摘要:
A dispersion stabilizer for suspension polymerization of vinyl compounds comprising a vinyl alcohol polymer (A) which has a saponification degree of 30 mol% or more and less than 60 mol% and a viscosity-average polymerization degree (P) of more than 200 and less than 600, and has a terminal alkyl group having 6 to 18 carbon atoms, and in which a content of monomer units having an oxyalkylene group is 0.3 mol% or less and the relationship between the viscosity-average polymerization degree (P) and a modification rate (S)(mol%) of the alkyl group satisfies Formula (1). Thus, there can be provided a dispersion stabilizer for suspension polymerization with which, during suspension polymerization of vinyl compounds including vinyl chloride, even when it is used in a small amount, the absorbency of a plasticizer is high, resulting in easy processing and formation of coarse particles is little and the remaining monomer components can be easily removed.
摘要:
A hierarchical catalyst composition comprising a continuous or particulate macroporous scaffold in which is incorporated mesoporous aggregates of magnetic nanoparticles, wherein an enzyme is embedded in mesopores of the mesoporous aggregates of magnetic nanoparticles. Methods for synthesizing the hierarchical catalyst composition are also described. Also described are processes that use the recoverable hierarchical catalyst composition for depolymerizing lignin, remediation of water contaminated with aromatic substances, polymerizing monomers by a free-radical mechanism, epoxidation of alkenes, halogenation of phenols, inhibiting growth and function of microorganisms in a solution, and carbon dioxide conversion to methanol. Further described are methods for increasing the space time yield and/or total turnover number of a liquid-phase chemical reaction that includes magnetic particles to facilitate the chemical reaction, the method comprising subjecting the chemical reaction to a plurality of magnetic fields of selected magnetic strength, relative position in the chemical reaction, and relative motion.
摘要:
The present invention relates to polymeric compositions useful in the manufacture of biocompatible medical devices. More particularly, the present invention relates to certain carboxylic monomers capable of polymerization to form polymeric compositions having desirable physical characteristics useful in the manufacture of ophthalmic devices. The polymeric compositions comprise polymerized carboxylic hydrophilic siloxanyl monomers.
摘要:
Novel vinyl carbamates, prepared from vinyl chloroformate and amino acids, and homo- and co-polymers containing from 5 to 100% of units of these novel vinyl carbamates, are disclosed. These polymers act as sequestering agents and are useful as detergency builders. Detergent compositions incorporating the polymers can be prepared without the use of phosphorus-containing detergent builders.
摘要:
A hydrogel implant article of significant softness, pliability and elasticity when dry as well as when wet consists of a random cross-linked copolymer of 2-hydroxyethyl acrylate and an alkyl acrylate. The acrylate hydrogel article is useful, in one instance, as the material to produce a scleral buckle in retinal detachment surgery.
摘要:
Disclosed are porous resin particles which contain a polymer of a monomer mixture containing, as monomers, at least a monofunctional (meth)acrylic acid ester and a crosslinking monomer. The monofunctional (meth)acrylic acid ester accounts for 1 wt% to 50 wt% of the monomer mixture, and the crosslinking monomer accounts for 50 wt% to 99 wt% of the monomer mixture. The porous resin particles have a specific surface area of 190 m 2 /g to 300 m 2 /g and a bulk specific gravity of 0.25 g/mL to 0.45 g/mL.
摘要:
Disclosed are emulsion polymerization methods of at least one ethylenically unsaturated monomer conducted in the presence of an aqueous phase comprising a water soluble chitosan salt and at least one co-stabilizer. Also disclosed is an aqueous dispersion prepared by the emulsion polymerization of at least one ethylenically unsaturated monomer conducted in the presence of a water soluble chitosan salt and at least one co-stabilizer. The emulsion polymer may be included in products including adhesives, binders, coatings, agricultural coatings, pharmaceutical formulations,medical formulations, and waste water treatment formulations.