Process for the oligomerization of olefins
    3.
    发明公开
    Process for the oligomerization of olefins 失效
    烯烃低聚过程

    公开(公告)号:EP0254956A3

    公开(公告)日:1988-08-03

    申请号:EP87110203

    申请日:1987-07-15

    IPC分类号: C07C02/20 B01J27/06

    摘要: Es wird ein Verfahren zur Oligomerisierung von Olefinen beschrieben. Um Umweltverschmutzungs- und Korrosionsprobleme zu vermeiden, wird vorgeschlagen, daß die Oligomerisierung in der Gasphase an einem festen Katalysator, der supersaure Fluorverbindungen der Elemente der III., IV. und/oder V. Hauptgruppe des Periodensystems enthält, durchgeführt wird. Das Verfahren kann beispielsweise zur Erhöhung der Olefinausbeute in Steamcrackern oder zur Gewinnung von Kraftstoffkomponenten aus FCC-Abgasen eingesetzt werden.

    Method of oxidative conversion of organic compounds.
    4.
    发明公开
    Method of oxidative conversion of organic compounds. 失效
    一种用于有机化合物的氧化转化法。

    公开(公告)号:EP0206044A1

    公开(公告)日:1986-12-30

    申请号:EP86107685

    申请日:1986-06-05

    摘要: A solid composition of matter selected from the group consisting of:

    (a) a component comprising: (1) an oxide of lanthanum and a component comprising: (2) at least one material selected from the group consisting of halogen ions, compounds containing halogen ions, tin and compounds containing tin; and
    (b) a component comprising: (1) at least one material selected from the group consisting of Group IA metals and compounds containing said metals, a component comprising: (2) at least one metal selected from the group consisting of lanthanum and compounds containing lanthanum and, optionally, a component comprising: (3) at least one material selected from the group consisting of halogen ions, compounds containing halogen ions, tin and compounds containing tin,

    and a method for the oxidative conversion of organic compounds to other organic compounds, particularly in the presence of a free oxygen containing gas. When the method is carried out in the presence of a free oxygen containing gas, a contact material including a Group IA metal, tin and, optionally, chloride ions has also been found to be effective.

    A stable and selective dehydrogenation catalyst and a process for the preparation thereof
    7.
    发明公开
    A stable and selective dehydrogenation catalyst and a process for the preparation thereof 审中-公开
    稳定的和选择性的脱氢催化剂和其制备方法

    公开(公告)号:EP1147810A1

    公开(公告)日:2001-10-24

    申请号:EP01303575.3

    申请日:2001-04-19

    IPC分类号: B01J27/13 B01J23/89 C07C5/333

    摘要: A novel catalyst for use in dehydrogenation of saturated hydrocarbons to unsaturated hydrocarbons and a method for its preparation is disclosed. Said catalyst comprises a composite incorporated within its spatial geometry on a percentage by weight basis, with a uniform concentration gradient, the following active elements:

    from 0.1 to 5.0% of a noble metal;
    from 0.1 to 5.0 % of a metal of Group IV A;
    from 0.1 to 6.0 % of a metal Group III A;
    from 0.1 to 10.0 % of an alkali or alkaline earth metal element;
    from 0.01 to 10.0 % of a halogen; and
    from 0.1 to 5.0 % of a metal Group VIII selected from Fe, Co and Ni provided on a high surface area meso or macroporous support. The the high surface mesoporous support comprises a spheroidal gamma alumina support with a diameter of 1.4 to 2.0 mm, a surface area in the range of from 150 to 220 m2/g, with bimodal narrow pore size distribution, water adsorption capacity in the range of from 1.4 to 2.5 ml/g, gamma crystallinity in the range of 60 to 80 % and a bulk density in the range of 0.25 to 0.4 g/ml.

    摘要翻译: 在饱和烃的脱氢使用为不饱和烃的新型催化剂及其制备方法是游离缺失盘。 所说的催化剂包括一个其空间几​​何形状内并入由按重量计的百分比复合材料,以均匀的浓度梯度,以下有源元件:从0.1到贵金属的5.0%; 从0.1至IV族A的金属的5.0%; 从0.1到金属III族A的6.0%; 从0.1到碱金属或碱土金属元素的10.0%; 从12:01到卤素的10.0%; 和从选自Fe的金属VIII族的0.1%至5.0%,Co和Ni设置在高表面积的内消旋或大孔载体。 所述高表面中孔载体包括球形γ-氧化铝载体,直径为1.4至2.0毫米,在从150至220米2 /克的范围内的表面积,具有双峰孔径分布窄,水吸附容量在范围内 从1.4至2.5毫升/克,在60至80%的范围内的γ结晶度和在0:25至0.4g / ml范围内的堆积密度。