomer units able to form cations (a3) 0 to 30 wt%, and flat cellulose particles (B) with an aspect ratio of 30 to 600, wherein a content of the flat cellulose particles (B) is 1 to 200 parts by weight with respect to 100 parts by weight of the nitrile copolymer rubber (A) is provided.

公开(公告)号：EP2746330A4

公开(公告)日：2015-06-17

申请号：EP12834133

申请日：2012-09-21

申请人： ZEON CORP

发明人： TSUKADA AKIRA ,  TAKEYAMA YOSHIHISA

IPC分类号： C08L9/02 ,  C08K5/11 ,  C08L27/06

CPC分类号： C08L15/00 ,  C08K5/11 ,  C08L9/02 ,  C08L25/08 ,  C08L27/06 ,  Y10T428/1379 ,  C08L71/02

摘要： A nitrile copolymer rubber composition containing a nitrile copolymer rubber (A) which contains ±,²-ethylenically unsaturated nitrile monomer units (a1) 35 to 85 wt%, conjugated diene monomer units which may be at least partially hydrogenated (a2) 15 to 65 wt%, cationic monomer units (a3) 0 to 30 wt%, and aromatic vinyl monomer units (a4) 0 to 50 wt%, the total content of the ±,²-ethylenically unsaturated nitrile monomer units (a1) and the aromatic vinyl monomer units (a4) being 35 to 85 wt%, a vinyl chloride resin (B), and a plasticizer (C) with a specific structure is provided.

公开(公告)号：EP1247835A4

公开(公告)日：2005-01-05

申请号：EP00966508

申请日：2000-10-16

申请人： ZEON CORP

发明人： KOTSUJI HIROYUKI ,  TSUKADA AKIRA

IPC分类号： C08C19/02 ,  C08F236/14 ,  C08L15/00 ,  C08L33/04 ,  C08C19/00 ,  C08L9/02

CPC分类号： C08C19/02 ,  C08F236/14 ,  C08L15/005

摘要： A highly saturated nitrile copolymer rubber which comprises 10 to 40 wt.% alpha , beta - ethylenically unsaturated nitrile monomer units (a), 10 to 60 wt.% alpha , beta - ethylenically unsaturated carboxylic ester monomer units (b), 0.01 to 56 wt.% conjugated diene monomer units (c), and 35 to 69.95 wt.% saturated conjugated diene monomer units (d), in which the total content of the monomer units (c) and the monomer units (d) is 20 to 70 wt.%, the monomer units (d) account for 70 wt.% or more of the sum of the monomer units (c) and the monomer units (d), and the difference between the extrapolated glass transition initiation temperature (Tig) and the extrapolated glass transition ending temperature (Teg) in differential scanning calorimetry is 10 DEG C or lower. The rubber is compounded with a crosslinking agent to crosslink it. Thus, a crosslinked object excellent in cold resistance, oil resistance, and dynamic properties is obtained.

公开(公告)号：EP2671914A4

公开(公告)日：2016-01-27

申请号：EP12742440

申请日：2012-02-02

申请人： ZEON CORP

发明人： TAKEYAMA YOSHIHISA ,  TSUKADA AKIRA

IPC分类号： C08L9/02 ,  C08C1/14 ,  C08C19/02 ,  C08F2/22 ,  C08F2/26 ,  C08F114/06 ,  C08F220/14 ,  C08F220/44 ,  C08F226/06 ,  C08F236/12 ,  C08J3/215 ,  C08J5/00 ,  C08K3/00 ,  C08K3/04 ,  C08K3/06 ,  C08K3/34 ,  C08K5/00 ,  C08K5/11 ,  C08K5/14 ,  C08K7/00 ,  C08L9/04 ,  C08L15/00 ,  C08L27/06 ,  C08L33/00 ,  C08L33/12 ,  F16L11/04

CPC分类号： C08J3/215 ,  C08C19/02 ,  C08F14/06 ,  C08F114/06 ,  C08F220/14 ,  C08F220/44 ,  C08F236/12 ,  C08J2309/02 ,  C08J2309/04 ,  C08J2315/00 ,  C08J2427/06 ,  C08J2433/06 ,  C08K3/04 ,  C08K3/06 ,  C08K3/346 ,  C08K5/0025 ,  C08K5/11 ,  C08L9/02 ,  C08L9/04 ,  C08L27/06 ,  C08L33/06 ,  C08L33/12 ,  C08F2/26 ,  C08F236/06 ,  C08F226/06

摘要： A nitrile rubber composition which contains a nitrile rubber (A) which contains ±,²-ethylenically unsaturated nitrile monomer units 20 to 80 wt%, conjugated diene monomer units which may be at least partially hydrogenated 20 to 80 wt%, and cationic monomer units 0 to 30 wt% and a layered inorganic filler (B) with a surface area particle size distribution where a) a median size (d50) of the cumulative surface area distribution is 0.20 µm to 6.0 µm and b) d90-d10 of the cumulative surface area distribution is 1.1 µm or more in a ratio of 1 to 100 parts by weight with respect to 100 parts by weigh of the nitrile rubber (A) is provided.

公开(公告)号：EP2343338A4

公开(公告)日：2015-01-07

申请号：EP09823662

申请日：2009-10-29

申请人： ZEON CORP

发明人： TSUKADA AKIRA ,  KATANO CHIKARA ,  EJIRI KAZUHIRO ,  NAKAMURA TADASHI

IPC分类号： C08L9/04 ,  C08K7/00 ,  C08L27/06 ,  C08L33/06

CPC分类号： C08K3/346 ,  C08K7/00 ,  C08L9/04 ,  C08L27/06 ,  C08L33/06 ,  C08L15/005 ,  C08L2666/04 ,  C08L2666/02

摘要： A nitrile copolymer latex composition containing a latex of a nitrile copolymer rubber (A) having ±,²-ethylenically unsaturated nitrile monomer units in 20 to 70 wt% and a plate-shaped filler (B), wherein said plate-shaped filler (B) has a swelling capacity with respect to water of 15 to 55 (ml/2g), a thixotropic index (TI value) when mixed with an aqueous medium in a 5 wt% concentration to obtain a slurry is 1 to 6, and a ratio of said plate-shaped filler (B) to said nitrile copolymer rubber (A), as 100 parts by weight, is 1 to 200 parts by weight.

公开(公告)号：EP2548919A4

公开(公告)日：2013-08-14

申请号：EP11756278

申请日：2011-03-15

申请人： ZEON CORP

发明人： TSUKADA AKIRA

IPC分类号： C08L9/02 ,  B32B1/08 ,  B32B25/14 ,  C08K3/00 ,  C08K5/053 ,  C08K5/06 ,  C08K5/548 ,  F16L11/06

CPC分类号： B32B1/08 ,  B32B25/14 ,  B32B2270/00 ,  B32B2597/00 ,  C08K3/013 ,  C08K5/053 ,  C08K5/06 ,  C08K5/548 ,  C08K2201/016 ,  C08L9/02

摘要： A nitrile copolymer rubber composition for hose use is provided containing a nitrile copolymer rubber (A) which has ±,²-ethylenically unsaturated nitrile monomer units in 20 to 80, an inorganic filler (B) with an aspect ratio of 30 to 2,000, a coupling agent (C), and a glycol compound (D), wherein the ratio of the coupling agent (C) is 0.05 to 15 parts by weight and the ratio of said glycol compound (D) is 0.05 to 15 parts by weight with respect to 100 parts by weight of the nitrile copolymer rubber (A).

公开(公告)号：EP1449873A4

公开(公告)日：2005-08-10

申请号：EP02800015

申请日：2002-09-26

申请人： ZEON CORP

发明人： TSUKADA AKIRA ,  FUJITA SHIGERU

IPC分类号： C08F2/44 ,  C08C19/02 ,  C08F220/18 ,  C08F236/14 ,  C08F279/00 ,  C08F279/02 ,  C08K5/098 ,  C08K5/14 ,  C08L9/02 ,  C08L15/00 ,  C08L51/04 ,  G09C1/00 ,  H04L9/32

CPC分类号： C08K5/14 ,  C08F279/02 ,  C08K5/098 ,  C08F220/06 ,  C08L13/00

摘要： A rubber composition comprising: (A) a nitrile copolymer rubber which comprises (a) 10 to 40 wt.% α,ß-ethylenically unsaturated nitrile monomer units, (b) 10 to 60 wt.% α,ß-ethylenically unsaturated carboxylic ester monomer units, (c) 0.01 to 56 wt.% conjugated diene monomer units, and (d) 14 to 69.99 wt.% saturated conjugated diene monomer units and in which the total content of the monomer units (c) and (d) is 20 to 70 wt.%, the content of the monomer units (d) is 70 wt.% or higher based on the sum of the monomer units (c) and (d), and the difference between the extrapolated glass transition initiation temperature (Tig) and the extrapolated glass transition ending temperature (Teg) in differential scanning calorimetry is 10°C or smaller; (B) a metal salt of an ethylenically unsaturated carboxylic acid; and (C) an organic peroxide. Also provided is a vulcanizate obtained by vulcanizing the rubber composition. The vulcanizate, which is obtained from the rubber composition, is excellent in cold resistance, oil resistance, and compression set.