摘要:
L'invention a pour objet un procédé de préparation de fluorures doubles d'uranium et d'ammonium ou d'un métal alcalin ou alcalino-terreux. Le procédé selon l'invention se caractérise en ce qu'il comporte les étapes suivantes : - la réduction catalytique par l'hydrogène, en présence d'ions H⁺, d'une solution d'un sel d'uranium (VI) soluble en une solution d'un sel d'uranium (IV) soluble, - la réaction du sel d'uranium (IV) obtenu à l'étape précédente avec des ions fluorures, en présence d'ions ammonium, alcalin ou alcalino-terreux, pour obtenir la précipitation du fluorure double d'uranium et d'ammonium ou d'un métal alcalin ou alcalino-terreux, - la récupération du fluorure double sous forme de précipité.
摘要:
This invention relates to material compositions, a manufacturing method for these materials and a manufacturing method for ceramic bodies, to be used as targets in physical vapour deposition techniques of p-type transparent conductive films. There is disclosed a method for manufacturing a pelletized oxide material Mx Sr1−xCu2-+aO2+b, wherein −0.2≦̸a≦̸0.2, −0.2≦̸b≦̸0.2, and M is either one or more of the group of bivalent elements consisting of Ba, Ra, Mg, Be, Mn, Zn, Pb, Fe, Cu, Co, Ni, Sn, Pd, Cd, Hg, Ca, Ti, V, Cr; with 0≦̸x≦̸0.2; comprising the steps of: —providing a precursor mixture having a given grain size distribution, and comprising stoichiometric quantities of Cu2O, Sr(OH)2.8H2O, and, when 0≦̸x≦̸0.2, M-hydroxide, —intimately mixing said precursor mixture so as to obtain a homogeneous mixture, and —sintering said homogeneous mixture at a temperature above 850° C. The oxide material Sr Cu2+aO2+b has a residual carbon content of less than 400 ppm, and a target having a density of at least 5.30 g/ml can be manufactured with it.
摘要:
For the recovery of uranium from a solution in which the uranium has a valency (VI), a solution is formed containing ammonium (NH 4 + ), fluoride (F―) and sodium hydrosulfite (Na 2 S 2 0 4 ). This forms a precipitate (NaNH 4 UF 6 ), a previously unreported compound. It can be dissolved in an aqueous solution of aluminum nitrate nonahydrate, Al(NO 3 ) 3 . 9H 2 0. This produces uranyl nitrate hexahydrate, which can be extracted in solutions conventionally used for that purpose.
摘要:
A pyroelectric ceramic having the composition:- where ⌀ is U (uranium) or Mn (manganese) and in which a is a number substantially within the range 0.01 to 0.10; x is a number substantially within the range 0.10 to 0.25; y is a number substantially within the range 0 to 0.4; z is a number substantially within the range 0 to 0.05 and 8 is a number substantially within the range 0 to 0.06. Methods of fabricating the pyroelectric ceramic are also described.
摘要:
A pyroelectric ceramic having the composition:- where ⌀ is U (uranium) or Mn (manganese) and in which a is a number substantially within the range 0.01 to 0.10; x is a number substantially within the range 0.10 to 0.25; y is a number substantially within the range 0 to 0.4; z is a number substantially within the range 0 to 0.05 and 8 is a number substantially within the range 0 to 0.06. Methods of fabricating the pyroelectric ceramic are also described.
摘要:
For the recovery of uranium from a solution in which the uranium has a valency (VI), a solution is formed containing ammonium (NH 4 + ), fluoride (F―) and sodium hydrosulfite (Na 2 S 2 0 4 ). This forms a precipitate (NaNH 4 UF 6 ), a previously unreported compound. It can be dissolved in an aqueous solution of aluminum nitrate nonahydrate, Al(NO 3 ) 3 . 9H 2 0. This produces uranyl nitrate hexahydrate, which can be extracted in solutions conventionally used for that purpose.
摘要翻译:为了从其中铀(VI)的溶液中回收铀,形成含有铵(NH 4 +),氟化物(F - )和亚硫酸氢钠(Na 2 S 2 O 4))的溶液。 这形成了以前未报告的化合物的沉淀物(NaNH4UF6)。 它可以溶解在硝酸铝九水合物Al(NO 3)3·4H 2 O的水溶液中。 这产生硝酸铀六水合物,其可在常规用于该目的的溶液中萃取。