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    PROCESS AND SYSTEM FOR MAKING CYCLOPENTADIENE AND/OR DICYCLOPENTADIENE
    1.
    发明公开
    PROCESS AND SYSTEM FOR MAKING CYCLOPENTADIENE AND/OR DICYCLOPENTADIENE 审中-公开

    公开(公告)号：EP3371133A1

    公开(公告)日：2018-09-12

    申请号：EP16862673.7

    申请日：2016-10-07

    申请人： ExxonMobil Chemical Patents Inc.

    发明人： IACCINO, Larry, L. ,  LEUNG, Kevin

    IPC分类号： C07C5/31 ,  C07C5/373 ,  C07C13/15 ,  C07C13/28 ,  C07C2/46 ,  C07C2/52 ,  C07C5/333

    CPC分类号： C07C5/373 ,  C07C2/52 ,  C07C5/333 ,  C07C2529/44 ,  C07C2601/10 ,  C07C2603/68 ,  C07C13/15 ,  C07C13/61

    摘要： Processes and systems for making cyclopentadiene and/or dicyclopentadiene include converting acyclic C5 hydrocarbon(s) into CPD in a first reactor in the presence of a C1-C4 co-feedstock to obtain a product mixture, separating the product mixture in a separation sub-system such as compression train to obtain a C5-rich fraction comprising CPD and essentially depleted of hydrogen and C1-C4 hydrocarbons, dimerizing the C5-rich fraction in a dimerization reactor to obtain a product effluent comprising DCPD, followed by separating the product effluent to obtain a DCPD-rich fraction. Multiple-stage of dimerization and separation steps can be optionally used to obtain multiple DCPD-rich fractions of various degrees of purity and quantity. C5-rich fractions from various stages of the process may be recycled to the first reactor, or converted into mogas components after selective hydrogenation. C5-rich fractions and mogas components may be optionally separated to produce value-adding chemicals.