COULOMETRISCHE TITRATIONSZELLE
    9.
    发明公开

    公开(公告)号:EP3036536A1

    公开(公告)日:2016-06-29

    申请号:EP14747947.1

    申请日:2014-08-07

    CPC classification number: G01N27/44704 G01N27/44 G01N27/44756 G01N31/164

    Abstract: Coulometric titration cell and a measurement arrangement comprising a coulometric titration cell, comprising a first electrochemical half-cell having a first electrode (205, 801, 7, 407, 507, 607, 907); a second housing (1, 401, 501, 601, 801, 901) comprising a second electrochemical half-cell having a second electrode (3, 403, 503, 603, 803, 903) and an electrolyte (2, 302, 402, 502, 602, 802, 902) into which the second electrode (3, 403, 503, 603, 803, 903) is immersed; a redox system having at least one first and second redox partner; at least one diaphragm (4, 604, 804) arranged between the first and second electrochemical half-cell; and a circuit (11, 411, 511) incorporating the first and second electrochemical half-cell; wherein, in operation, at least the diaphragm (4, 604, 804) and the first electrode (7, 407, 507, 607, 907) are in contact with the sample (14); characterized in that the second housing (1, 401, 501, 601, 801, 901) is closed, such that charge and mass transfer is possible only via the diaphragm (4, 604, 804); in that the electrolyte (2, 302, 402, 502, 602, 802, 902) is solid or consolidated and comprises a first redox partner, and in that the first and second redox partner of the redox system are chosen such that evolution of gas within the coulometric titration cell in operation is very substantially suppressed.

    IN-SITU ELECTROCHEMICAL DEPOSITION AND X-RAY FLUORESCENCE SPECTROSCOPY
    10.
    发明公开
    IN-SITU ELECTROCHEMICAL DEPOSITION AND X-RAY FLUORESCENCE SPECTROSCOPY 审中-公开
    电化学原位分离和X射线荧光光谱

    公开(公告)号:EP2885631A1

    公开(公告)日:2015-06-24

    申请号:EP13753294.1

    申请日:2013-08-09

    Abstract: A sensor comprising: a first electrode formed of an electrically conductive material and configured to be located in contact which a solution to be analysed; a second electrode configured to be in electrical contact with the solution to be analysed; an electrical controller configured to apply a potential difference between the first and second electrodes to electro-deposit chemical species from the solution onto the first electrode, and an x-ray fluorescence spectrometer configured to perform an x-ray fluorescence spectroscopic analysis technique on the electro-deposited chemical species, the x-ray fluorescence spectrometer comprising an x-ray source configured to direct an x-ray excitation beam to the electro-deposited chemical species on the first electrode and an x-ray detector configured to receive x-rays emitted from the electro-deposited chemical species and generate spectroscopic data about the chemical species electro-deposited on the first electrode, wherein the sensor is configured such that in use the x-ray excitation beam incident on the electro-deposited chemical species on the first electrode is attenuated by no more than 60%.

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