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    Proton-conducting polymer
    1.
    发明公开
    Proton-conducting polymer 有权
    质子聚合物

    公开(公告)号：EP2562864A1

    公开(公告)日：2013-02-27

    申请号：EP12189523.9

    申请日：2007-10-30

    申请人： Nippon Steel Chemical Co., Ltd.

    发明人： Kawada, Atsushi ,  Tashiro, Aya

    IPC分类号： H01M8/10 ,  C07D251/70 ,  C08F20/34 ,  C08G73/06

    CPC分类号： C08F20/34 ,  C07D251/70 ,  C08G73/0644 ,  C08G73/065 ,  C08G73/0655 ,  C08G73/0661 ,  H01M8/103 ,  H01M8/1048 ,  H01M8/1072 ,  H01M2300/0082 ,  H01M2300/0085 ,  H01M2300/0091 ,  Y02P70/56

    摘要： The present invention provides a proton conducting polymer which provides proton conductivity without humidification and is suitable for electrochemical device materials such as solid electrolytes for fuel cells and electrolytes for batteries. The proton conducting compound is produced by polymerization of a salt of a melamine compound represented by the following equation (2) and a Bronsted acid:

    wherein, R 1 , R 2 , R 3 , R 4 , and R 5 each is independently an alkyl group, an aryl group, a heterocyclic group, or hydrogen and at least one of them is an alkyl group, an aryl group, or a heterocyclic group; R 2 and R 3 or R 4 and R 5 may join together to form a heterocyclic structure; and the alkyl group, the aryl group, and the heterocyclic group each may have a substituent selected from the group of alkyl groups of 1 to 6 carbon atoms, aryl groups of 6 to 12 carbon atoms, heterocyclic groups, an amino group, alkylamino groups of 1 to 6 carbon atoms, a nitro group, a carboxyl group, acryl groups of 1 to 6 carbon atoms, acyloxy groups of 1 two 6 carbon atoms, a cyano group, alkylsulfonyl groups of 1 to 6 carbon atoms, alkylsulfonyloxy groups of 1 to 6 carbon atoms, a sulfoxide group, a sulfonic acid group, alkoxycarbonyl groups of 1 to 6 carbon atoms, aryloxycarbonyl groups of 6 to 12 carbon atoms, aryloxy groups of 6 to 12 carbon atoms, and alkynyl groups of 2 to 6 carbon atoms; R 6 is hydrogen or an alkyl group and n is an integer equal to or larger than 1,

    摘要翻译： 本发明提供质子传导性聚合物，其在不加湿的情况下提供质子传导性，并且适用于电化学装置材料，例如用于燃料电池的固体电解质和用于电池的电解质。 质子传导性化合物是通过聚合由下式（2）表示的三聚氰胺化合物的盐和布朗斯台德酸来制备的：其中，R 1，R 2，R 3，R 4和R 5各自独立地为烷基 基团，芳基，杂环基或氢，并且它们中的至少一个是烷基，芳基或杂环基; R 2和R 3或R 4和R 5可以连接在一起形成杂环结构; 烷基，芳基和杂环基各自可以具有选自1〜6个碳原子的烷基，6〜12个碳原子的芳基，杂环基，氨基，烷基氨基 1〜6个碳原子的硝基，羧基，1〜6个碳原子的丙烯酰基，1〜6个碳原子的酰氧基，1〜6个碳原子的氰基，烷基磺酰基，1〜6个碳原子的烷基磺酰氧基 6个碳原子，亚砜基，磺酸基，1〜6个碳原子的烷氧基羰基，6〜12个碳原子的芳氧基羰基，6〜12个碳原子的芳氧基，2〜6个碳原子的炔基 ; R 6是氢或烷基，n是等于或大于1的整数，

    ORGANIC ELECTROLUMINESCENT ELEMENT
    2.
    发明公开
    ORGANIC ELECTROLUMINESCENT ELEMENT 有权
    有机电致发光元件

    公开(公告)号：EP2541635A1

    公开(公告)日：2013-01-02

    申请号：EP11747125.0

    申请日：2011-01-27

    申请人： Nippon Steel Chemical Co., Ltd.

    发明人： TADA Masashi ,  OGAWA Junya ,  KAI Takahiro ,  MATSUMOTO Megumi ,  TSUTSUMI Yasuhisa

    IPC分类号： H01L51/50 ,  C07D209/86 ,  C07D401/14 ,  C07D403/14 ,  C07D405/14 ,  C07D409/14 ,  C09K11/06

    CPC分类号： C07D403/10 ,  C07D209/86 ,  C07D401/14 ,  C07D403/14 ,  C07D405/14 ,  C07D409/14 ,  H01L51/0067 ,  H01L51/0072 ,  H01L51/0073 ,  H01L51/0074 ,  H01L51/0087 ,  H01L51/5016 ,  H01L51/5048 ,  H01L51/5096 ,  Y10S428/917

    摘要： Disclosed is an organic electroluminescent device (organic EL device) that is improved in luminous efficiency, sufficiently secures driving stability, and has a simple configuration. This organic EL device comprises organic layers between an anode and a cathode piled one upon another on a substrate and at least one organic layer selected from a light-emitting layer, a hole-transporting layer, an electron-transporting layer, and a hole-blocking layer contains a carbazole compound represented by the following formula (1). In the case where the light-emitting layer of the organic electroluminescent device contains a phosphorescent dopant and a host material, it is the carbazole compound that is contained as the host material. In formula (1), X is C-Y or a nitrogen atom; Y is a hydrogen atom, an alkyl group, a cycloalkyl group, or an aromatic group; n is an integer of 2 to 4: A is an n-valent aromatic group; L is a direct bond or a divalent aromatic group; and R is a hydrogen atom, an alkyl group, or a cycloalkyl group.

    摘要翻译： 本发明公开了一种发光效率提高，充分确保驱动稳定性并且结构简单的有机电致发光器件（有机EL器件）。 该有机EL元件具备：在基板上层叠的阳极与阴极之间的有机层，以及选自发光层，空穴输送层，电子输送层和空穴输送层中的至少一个有机层， （1）表示的咔唑化合物。 在有机电致发光元件的发光层含有磷光掺杂剂和主体材料的情况下，作为主体材料含有咔唑化合物。 在式（1）中，X是C-Y或氮原子; Y是氢原子，烷基，环烷基或芳族基团; n是2至4的整数：A是n价芳族基团; L是直接键或二价芳族基团; 并且R是氢原子，烷基或环烷基。

    CURABLE RESIN COMPOSITION, CURED ARTICLE THEREOF, AND OPTICAL MATERIAL
    3.
    发明公开
    CURABLE RESIN COMPOSITION, CURED ARTICLE THEREOF, AND OPTICAL MATERIAL 审中-公开
    HÄRTBAREHARZZUSAMMENSETZUNG，GEHÄRTETERARTIKEL DARAUS UND OPTISCHES MATERIAL

    公开(公告)号：EP2540751A1

    公开(公告)日：2013-01-02

    申请号：EP11747433.8

    申请日：2011-02-24

    申请人： Nippon Steel Chemical Co., Ltd.

    发明人： KAWABE Masanao ,  WASANO Tsugutoshi ,  MIYATA Tsuyoshi

    IPC分类号： C08F257/00 ,  C08F212/32 ,  C08F220/10 ,  G02B1/04

    CPC分类号： G02B1/041 ,  C08F265/06 ,  C08L33/08 ,  C08L33/10 ,  C08F222/1006

    摘要： Provided is a curable resin composition which has excellent optical properties, heat resistance, transparency, low water absorbability, and mold release property in molding, and reduces the occurrence of a burr from a mold. Also provided are a cured product thereof and an optical material. The curable resin composition includes: a component (A): a soluble polyfunctional (meth)acrylic acid ester copolymer which is obtained by copolymerizing components including a monofunctional (meth) acrylic acid ester (a) having an alicyclic structure, a bifunctional (meth) acrylic acid ester (b), and 2,4-diphenyl-4-methyl-1-pentene (c), has a reactive (meth) acrylate group derived from (b) in a side chain and a structural unit derived from (c) at an end, has a Mw of 2,000 to 20, 000, and is soluble in an organic solvent; a component (B): a polyfunctional (meth)acrylate; and a component (C): an initiator, in which the blending amounts (weight ratio) of the respective components are as follows: (B)/(A)=5 to 250/100, and (C)/[(B)+(A)]=0.1 to 10/100.

    摘要翻译： 提供一种在成型时具有优异的光学性能，耐热性，透明性，低吸水性和脱模性的固化性树脂组合物，并且减少了来自模具的毛刺的发生。 还提供了其固化产物和光学材料。 固化性树脂组合物包括：成分（A）：通过使包含具有脂环结构的单官能（甲基）丙烯酸酯（a），双官能（甲基）丙烯酸酯共聚物， 丙烯酸酯（b）和2,4-二苯基-4-甲基-1-戊烯（c）在侧链具有衍生自（b）的反应性（甲基）丙烯酸酯基团和衍生自（c ）的Mw为2000〜2000，可溶于有机溶剂; 组分（B）：多官能（甲基）丙烯酸酯; （B）/（A）= 5〜250/100，（C）/ [（B））的组分（C）：其中各成分的配合量（重量比） +（A）] = 0.1〜10/100。

    SURFACE-TREATED COPPER FOIL, METHOD FOR PRODUCING SAME, AND COPPER CLAD LAMINATED BOARD
    5.
    发明公开
    SURFACE-TREATED COPPER FOIL, METHOD FOR PRODUCING SAME, AND COPPER CLAD LAMINATED BOARD 审中-公开
    表面处理铜箔，方法用于生产和覆铜箔层压板

    公开(公告)号：EP2527498A1

    公开(公告)日：2012-11-28

    申请号：EP11734780.7

    申请日：2011-01-21

    申请人： Furukawa Electric Co., Ltd. ,  Nippon Steel Chemical Co., Ltd.

    发明人： FUJISAWA, Satoshi ,  UNO, Takeo ,  HATTORI, Koichi

    IPC分类号： C25D7/06 ,  B32B15/01 ,  B32B15/08 ,  C25D5/10 ,  H05K1/09

    CPC分类号： C25D5/34 ,  B32B15/01 ,  B32B15/08 ,  B32B2457/00 ,  C22C19/002 ,  C22C19/03 ,  C25D3/562 ,  C25D5/48 ,  H05K3/384 ,  H05K2201/0154 ,  Y10T156/10 ,  Y10T428/12438 ,  Y10T428/12451 ,  Y10T428/12472 ,  Y10T428/12535 ,  Y10T428/12556 ,  Y10T428/12792 ,  Y10T428/12882 ,  Y10T428/1291

    摘要： Provided is an industrially excellent surface-treated copper foil which satisfies requirements for adhesiveness to an insulating resin such as polyimide, heat-resistant adhesiveness, chemical resistance and soft etching properties. Also provided is a method for producing a surface-treated copper foil which achieves a high adhesion strength between an insulating resin and the copper foil, shows high chemical resistance in circuit formation and sustains good soft etching properties after forming vias by laser-processing. A base copper foil is subjected to a roughening treatment to give a surface roughness (Rz) of 1.1 µm or below. On the roughened surface, an Ni-Zn alloy layer is formed. The aforesaid roughening treatment is conducted in such a manner that the roughened surface comprises sharp-pointed convexes, which have a width of 0.3-0.8 µm, a height of 0.6-1.8 µm and an aspect ratio of 1.2-3.5, and the surface roughness (Rz) of said base copper foil is increased by 0.05-0.3 µm. The aforesaid Ni-Zn alloy layer has a Zn content of 6-30 wt% and a Zn deposition amount of 0.08 mg/dm 2 or more.

    摘要翻译： 本发明提供一种用于SATIS外资企业粘合性要求，在绝缘性树脂的工业上优异的表面处理铜箔：如聚酰亚胺，耐热粘合性，耐化学性和软蚀刻性。 如此提供的是一种用于制造其实现绝缘性树脂和铜箔之间的密合强度高的表面处理铜箔，示出了在电路形成高耐化学性，并通过激光加工形成通孔后维持goodsoft蚀刻性。 甲碱铜箔进行粗化处理，得到的1.1微米或以下的表面粗糙度（R z）表示。 在粗糙化的表面，Ni-Zn合金层的形成。 上述粗糙化处理是在寻求的方式进行没有粗糙表面包括尖锐的凸部，其具有0.3-0.8微米的宽度，0.6-1.8微米，1.2-3.5的纵横比的高度，并且，表面粗糙度 所述基座铜箔（裕度）是通过0.05-0.3微米增加。 上述Ni-Zn合金层具有6-30重量％的Zn含量和0:08毫克/分米2以上的Zn附着量。

    ORGANIC ELECTROLUMINESCENT ELEMENT
    6.
    发明公开
    ORGANIC ELECTROLUMINESCENT ELEMENT 有权
    有机电致发光元件

    公开(公告)号：EP2492987A1

    公开(公告)日：2012-08-29

    申请号：EP10824912.9

    申请日：2010-10-19

    申请人： Nippon Steel Chemical Co., Ltd. ,  Pioneer Solutions Corporation ,  Tohoku Pioneer Corporation

    发明人： KAI Takahiro ,  YAMAMOTO Toshihiro ,  KOMORI Masaki ,  YOSHIMURA Kazuaki ,  TSUJI Taishi ,  TAKAHASHI Yasuhiro ,  YUKI Toshinao ,  NAKAJIMA Yusuke

    IPC分类号： H01L51/50 ,  C07D487/04

    CPC分类号： C07D487/04 ,  H01L51/0072 ,  H01L51/5096

    摘要： Disclosed is an organic electroluminescent device (organic EL device) which is improved in luminous efficiency, fully secure of driving stability, and of a simple configuration. The organic EL device comprises organic layers comprising a hole-transporting layer and a light-emitting layer sandwiched between an anode and a cathode. The light-emitting layer contains a fluorescent light-emitting material and an electron- and/or exciton-blocking layer containing an indolocarbazole derivative represented by general formula (2) is disposed between the hole-transporting layer and the light-emitting layer so as to be adjacent to the light-emitting layer. In general formula (2), ring B is a heterocyclic ring fused to the adjacent rings and represented by formula (1c), Z is an n-valent aromatic hydrocarbon group or aromatic heterocyclic group, and n is 1 or 2.

    摘要翻译： 本发明公开了一种发光效率提高，驱动稳定性充分可靠且结构简单的有机电致发光器件（有机EL器件）。 有机EL器件包括包含夹在阳极和阴极之间的空穴传输层和发光层的有机层。 发光层含有荧光发光材料，含有由通式（2）表示的吲哚并咔唑衍生物的电子和/或激子阻挡层设置在空穴传输层和发光层之间，以便 与发光层相邻。 在通式（2）中，环B是与相邻环稠合的由式（1c）表示的杂环，Z是n价芳族烃基或芳族杂环基，并且n是1或2。

    ORGANIC ELECTROLUMINESCENT ELEMENT
    10.
    发明公开
    ORGANIC ELECTROLUMINESCENT ELEMENT 有权
    有机电致发光元件

    公开(公告)号：EP2388842A1

    公开(公告)日：2011-11-23

    申请号：EP10731290.2

    申请日：2010-01-15

    申请人： Nippon Steel Chemical Co., Ltd.

    发明人： SUDA Mitsuru ,  KAI Takahiro ,  YAMAMOTO Toshihiro

    IPC分类号： H01L51/50 ,  C09K11/06 ,  C07D209/86

    CPC分类号： C07D209/86 ,  C07D213/74 ,  C07D239/48 ,  C07D403/10 ,  C07D403/14 ,  C07D471/14 ,  H01L51/0072 ,  H01L51/5016 ,  H01L51/5048 ,  H01L51/5096 ,  Y10S428/917

    摘要： Disclosed is a useful organic EL device which comprises a phosphorescent light-emitting layer and is endowed with improved luminous efficiency and high driving stability. Also disclosed is a hole-transporting material suitable for use in the phosphorescent light-emitting device. The hole-transporting material is a triptycene derivative which has substituents at the 9- and 10-positions and is substituted with an aromatic group containing at least one diarylamino group (-ArNAr 2 ). The organic EL device contains the triptycene derivative in at least one organic layer selected from the group of a phosphorescent light-emitting layer, a hole-transporting layer, an electron-blocking layer, and an exciton-blocking layer. The diarylamino group (-NAr 2 ) may be fused to form an aromatic heterocyclic group such as a carbazolyl group.

    摘要翻译： 公开了一种有用的有机EL器件，其包含磷光发光层并且具有改进的发光效率和高的驱动稳定性。 还公开了适用于磷光发光器件的空穴传输材料。 空穴传输材料是在9位和10位具有取代基并被含有至少一个二芳基氨基（-ArNAr 2）的芳基取代的三蝶烯衍生物。 有机EL器件在选自磷光发光层，空穴输送层，电子阻挡层和激子阻挡层中的至少一个有机层中含有三蝶烯衍生物。 二芳基氨基（-NAr 2）可以稠合形成芳族杂环基如咔唑基。