THE SURFACE OF TREATMENT OF NANOPARTICLES TO CONTROL INTERFACIAL PROPERTIES AND METHOD OF MANUFACTURE
    1.
    发明公开
    THE SURFACE OF TREATMENT OF NANOPARTICLES TO CONTROL INTERFACIAL PROPERTIES AND METHOD OF MANUFACTURE 有权
    纳米颗粒用于控制表面特性和方法表面处理

    公开(公告)号:EP1735823A4

    公开(公告)日:2009-06-17

    申请号:EP05760444

    申请日:2005-03-30

    摘要: A surface treated particle comprising a plurality of inorganic, metallic, semi-metallic, and/or metallic oxide particles and a star-graft copolymer with looped and/or linear polymeric structure on a star-graft copolymer, obtainable by a heterogeneous polymerization reaction in the particle surface proximity, encapsulating at least a portion of said particles and a method for making the same. The surface treatment comprises: Si (w, x, y, z), where: w, x, y, and z are mole percent tetrafunctional, trifunctional, difunctional, and monofunctional monomeric units, respectively; w, x, y, and z are about 0-50, 0-50, 5 - 99, and 0-5, respectively; w is tetraethylorthosilicate; x is selected from the group consisting of Ϝ-glycidoxypropyltrimethoxysilane, Ϝ-methacryloxypropyltrimethoxysilane, methyltrimethoxysilane, n-propyltrimethoxysilane, isobutyltrimethoxysilane, n-hexyltrimethoxysilane, n-octyltrimethoxysilane, n-octadecyltrimethoxysilane, phenyltrimethoxysilane, 3-(trimethoxysilyl)propylsuccinic anhydride, heptadecafluorotrimethoxysilane, 3-isocyanatopropyltrimethoxysilane, 2-(diphenylphosphino)ethyltrimethoxysilane, 3-aminopropyltrimethoxysilane, 3-mercaptopropyltrimethoxysilane, n-(trimethoxysilylpropyl)EDTA, pentafluorophenylpropyltrimethoxysilane, trifluoropropyltrimethoxysilane, and the triethoxy-containing counterparts of these monomers; y is selected from the group consisting of dicyclohexyldimethoxysilane, diethyldiethoxysilane, dimethyldichlorosilane, dimethyldiethoxysilane, dimethyldimethoxysilane, diphenyldiethoxysilane, diphenyldimethoxysilane, di-n-hexyldichlorosilane, n-hexylmethyldichlorosilane, methyldodecyldiethoxysilane, n-octylmethyldimethoxysilane, and the diethoxy-containing counterparts of these monomers; and z is selected form the group consisting of n-octadecyldimethylmethoxysilane, triethylsilanol, trimethylethoxysilane, trimethylmethoxysilane, and the ethoxy-containing counterparts of these monomers. Product(s) per se, defined as surface treated ZnO and/or TiO2, and the use of the product(s) per se in personal care formulations are excluded.

    FUNCTIONALIZED FLUORESCENT NANOCRYSTALS, AND METHODS FOR THEIR PREPARATION AND USE
    6.
    发明授权
    FUNCTIONALIZED FLUORESCENT NANOCRYSTALS, AND METHODS FOR THEIR PREPARATION AND USE 有权
    对于使用功能化的荧光纳米晶和方法以及

    公开(公告)号:EP1809720B1

    公开(公告)日:2012-05-02

    申请号:EP05858281.8

    申请日:2005-10-28

    发明人: NAASANI, Imad

    IPC分类号: C09K11/54 G01N33/58

    摘要: Functionalized fluorescent nanocrystal compositions and methods for making and using these compositions are disclosed. The compositions are fluorescent nanocrystals coated with at least one material. The coating material has chemical compounds or ligands with functional groups or moieties with conjugated electrons and moieties for imparting solubility to coated fluorescent nanocrystals in aqueous solutions. The coating material provides for functionalized fluorescent nanocrystal compositions which are water soluble, chemically stable, and emit light with a high quantum yield and/or luminescence efficiency when excited with light. The coating material may also have chemical compounds or ligands with moieties for bonding to target molecules and cells as well as moieties for cross-linking the coating. In the presence of reagents suitable for reacting to form capping layers, the compounds in the coating may form a capping layer on the fluorescent nanocrystal with the coating compounds operably bonded to the capping layer.

    Nanocristaux inorganiques à couche de revêtement organique, leur procédé de préparation
    8.
    发明公开
    Nanocristaux inorganiques à couche de revêtement organique, leur procédé de préparation 有权
    Anorganische Nanokristalle mit einer organischen Beschichtung und deren Vorbereitungsverfahren

    公开(公告)号:EP1548431A1

    公开(公告)日:2005-06-29

    申请号:EP04106173.0

    申请日:2004-11-30

    IPC分类号: G01N33/00 C30B7/00

    摘要: Nanocristal comprenant un coeur inorganique constitué par au moins un métal et/ou au moins un composé semi-conducteur comprenant au moins un métal, la surface externe dudit nanocristal étant pourvue d'une couche de revêtement organique, constituée par au moins un composé ligand de formule (I) :

            X-Y-Z     (I)

       dans laquelle

    X représente un groupe 1,1-dithiolate ou 1,1-disélénoate qui est lié par les deux atomes de soufre ou de sélénium à un atome de métal de la surface externe dudit nanocristal ;
    Y représente un groupe espaceur, tel qu'un groupe susceptible de permettre un transfert de charge ou un groupe isolant ;
    Z est un groupe choisi parmi les groupes susceptibles de communiquer des propriétés spécifiques au nanocristal.

    Leurs procédés de fabrication.

    摘要翻译: 包含金属和/或半导体的纳米晶体用包含配体的有机材料涂覆。 纳米晶体包括由金属和/或金属半导体组成的无机芯,外表面涂覆有由下式的配体构成的有机材料:XYZ(I):其中X是1,1-二硫醇盐或 由S或Se的两个原子连接的1,1-硒酸酯基团与外表面的金属原子连接,Y为间隔基团,以允许电荷或隔离基团转移,Z为能够产生的基团 某些特定的纳米晶体性质。 还包括用于制备化合物的独立权利要求。