A METHOXYL ACRYLIC ESTER FUNGICIDE, THE PREPARATION METHOD AND USES THEREOF
    6.
    发明公开
    A METHOXYL ACRYLIC ESTER FUNGICIDE, THE PREPARATION METHOD AND USES THEREOF 审中-公开
    甲氧基丙烯酸酯 - 灭菌剂,VERFAHREN ZU SEINER HERSTELLUNG UND ANWENDUNGEN DAVON

    公开(公告)号:EP2301925A1

    公开(公告)日:2011-03-30

    申请号:EP09741682.0

    申请日:2009-04-16

    IPC分类号: C07D277/72 A01N43/78 A01P3/00

    摘要: A methoxyl acrylic ester fungicide, the preparation method and uses thereof. The fungicide contains at less the following compound of formula (I) as active ingredient.

    The fungicide can be further prepared to form the emulsifier oil by mixing with the emulsifier, latent solvent, stabilizer, and solvent. The fungicide is useful for preventing and controlling powdery mildew, downy mildew, gray mold and tan discase of vegetable, melon and fruit, discase of vegetable, melon and fruit cased by Phoma citricarpa, leaf spot of maize, false smut, blossom-end rot of orange and Sclerotinia rot of colza et al. The fungicide has many advantages such as be effect to the strain which produced the resistance, high effect, less toxic and environmrnt-friendly.

    摘要翻译: 甲氧基丙烯酸酯杀真菌剂及其制备方法及用途。 杀真菌剂含有较少的下列式(I)化合物作为活性成分。 可以通过与乳化剂,潜在溶剂,稳定剂和溶剂混合来进一步制备杀真菌剂以形成乳化油。 该杀菌剂可用于预防和控制植物,瓜类和水果的白粉病,霜霉病,灰霉病和褐斑病,植物,瓜子和果实由Phoma lemonarpa,玉米叶斑病,假丝酵母​​,开花腐烂 的柯萨等人的橙色和核盘菌病 杀菌剂具有许多优点,例如对产生抗性,效果高,毒性低,环境友好的菌株。

    BIPHENYL DERIVATIVES AND THEIR USE AS FUNGICIDES
    7.
    发明授权
    BIPHENYL DERIVATIVES AND THEIR USE AS FUNGICIDES 有权
    BENHENYLDERIVATE UND DEREN VERWENDUNG ALS FUNGIZIDE

    公开(公告)号:EP1575922B1

    公开(公告)日:2008-05-14

    申请号:EP03813891.3

    申请日:2003-12-15

    摘要: A fungicidally active compound of formula (I): where Het is a substituted 5- or 6-membered heterocyclic ring; R1 is hydrogen, formyl, CO-C1-4 alkyl, COO-C1-4 alkyl, C1-4 alkoxy(C1-4)alkylene, CO-C1-4 alkylenoxy(C1-4)alkyl, propargyl or allenyl; R2, R3, R4 and R5 are each, independently, hydrogen, halogen, methyl or CF3; each R6 is, independently, halogen, methyl or CF3; R7 is (Z)mC=C(Y1), (Z)mC(Y1)=C(Y2)(Y3) or tri(C1-4)alkylsilyl; X is O or S; Y1, Y2 and Y3 are each, independently, hydrogen, halogen, C1-6 alkyl [optionally substituted by one or more substituents each independently selected from halogen, hydroxy, C1-4 alkoxy, C1-4 haloalkoxy, C1-4 alkylthio, C1-4 haloalkylthio, C1-4 alkylamino, di(C1-4)alkylamino, C1-4 alkoxycarbonyl, C1-4 alkylcarbonyloxy and tri(C1-4)alkylsilyl], C2-4 alkenyl [optionally substituted by one or more substituents each independently selected from halogen], C2-4 alkynyl [optionally substituted by one or more substituents each independently selected from halogen], C3-7 cycloalkyl [optionally substituted by one or more substituents each independently selected from halogen, C1-4 alkyl and C1-4 haloalkyl] or tri(C1­4)alkylsilyl; Z is C1-4 alkylene [optionally substituted by one or more substituents each independently selected from hydroxy, cyano, C1-4 alkoxy, halogen, C1-4 haloalkyl, C1-4 haloalkoxy, C1-4 alkylthio, COOH and COO-C1-4 alkyl]; m is 0 or 1; and n is 0, 1 or 2; the invention also relates to novel intermediates used in the preparation of these compounds, to agrochemical compositions which comprise at least one of the novel compounds as active ingredient and to the use of the active ingredients or compositions in agriculture or horticulture for controlling or preventing infestation of plants by phytopathogenic microorganisms, preferably fungi.

    摘要翻译: 杀真菌活性的式(1)化合物:其中Het是取代的5或6元杂环; R 1是氢,甲酰基,CO-C 1-4烷基,COO-C 1-4烷基,C 1〜 4个C 1-4烷氧基(C 1-4-4)亚烷基,CO-C 1-4亚烷基氧基(C 1-4-4烷基)烷基, 炔丙基或二烯丙基; R 2,R 3,R 4和R 5各自独立地为氢,卤素,甲基或 CF 3 ; 每个R 6独立地是卤素,甲基或CF 3; (Z)C(Y 1),(Z)m C(Y [任选被一个或多个各自独立地选自卤素的取代基取代的]烯基,任选被一个或多个各自独立地选自卤素的取代基取代的C 2-4 - 炔基,C 1-3 - 7个环烷基[任意被一个或多个取代基取代,各自独立地选自卤素,C 1-4烷基和C 1-4卤代烷基]或三(C 1-4 )烷基甲硅烷基; Z是任选被一个或多个各自独立地选自羟基,氰基,C 1-4烷氧基,卤素,C 1 -C 4烷基的取代基取代的C 1-4亚烷基 -4个卤代烷基,C 1-4卤代烷氧基,C 1-4烷基硫基,COOH和COO-C 1-4烷基 ]。 m为0或1; 并且n为0,1或2; 本发明还涉及用于制备这些化合物的新型中间体,包含至少一种新化合物作为活性成分的农用化学组合物以及农业或园艺中的活性成分或组合物用于控制或预防 植物通过植物病原微生物,优选真菌。

    PYRAZOL-4-YL-BENZOYLDERIVATE UND IHRE VERWENDUNG ALS HERBIZIDE
    8.
    发明授权
    PYRAZOL-4-YL-BENZOYLDERIVATE UND IHRE VERWENDUNG ALS HERBIZIDE 失效
    吡唑-4-基苯甲酰及其作为除草剂

    公开(公告)号:EP0811007B1

    公开(公告)日:2005-11-23

    申请号:EP96902274.8

    申请日:1996-02-14

    摘要: Pyrazol-4-yl-benzoyl derivatives have the formula (I), in which the substituents have the following meanings: L, M are hydrogen, C1-C6 alkyl, C2-C6 alkenyl, C2-C6 alkinyl, C1-C4 alkoxy, these groups being optionally substituted by 1 to 5 halogen atoms or C1-C4 alkoxy, halogen, cyano, nitro, a group -(Y)n-S(O)mR7 or a group -(Y)¿n-CO-R?8; Z is a 5 or 6-membered saturated or unsaturated heterocyclic rest, that contains 1 to 3 heteroatoms selected from the group that includes oxygen, sulphur or nitrogen, optionally substituted by halogen, cyano, nitro, a group -CO-R8, C1-C4 alkyl, C1-C4 halogen alkyl, C3-C8 cycloalkyl, C1-C4 alkoxy, C1-C4 halogen alkoxy, C1-C4 alkylthio, C1-C4 halogen alkylthio, di-C1-C4-alkylamino, a phenyl optionally substituted by halogen, cyano, nitro C1-C4 alkyl or C1-C4 halogen alkyl or a twice bound oxygen that optionally in the tautomer form may also be a hydroxy group, or that forms a bicyclic system together with a condensed phenyl ring optionally substituted by halogen, cyano, nitro, C1-C4 alkyl or C1-C4 halogen alkyl, with a condensed carbon cycle or with a second condensed heterocycle optionally substituted by halogen, cyano, nitro, C1-C4 alkyl, di-C1-C4-alkylamino, C1-C4 alkoxy, C1-C4 halogen alkoxy or C1-C4 halogen alkyl; Y is O, NR9; n equals 0 or 1; m equals 0, 1 or 2; R7 is C1-C4 alkyl, C1-C4 halogen alkyl or NR?9R10; R8 is C¿1-C4 alkyl, C1-C4 halogen alkyl, C1-C4 alkoxy or NR?9R10; R9¿ is hydrogen or C¿1?-C4 alkyl; R?10 is C¿1-C4 alkyl; Q is a pyrazol ring linked at position 4 having the formula (II) in which R1 is C1-C4 alkyl; R2 is hydrogen or C¿1?-C4 alkyl; and R?3¿ is hydrogen, C¿1?-C4 alkyl sulphonyl, phenyl sulphonyl or alkyl phenyl sulphonyl. Also disclosed are the salts of compounds (I) usually utilized in agriculture.