摘要:
A production method of an elastically stretchable artificial leather which includes a step of making microfiberizable fibers into a web; a step of entangling the obtained web to produce an entangled nonwoven fabric; a step of converting the microfiberizable fibers in the nonwoven fabric to microfine fibers, thereby producing a substrate for artificial leather; a step of producing an artificial leather by using the obtained substrate for artificial leather; and a step wherein the obtained artificial leather is brought into close contact with an elastomer sheet stretched in a machine direction by 5 to 40%; the artificial leather is allowed to shrink in the machine direction simultaneously with allowing the elastomer sheet to shrink in the machine direction by relaxing elongation of the elastomer sheet; the artificial leather is heat-treated in shrunk state; and then the artificial leather is peeled off from the elastomer sheet.
摘要:
The present invention relates to a process for the production of aqueous polyurethane-polyurea dispersions for which A) firstly A1) primary and/or secondary monoamines or diamines are reacted with A2) cyclic carbonates which contain precisely one hydroxy group, where the molar ratio of A1) and A2) is such that in the case of monoamines A1) the theoretical ratio of the entirety of the primary and secondary amine groups to the cyclic carbonate groups is from 0.8 to 1.2 and in the case of diamines A1) the theoretical ratio of the entirety of the primary and secondary amine groups to the cyclic carbonate groups is from 1.8 to 2.2, and A3) in the case of diamines A1) the remaining primary and secondary amine groups are reacted with compounds which bear precisely one functional group which reacts with primary or secondary amines in an addition reaction, in such a way that there are no resultant isocyanate-reactive groups, where the molar amount of A3) is such that the theoretical ratio of the entirety of the theoretically remaining primary and secondary amine groups after reaction of A1) and A2) to the amine-reactive groups in A3) is from 0.8 to 1.2, where the reaction with A3) can take place after, at the same time as or prior to the reaction with A2), B) then a polyurethane prepolymer containing NCO groups is produced by reaction of B1) polyisocyanates with B2) polymeric polyols and/or polyamines with number-average molar masses of more than 400 to 8000 g/mol and B3) optionally low-molecular-weight compounds with number-average molar masses of 17-400 g/mol selected from the group consisting of mono- and polyalcohols, mono- and polyamines and aminoalcohols and B4) optionally isocyanate-reactive, ionically or potentially ionically hydrophilizing compounds and/or isocyanate-reactive non-ionically hydrophilizing compounds and B5) the reaction products of A), C) the prepolymer from B) is dispersed in water, and D) optionally the remaining free NCO groups of the prepolymer are reacted with isocyanate-reactive monoamines, polyamines, hydrazine and/or hydrazides, where the molar amount of these is such that the theoretical ratio of the isocyanate-reactive NH groups to the NCO groups is from 0 to 1.2, where the reaction D) can take place to some extent or else entirely prior to or during the dispersion step C).
摘要:
Disclosed are an artificial leather that comprises two or more types of short fibers made of different components and thus exhibits superior texture, flexibility, breathability and fullness and enables great weight reduction, and a method for manufacturing the same. The artificial leather includes a non-woven fabric having a fineness of 0.001 to 0.5 denier, and a polymeric elastomer impregnated in the non-woven fabric, wherein the short fibers are two or more types of polyester short fibers having different numbers of repeat units of -CH 2 -.
摘要:
Floor covering, consisting of hard panels, with a laminated structure, whereby at least at the upper surface a printed decorative layer (16) with a wood pattern (5) is present, with thereupon a transparent layer of synthetic material (17) in which impressions (18A-18B-18C) are formed, characterized in that the impressions (18A-18B-18C) substantially follow the wood pattern (5).
摘要:
Disclosed is a leather-like sheet, comprising a microfiber interlaced body formed from a microfiber bundle and a polymeric elastic body provided in the inside of the interlaced body. The microfiber bundle comprises extremely fine unit fibers having an average cross section of 0.1 to 30 μm2, has an average cross section of 40 to 400 μm2, and is formed at a density of 600 to 4000 pieces/mm2 as measured on an arbitrary cross section parallel with the thickness-wise direction of the microfiber interlaced body. The polymeric elastic body contains a polymer of an ethylenically unsaturated monomer in an amount of 30 to 100% by mass, wherein the polymer of the ethylenically unsaturated monomer comprises a soft component having a glass transition temperature (Tg) of less than -5°C and a crosslinkable component and optionally a hard component having a glass-transient temperature (Tg) exceeding 50°C and other components. In the leather-like sheet, the polymer of the ethylenically unsaturated monomer is fixed to a microfiber present in the inside of the microfiber bundle. The leather-like sheet has a natural leather-like flexibility, a texture (e.g., solid touch feeling) and expensive aesthetic appearance and is excellent in stability of quality (e.g., rigidity, surface wear resistance) and practical performance.
摘要:
Floor covering consisting of hard panels (2) with a core (23) upon which is provided a decorative layer (25), wherein these panels (2) are rectangular and elongated and are provided with coupling means (7) at least on the two opposite longitudinal edges (3-4), so that several of such panels (2) can be mutually coupled to one another, wherein these coupling means (7) provide for an interlocking in a direction (R1) perpendicular to the plane of the floor covering (1), as well as in a direction (R2) perpendicular to the edges (3-4) concerned and parallel to the plane of the floor covering (1), and wherein these coupling means (7) are made such that the panels (2) can be coupled and/or uncoupled by means of a rotation along their longitudinal edges (3-4), characterized in that the width (B) of the panels (2) is smaller than 17 cm and in that the panels (2) have a single pattern which is repeated over the entire top surface.
摘要:
The invention relates to multi-layer composite materials which comprise the following components: (A) a foam layer, the foam being selected from polystyrene foams, polyurethane foams, polyester foams, butadiene-styrene block copolymer foams, sea sponges and aminoplast foams, (B) optionally at least one connecting layer and (C) a polyurethane layer.
摘要:
Method for realizing a floor panel, said floor panel having a laminated structure, wherein at least at the upper surface a printed decorative layer (16) with a wood pattern (5) is present, with thereupon a transparent layer of synthetic material (17) in which impressions (18A-18B-18C) are formed, characterized in that the floor panels (2) are formed of larger plates and wherein during the formation of these plates, at least one printed decorative layer (16) and a layer of synthetic material (17) are provided on a base plate (22), wherein, when said layers (16-17) are pressed onto the base plate (22), heat is supplied and simultaneously said impressions (18A-18B-18C) are formed in said layer of synthetic material (17) by means of a pressing mould, wherein said impressions (18A-18B-18C) are formed to substantially follow the wood pattern of the printed decorative layer (16).