摘要:
The invention relates to a process for the selective oxidation of carbon monoxide to carbon dioxide present in a gas mixture comprising at least one hydrocarbon or a hydrocarbon derivative, and to its integration into a process for producing hydrocarbon derivatives. The process according to the invention comprises a step that consists in bringing said gas mixture into contact with a solid catalyst capable of oxidizing carbon monoxide to carbon dioxide at a chosen temperature, characterized in that said step is carried out in a fluidized bed.
摘要:
Stage 1 Group 1 metal/porous metal oxide compositions or Stage II Group 1 metal/porous metal oxide compositions are shown to be useful to remove impurities and act as drying agents for various types of solvents and for olefinic monomers used in anionic polymerizations. One important advantage of these compositions is their ability to dry simultaneously solvent and monomers, without inducing a significant polymerization of the latter. Another important characteristic is the capacity of the compositions to be totally inactive toward conventional anionic polymerization which allows them to be left in situ during the polymerization itself.
摘要:
A process for purifying an olefin feed comprising a content of phosphorus-containing impurities, said process comprising contacting said olefin feed with a sorbent comprising a metal under conditions and for a time effective to reduce said content of phosphorus-containing impurities and to produce a purified olefin feed.
摘要:
The recycled olefins are passed over a material comprising nickel deposited on a support, the nickel being present as metallic nickel and nickel oxide. Catalyst yields are improved and a better control of the polymer properties is obtained.
摘要:
The present invention relates to a method for regenerating a system for removing impurities from a feed fluid, the feed fluid comprising primarily a hydrocarbon and the method comprising: contacting an oxidized copper-based material and an adsorbent in a single vessel with an inert gas heated to a first temperature above an ambient temperature for removing hydrocarbon adsorbed thereon; adding a reducing agent to the heated inert gas for reducing the copper-based material; increasing a concentration of reducing agent added in the heated inert gas contacting the copper-based material and the adsorbent; heating the inert gas and the reducing agent to a second temperature higher than the first temperature; and contacting the copper-based material and the adsorbent with the inert gas and the reducing agent at the second temperature.
摘要:
The invention provides a method for purification of an α-olefin selected from ethylene and propylene for polymerization use which comprises contacting the α-olefin with an alkali metal carried on a support material. The invention further provides a method for production of a poly-α-olefin which comprises polymerizing the thus purified α-olefin in the presence of a polymerization catalyst comprising a transition metal catalyst component and an organometallic catalyst component.
摘要:
Desulphurisation of natural gas is effected using a bed of a particulate adsorbent comprising zinc oxide at below 30°C before molecular sieve drying of the gas. The absorbent particles preferably have a high BET surface area and pore volume.
摘要:
A two catalyst system is described having separate catalyst beds for the selective conversion of acetylene to ethylene which reduces the concentration of acetylene, dienes, O2, and NOx is disclosed. An ethylene containing gas stream, such as an off-gas stream from a refinery catalytic cracking unit used in the production of fuels and gas oils, is treated by first contacting the gas stream with a silver catalyst supported on a metal oxide and subsequently contacting the gas stream with a ruthenium catalyst supported on metal oxide. The two catalysts are contained within contiguous continuous reactors or reactor compartments