METHODS FOR OBTAINING SALTS OF SILVER(II) AND HYDRATES THEREOF, PRODUCTS OBTAINED BY THE METHODS AND USE OF THE SAME

    公开(公告)号:EP3347309A1

    公开(公告)日:2018-07-18

    申请号:EP16794402.4

    申请日:2016-09-12

    IPC分类号: C01G5/00

    CPC分类号: C01G5/006 C01G5/00

    摘要: The present invention relates to process of the electrochemical synthesis of the silver(ll) salts of high purity, the methods of synthesis of silver(ll) hydrates of high purity, products produced by these methods, and the use of so obtained silver(ll) compounds to modify the molecular structures of organic compounds including waste disposal. A method of electrochemical synthesis of a silver(II) salts with the electrolysis of the silver(l) salts or hydrogensalts of silver(l) in the acid solution containing the same anion as electrolyzed salt, preferably oxoanion or oxofluoroanion with inorganic element in a high degree of oxidation. Use of concentrated acid solution, preferably at a concentration of above 80%. The invention includes silver(II) salts obtained by this method. Process of the synthesis of silver(ll) salts hydrates with expose of silver(II) or silver(I/If) salts to liquid water, ice or water vapour, under strictly controlled conditions. Preferably, the gas solution with a concentration of water vapor 0-100 g/m 3, for 1-200 hours. The invention includes silver(II) salts hydrates obtained by this method. A method of modifying the molecular structures of organic compounds using an oxidising agent is based in on the oxidative initiation of a reagent with a redox compound, using at least one of silver(ll) compound. The invention comprises the use of a silver(ll) salt. The invention comprises the use of a silver(ll) salt as the redox reagent for disposal of hazardous waste and/or toxic substances, particularly organic.

    METHOD FOR RECOVERY OF SILVER FROM SULPHUR-CONTAINING ZINC LEACH RESIDUES
    8.
    发明授权
    METHOD FOR RECOVERY OF SILVER FROM SULPHUR-CONTAINING ZINC LEACH RESIDUES 有权
    从含硫锌矿渣回收银的方法

    公开(公告)号:EP2904126B1

    公开(公告)日:2017-12-06

    申请号:EP13844294.2

    申请日:2013-10-03

    摘要: The invention relates to a method of recovering silver and a method of controlling a leaching process for recovering silver from a direct zinc leach residue, an apparatus for recovering silver from a direct zinc leach residue, a control system for implementing the control method, and a computer program. The method comprising the steps of: 1) a silver leaching step, wherein the direct zinc leach residue is subjected to oxidative chloride leaching, having the following conditions: 1) chloride concentration of the leach solution in the range of 25-70 g/l ii) pH of the leach solution in the range 1.6 - 2.6 iii) redox potential of less than 460 mV (Pt vs. Ag/AgCI) 2) a silver recovery step, wherein silver is recovered from the silver containing leach solution.