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13 条记录 (耗时 0.019 秒)

    CATALYTIC HYDROGENATION OF FLUOROOLEFINS WITH SUPPORTED PALLADIUM CATALYSTS
    8.
    发明公开
    CATALYTIC HYDROGENATION OF FLUOROOLEFINS WITH SUPPORTED PALLADIUM CATALYSTS 审中-实审

    公开(公告)号：EP4368605A1

    公开(公告)日：2024-05-15

    申请号：EP24164395.6

    申请日：2012-05-16

    申请人： The Chemours Company FC, LLC

    发明人： Cheung, Patricia ,  Sievert, Allen Capron ,  Lamarca, Concetta

    IPC分类号： C07C17/354 ,  C07C19/08 ,  B01J8/02 ,  B01J21/04 ,  B01J23/44 ,  B01J35/61

    CPC分类号： B01J21/04 ,  B01J23/44 ,  C07C17/354 ,  B01J35/612

    摘要： A hydrogenation process is disclosed. The process involves reacting a fluoroolefin with H2 in a reaction zone in the presence of a palladium catalyst to produce a hydrofluoroalkane product, wherein the palladium catalyst comprises palladium supported on a carrier wherein the palladium concentration is from about 0.001 wt % to about 0.2 wt % based on the total weight of the palladium and the carrier. Also disclosed is a palladium catalyst composition consisting essentially of palladium supported on α-Al2O3 wherein the palladium concentration is from about 0.001 wt % to about 0.2 wt % based on the total weight of the palladium and the α-Al2O3. Also disclosed is a hydrogenation process comprising reacting a fluoroolefin with H2 in a reaction zone in the presence of a palladium catalyst to produce a hydrofluoroalkane product, characterized by: the palladium catalyst consisting essentially of palladium supported on α-Al2O3 wherein the palladium concentration is from about 0.001 wt % to about 0.2 wt % based on the total weight of the palladium and the α-Al2O3. Also disclosed is a hydrogenation process comprising (a) passing a mixture comprising fluoroolefin and H2 through a bed of palladium catalyst in a reaction zone wherein the palladium catalyst comprises palladium supported on a carrier; and (b) producing a hydrofluoroalkane product; characterized by: the palladium catalyst in the front of the bed having lower palladium concentration than the palladium catalyst in the back of the bed.