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    Process for the separation of hydrogen from a mixture of gases
    3.
    发明公开
    Process for the separation of hydrogen from a mixture of gases 失效
    Verfahren zum Abtrennen von Wasserstoff aus einer Gasmischung。

    公开(公告)号：EP0094136A1

    公开(公告)日：1983-11-16

    申请号：EP83200660.5

    申请日：1983-05-06

    申请人： STAMICARBON B.V.

    发明人： Beenackers, Antoni A. C. M. ,  van Swaaij, Willibrordus P. M.

    IPC分类号： B01D53/06 ,  C01B3/56 ,  B01J20/02

    CPC分类号： C01B3/0063 ,  B01J8/20 ,  C01B3/0031 ,  C01B3/0068 ,  C01B3/0073 ,  C01B3/56 ,  C01B2203/043 ,  Y02E60/327

    摘要： A process for separating hydrogen gas from a stream of a mixture of gases containing the hydrogen gas includes contacting a suspension of hydride-forming material particles in a fluid medium with the stream to permit the particles to form a hydride. The hydrided particles can then be thermally decomposed to liberate hydrogen and to regenerate the hydride-forming capabilities of the particles. By preference, the fluidized bed is a slurry mixture of the hydride-forming material particles in an auxiliary liquid such as, for example, a heat resistant oil.
    The amount of hydride-forming particles in the slurry mixture is preferably between about 10% to about 70% by weight.

    摘要翻译： 从含有氢气的气体混合物流中分离氢气的方法包括将流体介质中的氢化物形成材料颗粒的悬浮液与流接触以允许颗粒形成氢化物。 氢化颗粒然后可以被热分解以释放氢气并再生形成颗粒的氢化物形成能力。 优选地，流化床是氢化物形成材料颗粒在辅助液体中的浆料混合物，例如耐热油。 浆料混合物中氢化物形成颗粒的量优选为约10重量％至约70重量％。

    CATALYST AND PROCESS FOR THE PREPARATION OF HYDROGEN GAS FROM FORMATE AND HYDROGENATION OF HYDROGEN CARBONATE, AND HYDROGEN STORAGE SYSTEM USING THEM
    5.
    发明公开
    CATALYST AND PROCESS FOR THE PREPARATION OF HYDROGEN GAS FROM FORMATE AND HYDROGENATION OF HYDROGEN CARBONATE, AND HYDROGEN STORAGE SYSTEM USING THEM 审中-公开
    催化剂和方法生产氢气气体的格式和碳酸氢盐的氢化和氢存储系统

    公开(公告)号：EP3046667A2

    公开(公告)日：2016-07-27

    申请号：EP14845965.4

    申请日：2014-09-17

    申请人： Debreceni Egyetem

    发明人： GYÖRVÁRINÉ HORVÁTH, Henrietta ,  PAPP, Gábor ,  JOÓ, Ferenc ,  KATHÓ, Ágnes

    IPC分类号： B01J23/46 ,  B01J27/185 ,  B01J27/24 ,  B01J31/18 ,  C01B3/26 ,  C01B3/04 ,  F17C11/00 ,  B01J19/14

    CPC分类号： B01J31/2457 ,  B01J31/2273 ,  B01J31/2295 ,  B01J31/2404 ,  B01J31/2409 ,  B01J31/2485 ,  B01J37/04 ,  B01J2231/62 ,  B01J2231/70 ,  B01J2231/763 ,  B01J2531/827 ,  B01J2531/96 ,  B01J2540/32 ,  C01B3/0073 ,  C01B3/042 ,  C01B3/326 ,  C01B2203/1047 ,  H01M8/04089 ,  H01M8/0618 ,  Y02E60/321 ,  Y02E60/324 ,  Y02E60/364 ,  Y02P20/52

    摘要： The invention relates to a catalyst according to the formula lrCI(cod)(NHC)] + nP (n = 2, 3 or 4), or [lr(cod)(NHC)(P)] + nP (n = 1, 2 or 3), which is suitable to decompose formates in an aqueous reaction system, and for the production of hydrogen gas or hydrogenation of carbonates, wherein Ir means irydium; CI means chlorine; cod means 1,5-cyclooctadiene; NHC means N-heterocyclic carbene, preferably 1-R-3-methylimidasolium chloride, wherein R means C 1-5 alkyl es P means 1,3,5-triaza-7-phosphaadamantane (pta), monosulphonated triphenilphosphine (
    m tppms), trisulphonated triphenylphosphine (
    m tppts), or four times sulphonated diphenylphosphynopropane (dpppts). Furthermore, the invention relates to a process for the preparation of the catalyst accoring to the invention. Further, the invention relates to a process for the decomposition of formate in aqueous reaction system, and for the production of hydrogen gas free of CO
    x , still further, a process for the hydrogenation of hydrogen carbonate in an aqueous reaction system, as well as the production of the respective formate. Further, the invention relates to a process for the decomposition of formate accoring to the invention, and the hydrogenation of the carbonate generated in the same reaction system. The invention relates to a hydrogen storage system based on the process according to the invention, preferably battery or fuel cell, and the use thereof.

    摘要翻译： 本发明涉及催化剂雅丁式的IrCl（COD）（NHC）] + NP（N = 2，3或4），或物[Ir（COD）（NHC）（P）] + NP（n = 1时， 2或3）的所有其适合于分解甲酸盐在反应wässrige系统，以及用于生产无CO x或碳酸氢盐，worin铱手段铱的氢化的氢气; 氯是指氯; 意味着鳕鱼1.5环辛二烯; NHC手段N-杂环卡宾，优选为1-R-3- methylimidasolium酰氯，worin R表示C1-C5烷基和P表示1,3,5-三氮杂-7-磷（PTA），monosulphonated triphenilphosphine（mtppms）trisulphonated三苯基膦 （mtppts），或四磺酸基diphenylphosphynopropane（dpppts）。 进一步，本发明涉及用于制备催化剂的gemäß到本发明的方法。 此外，本发明涉及一种用于格式分解成wässrige反应体系中，和用于生产氢气的游离CO x的，更进一步，为碳酸氢在wässrige反应体系中加氢的方法，以及在 生产respectivement格式。 此外，本发明涉及一种用于格式分解雅丁到本发明，并且在同一反应体系中生成的碳酸氢盐的氢化的方法。本发明涉及一种基于过程雅丁本发明的氢存储系统，优选 蓄电池或燃料电池，和其用途。